COMPOSITION COMPRISING PYRIDINE CARBOXYLATE AND CLOQUINTOCET HERBICIDES

Abstract

Protected compositions comprising (a) a pyridine carboxylate or N-oxide herbicide, or an agriculturally acceptable salt or ester thereof, and (b) a quinolinoxyacetate protectant, or an agriculturally acceptable salt or ester thereof. Methods for controlling unwanted vegetation comprising applying to vegetation or an area adjacent to vegetation, or applying to soil or water to control the emergence or growth of vegetation, (a) a pyridine carboxylate or N-oxide herbicide, or an agriculturally acceptable salt or ester thereof, and (b) a quinolinoxyacetate protectant, or an agriculturally acceptable salt or ester thereof.Claim 1: A protected composition comprising: (a) a pyridine carboxylate herbicide defined by formula (1), wherein: R¹ is cyanomethyl or propargyl; R² and R²' are independently hydrogen, C₁₋₆ alkyl, formyl, alkoxycarbonyl, or acyl; R³, R³', R³'', and R³''' are independently hydrogen, halogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₃ alkoxy, or C₁₋₃ haloalkoxy; or an agriculturally acceptable N-oxide, salt, or ester thereof; and (b) a protectant comprising cloquintocet or an agriculturally acceptable salt or ester thereof.

Description

20:26:54-03:00 PROTECTED COMPOSITIONS COMPRISING PYRIDINE CARBOXYLATE AND CLOQUINTOCET HERBICIDES CROSS REFERENCE TO RELATED APPLICATION This application claims the benefit of priority of U.S. provisional patent application no. D62 / 756,163, filed on November 6, 2016, which is incorporated herein by reference in its entirety. FIELD OF DISCLOSURE The description includes protected compositions comprising a pyridine carboxylate herbicide and a cloquintocet protectant, as well as methods for controlling unwanted vegetation by using these. BACKGROUND OF THE INVENTION Several recurring problems in agriculture involve controlling the growth of unwanted vegetation, which can negatively impact the growth of desired vegetation. To aid in the control of unwanted vegetation, researchers have developed a variety of chemicals and chemical formulations effective in controlling such unwanted growth. In some cases, while a herbicide may be effective in controlling unwanted vegetation, it can also have a phytotoxic effect on a crop, causing damage or even destroying it. Therefore, there is a need for new combination herbicides that limit the phytotoxicity of the herbicide active ingredient to the desired crops. COMPENDIUM This document describes protected compositions that can be used as IF-2020-07208301-APN-ANP#INPI Page 1 of 67 herbicides, for example, in crops. Protected compositions may contain (a) a pyridine carboxylate herbicide or an N-oxide, an agriculturally acceptable salt or ester thereof and (b) the quinolinoxyacetate protectant cloquintocet or an agriculturally acceptable salt or ester thereof. The weight ratio of (a) to (b) may be from 1:5 to 65:1 (e.g., from 1:5 to 5:1, or from 1:2 to 2:1). In some respects, the protected composition comprises (a) a pyridine carboxylate herbicide defined by Formula (i): where: R1 is cyanomethyl or propargyl; R2 and R2 are independently hydrogen, Ci-Ce alkyl, formyl, alkoxycarbonyl, or acyl; Ra. R1, R3, and R3 are independently hydrogen, halogen, alkyl, haloalkyl CrQi, C1-C3 alkoxy or C1-C3 haloalkyloxy or an agriculturally acceptable N-oxide, salt or ester thereof; and (b) a protectant comprising cloquintocet, or an agriculturally acceptable salt or ester thereof. In some respects, the protected composition comprises: (a) the pyridine carboxylate herbicide compound 4-amino-3-chloro-5-fluoro-6-(7fluoro-1H-indol-6-yl)pyridine-2-carboxylate cyanomethyl, hereinafter referred to as Compound A: IF-2020-07208301-APN-ANP#INPI Page 2 of 67 NH2 Fx.