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Home»TRIZ Case»Solid-State Electrolyte Film for Safer Lithium Batteries

Solid-State Electrolyte Film for Safer Lithium Batteries

May 22, 20263 Mins Read
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Solid-State Electrolyte Film for Safer Lithium Batteries

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Summary

Problems

Lithium-ion batteries face issues with liquid electrolytes, such as leakage, stability, corrosion, flammability, and safety concerns, while solid electrolytes have low ionic conductivity and high interface impedance, which hinder their performance and reliability.

Innovation solutions

A solid-state electrolyte film comprising a lithium salt, two polymers with specific molecular weights and granular shape, and a solid-state electrolyte with controlled particle size, integrated into a single film to enhance ionic conductivity and mechanical strength, along with a gel structure and buffer structure to reduce interface impedance.

TRIZ Analysis

Specific contradictions:

film strength
vs
film-forming capability

General conflict description:

Strength
vs
Ease of manufacture
TRIZ inspiration library
35 Parameter changes
Try to solve problems with it

Principle concept:

If polymer molecular weight is increased to improve mechanical strength, then film strength is improved, but film-forming capability and ion transport deteriorate

Why choose this principle:

The patent applies parameter changes by optimizing the molecular weight of PVDF within a specific range (60,000-1,800,000 g/mol) and controlling the weight ratio of polymer to solid electrolyte (1:0.05-1:2). These parameter optimizations balance mechanical strength, film-forming capability, and ion transport properties.

TRIZ inspiration library
35 Parameter changes
Try to solve problems with it

Principle concept:

If solid electrolyte particle size is reduced to improve ionic conductivity, then ionic conductivity is improved, but manufacturing precision and uniformity deteriorate

Why choose this principle:

The patent applies parameter changes by optimizing the particle size of solid electrolyte within a specific range (50 nm – 2 μm) and controlling the weight ratio parameters. These optimized parameters enable effective ion conduction while maintaining uniform dispersion and manufacturability.

Application Domain

solid-state electrolyte lithium battery safety ionic conductivity

Data Source

Patent EP4145578A1 Solid-state electrolyte film and solid-state battery
Publication Date: 08 Mar 2023 TRIZ 新能源汽车
FIG 01
IMGF0001
FIG 02
SREP0001
FIG 03
SREP0002
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AI summary:

A solid-state electrolyte film comprising a lithium salt, two polymers with specific molecular weights and granular shape, and a solid-state electrolyte with controlled particle size, integrated into a single film to enhance ionic conductivity and mechanical strength, along with a gel structure and buffer structure to reduce interface impedance.

Abstract

A solid-state electrolyte film includes a first lithium salt, a first polymer, a second polymer, and a solid-state electrolyte. The first polymer has a weight average molecular weight of between 60,000 g/mol and 1,800,000 g/mol. The second polymer has a granular shape. The solid-state electrolyte has a granular shape and a particle size (D50) of between 50 nm and 2 µm.

Contents

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    ionic conductivity lithium battery safety solid-state electrolyte
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    Table of Contents
    • Solid-State Electrolyte Film for Safer Lithium Batteries
      • Summary
      • TRIZ Analysis
      • Data Source
      • Accelerate from idea to impact
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