-Cl Compound A is an N-oxide, an agriculturally acceptable salt or ester thereof; and (b) a protectant comprising cloquintocet or an agriculturally acceptable salt or ester thereof. In some respects, the protected composition comprises: (a) the pyridine carboxylate herbicide compound 4-amino-3-chloro-5-fluoro-6-(7fluoro-1H-indole-6-yl)pyridine-2-carboxylate propargyl, hereinafter referred to as Compound B: Compound B an agriculturally acceptable N-oxide, salt or ester thereof; and (b) a protectant comprising cloquintocet or an agriculturally acceptable salt or ester thereof. In some aspects, the composition may also include an agriculturally acceptable adjuvant or carrier, an additional pesticide, or combinations thereof. In some aspects, the only active ingredients in the composition are (a) and (b). Also described herein are methods for controlling unwanted vegetation comprising applying to the vegetation, to an area adjacent to the vegetation, or to the soil or water to control the emergence or growth of vegetation a protected composition comprising: (a) a decarboxylat herbicide Page 3 of 67 (a) a salt or an agriculturally acceptable ester thereof; and (b) a protectant comprising cloquintocet or an agriculturally acceptable salt or ester thereof. In some aspects, (a) and (b) are applied simultaneously. In some aspects, (a) and (b) are applied sequentially. In some aspects, (a) and (b) are applied prior to the emergence of unwanted vegetation. In some aspects, (a) and (b) are applied after the emergence of unwanted vegetation. In some aspects, (a) is applied before or after emergence in the unwanted vegetation, and (b) is applied as a seed treatment to the crop. In some aspects, unwanted vegetation is found in cereals. In some aspects, unwanted vegetation is found in maize, wheat, barley, rice, sorghum, millet, or oats. In some aspects, unwanted vegetation is found in broadleaf crops.In some respects, unwanted vegetation is found in canola, flax, sunflower, soybeans, or cotton. In some cases, the pyridine carboxylate herbicide (a) may be applied at a rate of 0.1 grams of active ingredient per hectare (g ai / ha) to 300 g ai / ha (e.g., from 30 g ai / ha to 40 g ai / ha). In some cases, cloquintocet (b) may be applied at a rate of 1 g ai / ha to 300 g ai / ha (e.g., from 30 g ai / ha to 40 g ai / ha). In some cases, (a) and (b) may be applied at a weight ratio of 1:5 to 65:1 (e.g., from 1:5 to 5:1 or from 1:2 to 2:1). The description below sets forth details of one or more aspects of the present description. Other features, objects, and advantages will be evident from the description and the claims. DETAILED DESCRIPTION This description includes protected compositions comprising: (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide salt or ester thereof, and (b) a cloquintocet quinolinoxyacetate protectant or an agriculturally acceptable salt or ester thereof. This description also includes methods for controlling unwanted vegetation. In some TO Page 4 of 67 It is found in cereals. In some respects, unwanted vegetation is found in corn, wheat, barley, rice, sorghum, millet, or oats. In some respects, unwanted vegetation is found in broadleaf crops. In some respects, unwanted vegetation is found in canola, flax, sunflower, soybeans, or cotton. I. Definitions The terms used herein shall have their usual meaning in the art unless otherwise specified. The singular forms 'dn / una' and 'el / la' include plural references unless otherwise indicated. This description also covers other modalities comprising, consisting of, and essentially consisting of the modalities or elements presented herein, whether explicitly or implicitly. To the extent that the term 'or' is used (e.g., A or B), it is intended to mean A or B or both. If this description is intended to mean only A or B but not both, then the expression 'only A or B but not both' shall be used. Therefore, the use of the term 'Lo' herein is inclusive, not exclusive. The chemical groups mentioned when defining variable positions within the general formulas described herein (e.g., the term “alkyl”) are collective terms for the individual substituents included by the chemical group. The affix Cn-Cm next to a group or group indicates, in each case, the possible number of carbon atoms in the following group or group. As used in this description, the terms herbicide and herbicide active ingredient may be understood to include an active ingredient that kills, controls, or otherwise adversely modifies the growth of vegetation, particularly unwanted vegetation such as weed species, when applied in an adequate amount. As used in the present description, the term “herbicide effect” may be understood to include an adverse modifying effect of an active ingredient on vegetation, which includes, for example, a deviation[p_glg¿QC09gii^^ntqypt\[d^5¡gpi?ppi|pi 5 Page 5 of 67 natural!, elimination, regulation, desiccation, growth inhibition, growth reduction, and retardation. The term “herbicidal activity” generally refers to the herbicidal effects of an active ingredient. As used herein, “applying a herbicide or herbicidal composition” means administering it directly to the target vegetation or to the locus of the target vegetation or to the area where unwanted vegetation is to be controlled. Application methods include, but are not limited to, pre-emergence contact with the soil or water, post-emergence contact with the unwanted vegetation, or contact with the area adjacent to the unwanted vegetation. As used herein, the term ''vegetation'' may include, for example, dormant seeds, germinated seeds, emerging seedlings, plants propagated from vegetative propagules, immature vegetation, and established vegetation. As used herein, the term crop refers to desired vegetation, for example, plants grown to provide food, shelter, pasture, erosion control, etc. Examples of crops include cereals, pulses, vegetables, turf, pasture, orchard and timber trees, vines, etc. Preferably, herbicides or herbicidal compositions have no or minimal herbicidal effect on crops. As used herein, the term unwanted vegetation refers to vegetation that is not desired in a given area, for example, weed species. Herbicides or herbicidal compositions are used to control unwanted vegetation. Preferably, the herbicides or herbicidal compositions have a broad or complete herbicidal effect on the unwanted vegetation. As used herein, the term “active ingredient” may be understood to include a chemical composition or compound that has an effect on vegetation, specifically, a herbicidal effect or a protective effect on vegetation. As used herein, “acid equivalent” may be understood to include the amount of the acid form of an active ingredient that is calculated from the amount of the salt or ester form of that active ingredient. Page 6 of 67 The acid of an active ingredient Z' has a molecular weight of 100 Daltons and the salt form of Z has a molecular weight of 130 Daltons, an application of 130 g ai / ha of the salt of Z would be equal to the application of 100 g ae / ha of the acid form of Z: 130 g ai / ha of Z salt * (100 Da of acid 2 / 130 Da of Z salt) = 100 g ae / ha of Z acid. As used herein, unless otherwise indicated, the term “acyl” may be understood to include a group of formula -C(O)R, where O(O)” is shorthand notation for C=O. In the acyl group, the R may be alkyl (e.g., C₁-C₅alkyl), haloalkyl (e.g., O₁-O₂haloalkyl), alkenyl (e.g., C₂-C₅alkenyl), haloalkenyl (e.g., O₂-O₅haloalkenyl), alkynyl (e.g., C₁-C₅halkynyl), aryl or heteroaryl or arylalkyl (e.g., C₇-C₅alkyl). As used herein, the term “alkyl” may be understood to include saturated hydrocarbon residues of linear, branched, or cyclic chains. Unless otherwise stated, alkyl groups (e.g., CrC121, CrC12, CrCa, CrC6, or CrC1) are intended. Examples of alkyl groups include methyl, ethyl, propyl, cyclopropyl, 1-methylethyl, butyl, cyclobutyl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, pentyl, cyclopentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl, cyclohexyl, 1,1-dimethylpropyl, and 1,2-dimethylpropyl. 1-methyl-pentyl, 2-methyl-pentyl, 3-methyl-pentyl, 4-methyl-pentyl, 1,1-dimethyl-butyl, 1,2-dimethyl-butyl, 1,3-dimethyl-butyl, 2,2-dimethyl-butyl, 2,3-dimethyl-butyl, 3,3-dimethyl-butyl, 1-ethyl-butyl, 2-ethyl-1-butyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methyl-1-propyl, and 1-ethyl-2-methyl-2-propyl.Alkyl substituents can also be substituted with one or more chemical groups. Examples of suitable substituents include, for example, hydroxy, nitro, cyano, formite, alkoxy (CrC6), haloalkoxy (CrC6), acyl (CrC6), alkylthio (CrC6), haloalkylthio (CrC3), alkylsulfinyl (CrC6), haloalkylsulfinyl (CrC6), alkoxycarbonyl (CrC6), haloalkoxycarbonyl (CrC6), carbamoyl (CrC6), halocarbamoyl (CrC6), hydroxycarbonyl, alkylcarbonyl (CrC6), haloalkylcarbonyl (CrC6), aminocarbonyl, alkylaminocarbonyl (CrC6), haloalkylaminocarbonyl. Page 7 of 67 dihaloalkyllammocarbonyl CvCe, provided that the substituents are aesthetically compatible and that the chemical bonding and chain energy rules are satisfied. Preferred substituents include cyano and alkoxy CrC6. As used herein, the term alkyl group may be understood to include alkyl groups in which the hydrogen atoms may be partially or completely substituted with halogen atoms. Unless otherwise stated, the intended group includes C1-C2 alkyl groups (e.g., CrC12, CrC10, CrC10, CrC6, or C4-C4). Examples include chloromethyl, bromomethyl, dichloromethyl, trichlorofluoromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, and chlorodifluoromethyl. 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, and 1,1,1-trifluoroprop-2-yl. The hydroxyalkyl substituents may also be substituted with one or more chemical groups. Examples of suitable substituents include, for instance, hydroxy, nitro, cyano, thyme, CrC6 alkoxy, and CrC6 haloalkoxy.acyl CrCe, alkylthio CrCe, alkylsulfinyl Ct-Ce, haloalkylsulfinyl C1-C3, alkylsulfonyl C1-Ce, haloalkylsulfonyl Ci-Cs, alkoxycarbonyl C1-C5, haloalkoxycarbonyl C1-C3, carbamoyl Ci-Cg, halocarbamoyl Ci-Ce, hydroxycarbonyl, alkylcarbonyl C-C6, haloalkylcarbonyl Ci-Cs, aminocarbonyl, alkylaminocarbonyl CtCe, haloalkylaminocarbonyl, dialkylaminocarbonyl OC6 and dihaloalkylaminocarbonyl Ci-C6; provided that the substituents are aesthetically compatible and that the chemical bonding and chain energy rules are satisfied. Preferred substituents include cyano and alkoxy C-ι-Ce. As used herein, the term “alkoxy” may be understood to include a group of the formula RO-, wherein R is a substituted or unsubstituted alkyl group, as defined above. Unless otherwise stated, alkoxy groups are intended wherein R is a CfCzc· alkyl group (e.g., CrC1·, CrC10, CrCe, Ci-Cti; or O,C4).Examples include methoxy, ethoxy, propoxy, 1-methyl-ethoxy, 1-butoxy, 1-methyl-propoxy, 2-methyl-propoxy, 1,1-dimethyl-ethoxy, pentoxy, 1-methyl-butyloxy, 2-ni^íl2fou(tH53b8S <riietiFKyíd5íÍ?#lt0)I 8 Página 8 de 67. dimethyl-propoxr 1-ethyl-propoxy, hexoxL 1,1-dimethyl-propoxy, 1,2-dmneta-propoxy, 1-methylpentoxy, 2-methyl-pentoxy, 3-methyl-pentoxL 4-methyl-pentoxy, 1,1-dimethyl-butoxy, 1,2-dimethyl·· butoxy, 1,3-dimethyl-butoxyr2,2-dimethyl-butoxy, 2,3-dimethyl-butoxy, 3,3-dimethyl-butoxy, 1-ethllbutoxy, 2-ethyl I butoxy, 1,1,2-trimettl-propoxy. 1,2,2-trimethyl-propoxy, 1-ethyl-1-methyl-propoxy and 1-ethyl-2-methyl-propoxy. As used herein, the term “alkoxycarbonyl*” may be understood to include a group of the formula -C(O)OR, where R is a substituted or unsubstituted alkyl group, as defined above. Unless otherwise stated, alkoxycarbonyl groups are intended where R is an alkyl group (e.g., Ci-C12lCrC10rCi-Ca. CrC$, or Ci-C <i). Los ejemplos incluyen metoxicarbonilo, etoxicarbonilo, propoxicarbonilo, 1-metil-etoxicarbonilo. butoxicarbonilo, 1-metil-propoxicarbonilo, 2-metilpropoxicarbonilo, 1,1 -dimetil-etoxicarbonilo, pentoxicarbonilo, 1-metil-butiloxicarbonilo, 2metil-butoxicarbonilo, 3-metil-butoxioarbonilo, 2,2-dimetil-propoxicarbonílo. 1-etllpropoxicarbonilo. hexoxicarbonilo, 1,1-dimetil-propoxicarbonilo, 1,2-dimetilpropoxicarbonilo. 1-metíl-pentoxicarbonilo, 2-metil-pentoxicarbonilo, 3-metí Ipentoxicarbonilo.4-methyl-phenoxycarbonyl, 1,1-dimethyl-butoxycarbonyl, 1h2-dimethyl-butoxycarbonyl, 1,3-dimethyl-butoxycarbonyl, 2,2-dimethyl-butoxycarbonyl, 2,3-dimethyl-butoxycarbonyl, 3,3-dimethyl-butoxycarbonyl, 1-ethyl-butoxycarbonyl, 2-ethyl-butoxycarbonyl, 1,1,2-trimethyl-propoxycarbonyl, 1, 2,2-trimethyl-propoxycarbonyl, 1 -ethyl-1 -methyl-propoxycarbonyl, and 1-ethyl-2-methyl-propoxycarbonyl. As used herein, the term “haloalkoxy” may be understood to include a group of the formula R-Ck where R is a substituted or unsubstituted haloalkyl, as defined above. Unless otherwise stated, haloalkoxy groups are intended where R is a CrC2C alkyl group (e.g., CrCl2, CrCl0, CrCl3, CrCl4, or CrCl4). Examples include chloromethoxy, bromomethoxy, dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloroethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2-chloro ... <pD2t^fLMPKl)étqxÍrAP2fCÍiíNí<Pf2t2PI 9 Page 9 of 67 difluoroethoxy, 2,2dichloro-2“fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy and 1,1,1triflu oro pro p-2-oxt, As used in this description, the term “aryl,” as well as derived terms such as aryloxy, may be understood to include groups containing a monovalent aromatic carbocyclic group of 6 to 14 carbon atoms. Aryl groups may consist of a single ring or multiple fused rings. In some respects, aryl groups include Ce-Ca aryl groups. Examples of aryl groups include, but are not limited to, phenyl, biphenyl, naphthyl, tetrahydronaphthyl, phenylcyclopropyl, and indanyl. In some respects, the aryl group may be a phenyl, indanyl, or naphthyl group. As used herein, the term heteroaryl, as well as derived terms such as “heteroaryloxy”, may be understood to include a 5- or 6-membered aromatic ring containing one or more heteroatoms, for example, N, O, or S. Heteroaryl rings may be fused with other aromatic systems. Aryl or heteroaryl substituents may also be substituted with one or more chemical groups. Examples of suitable substituents include, for example, hydroxy, nitro, cyano, formyl, CrC3 alkyl, C2-C3 alkenyl, C2-C3 alkynyl, C6 alkoxy, C6 halioalkyl, C6 haloalkoxy, C6 acyl, C6 alkylthio, C6 alkylsulfinium, C6 alkylsulfonyl, C6 alkoxycarbonyl, C6 carbamoyl, and hydroxycarbonyl. alkylcarbonyl CrC6, aminocarbonyl, alkylaminocarbonyl O,-Oβ, dialkylaminocarbonyl Ch-Ce, provided that the substituents are spherically compatible and that the chemical bonding and chain energy rules are satisfied.Preferred substituents include halogen, CrC4 alkyl and C-C4 ioalkyl. As used herein, the term halogen, which includes derivative terms such as halo, refers to fluorine, chlorine, bromine, and iodine. As used herein, it may be understood that agriculturally acceptable salts and esters include salts and esters that exhibit herbicidal activity or that are or can be converted into plants, water, or soil for the herbicide mentioned. Illustrative agriculturally acceptable esters are shown in the following: Page 10 of 67 oxidized, metabolized or otherwise can be converted, e.g. in plants, water or soil, to the corresponding carboxylic acid which, depending on the pH, may be in a dissociated or undissociated form. The compounds described herein may include N-oxides. Pindine N'oxides can be obtained by oxidation of the corresponding pyridines. Suitable oxidation methods are described, for example, in Houben-Weyl, Methoden tier organischen Chemie [Methods in organic chemistry], enlarged and later volumes to the 4th edition, volume E 7b, p. 565 f. II. Pyridine Carboxylate Herbicides The compositions and methods described herein include a protected composition comprising (a) a pindine carboxylate herbicide defined by Formula (I): where: R1 is cyanomethyl or propargyl; R2 and R2 are independently hydrogen, alkyl CrC6, formiium, alkoxycarbonyl, or acyl! R3, R3, RJ, and R3 are independently hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C4 alkoxy, or C3 haloalkoxy; an agriculturally acceptable N-oxide, salt or ester thereof; and (b) a protectant comprising cyagocyontocet or an agriculturally acceptable salt or ester thereof. In some respects, the compositions and methods of the jfej^jq)dg®8J(jac¡ÁPtSñAlWéffiNí®! Page 11 of 67 protected composition comprising (a) the cyanomethyl pyridine carboxylate herbicide 4-amino3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-1)pyridine-2-carboxylate, Compound A: Compound A an N-oxide, an agriculturally acceptable salt or ester thereof, and (b) a protectant comprising cloquintocet or an agriculturally acceptable salt or ester thereof. In some respects, the compositions and methods of the present description include the protected composition comprising (a) the pyridine carboxylate herbicide 4-amino3-chloro-5-fluoro-6-(7-fluoro-1H-indo-1-6-1I)pyridine a-2-carboxylate propargite, Compound B: Compound B an N-oxide, an agriculturally acceptable salt or ester thereof, and (b) a protectant comprising cloquintocet or an agriculturally acceptable salt or ester thereof. The pyridine carboxylate herbicides defined by Formula (I), as well as the methods for preparing these pyridine carboxylate herbicides, are described in application PCTAJS2018 / 031004, filed on May 4, 2018, the description of which is expressly incorporated herein in its entirety by reference. In some respects, the pyridine carboxylate herbicide can be provided as an agriculturally acceptable salt. The agricultural salts Page 12 of 67 pyridine carboxylate herbicides include, but are not limited to: sodium salts; potassium salts; ammonium salts or substituted ammonium salts, in particular monodi- and trialkylammonium salts such as methylammonium, dimethylammonium and isopropylammonium; mono-, di- and trihydroxyalkylammonium or C2-C2 salts such as hydroxyethylammonium, di(hydroxyethyl)ammonium, tri(hydroxyethyl)ammonium, hydroxypropylammonium, di(hydroxypropyl)ammonium and tri(hydroxypropyl)ammonium; olamine salts; diglycolamine salts, choline salts, and quaternary ammonium salts such as those represented by the formula RaR'°R11R1zN* and wherein RB, R10, R11 and R12 (e.g., R9-R12) may each independently represent hydrogen, alkyl groups O,-Cg, alkenyl C2-Ca, alkynyl CrCB, alkoxy Cr10 C3, alkylthio CpCe, or aryl, provided that R^-R12 are spherically compatible. In some respects, the herbicide pyridine carboxylate can be provided as an agriculturally acceptable ester. Illustrative agriculturally acceptable esters of pyridine carboxylate herbicides include, but are not limited to: methyl, ethyl, propryl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1-ethylpropyl, hexyl, 1-methylhexyl (mexyl), β-ethylhexyl, heptyl, 1-methylheptyl (meptyl), octyl, isoethyl (isoctyl), butoxyethyl (butoyl), and benzyl. The herbicide pyridine carboxylate or an agriculturally acceptable N-oxide, salt or ester thereof, may be applied to vegetation or an area adjacent to vegetation or applied to soil or water to prevent the emergence or growth of vegetation in a quantity sufficient to induce a herbicidal effect. In some respects, the herbicide pyridine carboxylate, or an agriculturally acceptable N-oxide, salt, or ester thereof, is applied to vegetation or an area adjacent to vegetation, or is applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.1 grams of acid equivalent per hectare (g ae / ha) or greater, such as 0.2 g ae / ha or greater, 0.3 g ae / ha or greater, 0.4 g ae / ha or greater, 0.5 g ae / ha or greater, 0.6 g ae / ha or greater, 0.7 g ae / ha or greater, 0.8 g ae / ha or greater, 0.9 g ae / ha or greater, 1 g ae / ha or greater, 1.1 g ae / ha or greater, 1.2 g ae / ha or greater, 1.3 g ae / ha or greater, 1.4 g ae / ha or greater, 1.5 g ae / ha or greater, 1.6 g ae / ha or greater.1.7 g ae / ha or greater, 1.8. Page 13 of 67 greater, 2 g ae / ha or greater, 2.25 g ae / ha or greater, 2.5 g ae / ha or greater, 2.75 g ae / ha or greater, 3 g ae / ha or greater, 4 g ae / ha or greater, 5 g ae / ha or greater, 6 g ae / ha or greater, 7 g ae / ha or greater, 3 g ae / ha or greater, 9 g ae / ha or greater, 10 g ae / ha or greater, 11 g ae / ha or greater, 12 g ae / ha or greater, 13 g ae / ha or greater, 14 g ae / ha or greater. 15 g ae / ha or greater, 5 16 g ae / ha or greater, 17 g ae / ha or greater, 18 g ae / ha or greater, 19 g ae / ha or greater, 20 g ae / ha or greater, 22 g ae / ha or greater, 24 g ae / ha or greater, 25 g ae / ha or greater, 26 g ae / ha or greater.28 g ae / ha or greater, 30 g ae / ha or greater, 32 g ae / ha or greater, 34 g ae / ha or greater, 35 g ae / ha or greater, 36 g ae / ha or greater, 38 g ae / ha or greater, 40 g ae / ha or greater, 42.5 g ae / ha or greater, 45 g ae / ha or greater, 47.5 g ae / ha or greater, 50 g ae / ha or greater, 52.5 g ae / ha or greater, 55 g ae / ha or greater, 57.5 g ae / ha or greater, 60 g ae / ha or greater, 65 g ae / ha or greater, 70 g ae / ha or greater, 75 g ae / ha or greater, 80 g ae / ha or greater, 85 g ae / ha or greater, 90 g ae / ha or greater 95 g ae / ha or greater, 100 g ae / ha or greater, 110 g ae / ha or greater, 120 g ae / ha or greater, 130 g ae / ha or greater, 140 g ae / ha or greater, 150 g ae / ha or greater, 160 g ae / ha or greater, 170 g ae / ha or greater, 180 g ae / ha or greater, 190 g ae / ha or greater, 200 g ae / ha or greater, 210 g ae / ha or greater, 220 g ae / ha or greater, 230 g ae / ha or greater, 240 g ae / ha or greater, 250 g ae / ha or greater, 260 g ae / ha or greater, 270 g ae / ha or greater, 280 g ae / ha or greater or 290 g ae / ha or greater; in an amount of 300 g ae / ha or less, such as 290 g ae / ha or less, 280 g ae / ha or less, 270 g ae / ha or less.260 g ae / ha the lowest, 250 g ae / ha the lowest, 240 g ae / ha the lowest, 230 g ae / ha the lowest, 220 g ae / ha the lowest, 210 g ae / ha the lowest, 200 g ae / ha the lowest, 190 g ae / ha the lowest, 180 g ae / ha the lowest, 170 g ae / ha the lowest, 160 g ae / ha the lowest, 150 g ae / ha the lowest, 140 g ae / ha the lowest, 130 g ae / ha the lowest, 120 g ae / ha the lowest, 110 g ae / ha the lowest, 100 g ae / ha the lowest, 95 g ae / ha the lowest, 90 g ae / ha the lowest, 85 g ae / ha the lowest, 80 g ae / ha the lowest smaller, 75 g ae / ha smaller, 70 g ae / ha smaller, 65 g ae / ha smaller, 60 g ae / ha smaller, 57.5 g ae / ha smaller, 55 g ae / ha smaller, 52.5 g ae / ha smaller, 50 g ae / ha smaller, 47.5 g ae / ha smaller, 45 g ae / ha smaller, 42.5 g ae / ha smaller, 40 g ae / ha smaller, 38 g ae / ha smaller, 36 g ae / ha smaller, 35 g ae / ha smaller, 34 g ae / ha smaller, 32 g ae / ha smaller, 30. Page 14 of 67 smaller, 26 g ae / ha smaller, 25 g ae / ha smaller, 24 g ae / ha smaller, 22 g ae / ha smaller, 20 g ae / ha smaller, 19 g ae / ha smaller, 16 g ae / ha smaller, 17 g ae / ha smaller, 16 g ae / ha smaller, 15 g ae / ha smaller, 14 g ae / ha smaller, 13 g ae / ha smaller, 12 g ae / ha smaller, 11 g ae / ha smaller, 10 g ae / ha smaller, 9 g ae / ha smaller, S g ae / ha or less, 7 g ae / ha or less, 6 g ae / ha or less, 5 g ae / ha or less, 4 g ae / ha or less, 3 g ae / ha or less, 2.75 g ae / ha or less, 2.5 g ae / ha or less, 2.25 g ae / ha or less, 2 g ae / ha or less, 1.9 g ae / ha or less less, 1.8 g ae / ha or less, 1.7 g ae / ha or less, 1.6 g ae / ha or less, 1.5 g ae / ha or less, 1.4 g ae / ha or less, 1.3 g ae / ha or less, 1.2 g ae / ha or less, 1.1 g ae / ha or less, 1 g ae / ha or less, 0.9 g ae / ha minor, 0.8 g ae / ha or less, 0.7 g ae / ha or less, 0.6 g ae / ha or less, 0.5 g ae / ha or less, 0.4 g ae / ha or less, 0.3 g ae / ha or less or 0.2 g ae / ha or less; or in an amount within any defined range between any pair of the above values, such as from 0.1 g ae / ha to 300 g ae / ha, from 1 g ae / ha to 150 g ae / ha, from 10 g ae / ha to 200 g ae / ha, from 25 g ae / ha to 75 g ae / ha, or from 40 g ae / ha to 100 g ae / ha. 111. Cloquintocet In addition to the pyridine carboxylate herbicide, the compositions and methods described herein may include a quinolinoxyacetate protectant or an agriculturally acceptable salt or ester thereof. Herbicide protectants are molecules used in combination with herbicides to make them safer, i.e., to reduce the herbicidal effect of the herbicide on crop plants and to improve selectivity between the crops and the unwanted vegetation targeted by the herbicide. Herbicide protectants may be used to pretreat crop seeds before planting. Protectants may also be sprayed onto plants as a mixture with the herbicide, or separately and sequentially with the herbicide. Quinolinoxyacetate shields are known in the art and are described, for example, in U.S. Patent No. 4,902,340 and U.S. Patent Application Publication No. 2014 / 0031224, descriptions of which are incorporated herein by reference. The shields of qróbti0£i^á2matn-ÁKluyá^P#WI 15 Page 15 of 67 For example, cloquintocet and its derivatives. Cloquintocet is a quinoline compound that has the following chemical structure: This form of cloquintocet can also be called “cloquintocet-acid* In some respects, the protectant may comprise an agriculturally acceptable salt of cloquintocet. Agriculturally acceptable salts of cloquintocet include, for example, sodium, potassium, ammonium, monoethanolammonium, diethanolammonium, triethanolammonium, monoisopropanommonium, diisopropanommonium, triisopropanommonium, choline, β-,β-dimethylethanolammonium, diethylammonium, dimethylammonium, trimethylammonium, triethylammonium, and isopropanommonium salts. In some respects, the protectant may comprise an agriculturally acceptable ester of cloquintocet. Agriculturally acceptable esters of cloquintocet include, for example, methyl, ethyl, propyl, butyl, or methylhexyl (also known as mexyl) cloquintocet esters. In some respects, the protectant comprises cloquintocetmexyl, the structure of which is shown below. In some respects, the protectant may comprise cloquintocet acid, an agriculturally acceptable salt of cloquintocet, an agriculturally acceptable ester of cloquintocet, or mixtures thereof. Cloquintocet can be a protectant when applied in combination with herbicides and can be used to reduce phytotoxicity in crops such as wheat, barley, triticale, rye, teff, oats, corn, sorghum, rice, millet, canola / oilseed, sunflower, and sugar beet. Page 16 of 67 of pastures. In some aspects, unwanted vegetation is found in broadleaf crops. In some aspects, unwanted vegetation is found in canola, flax, sunflower, soybeans, or cotton. Cloquintocet or an agriculturally acceptable salt or ester thereof may be used in a quantity sufficient to induce a protective effect. In some cases, cloquintocet or an agriculturally acceptable ester or salt thereof is applied to vegetation or an area adjacent to vegetation, or applied to soil or water in an amount of 1 g of active ingredient per hectare (ai / ha) or greater, such as 2 g ai / ha or greater, 3 g ai / ha or greater, 4 g ai / ha or greater.5 g ai / ha o mayor 6 g ai / ha o mayor, 7 g ai / ha o mayor, 8 g ai / ha o mayor, 9 g ai / ha o mayor, 10 g ai / ha o mayor, 11 g ai / ha o mayor, 12 g ai / ha o mayor, 13 g ai / ha o mayor, 14 g ai / ha o mayor, 15 g ai / ha o mayor, 16 g ai / ha o mayor, 17 g ai / ha o mayor, 13 g ai / ha o mayor, 19 g ai / ha o mayor, 20 g ai / ha o mayor, 22 g ai / ha o mayor, 24 g ai / ha o mayor, 25 g ai / ha o mayor, 26 g ai / ha o mayor, 28 g ai / ha o mayor, 30 g ai / ha o mayor, 32 g ai / ha o mayor, 34 g ai / ha o mayor, 35 g ai / ha o mayor, 36 g ai / ha o mayor, 38 g ai / ha o mayor, 40 g ai / ha o mayor, 42.5 g ai / ha o mayor, 45 g ai / ha o mayor, 47.5 g ai / ha o mayor, 50 g ai / ha o mayor, 52.5 g ai / ha o mayor, 55 g ai / ha o mayor, 57.5 g ai / ha o mayor, 60 g ai / ha o mayor, 65 g ai / ha o mayor, 70 g ai / ha o mayor, 75 g ai / ha o mayor, SO g ai / ha o mayor, 85 g ai / ha o mayor, 90 g ai / ha o mayor, 95 g ai / ha o mayor, 100 g ai / ha o mayor, 110 g ai / ha o mayor, 120 g ai / ha o mayor, 130 g ai / ha o mayor. 140 g aí / ha o mayor, 150 g aí / ha o mayor.160 g ai / ha o mayor, 170 g ai / ha o mayor, 180 g ai / ha o mayor, 190 g ai / ha o mayor, 200 g ai / ha o mayor, 210 g ai / ha o mayor, 220 g ai / ha o mayor. 230 g ai / ha o mayor. 240 g ai / ha o mayor, 250 g ai / ha o mayor, 260 g ai / ha o mayor, 270 g ai / ha o mayor, 230 g ai / ha o mayor, o 290 g ai / ha o mayor; en una cantidad de 300 g ai / ha o menor, tal como 290 g ai / ha o menor, 280 g ai / ha o menor, 270 g ai / ha o menor, 260 ga / ha o menor, 250 g ai / ha o menor, 240 g ai / ha □ menor, 230 g ai / ha o menor, 220 g ai / ha o menor, 210 g ai / ha o menor, 200 g ai / ha o menor, 190 g ai / ha o menor, 180 g ai / ha o menor. 170 g ai / ha o menor, 160 g ai / ha o menor, 150 g ai / ha o menor. 140 g ai / ha o menor, 130 g aí / ha o menor, 120 ^-aiffie-ayMgaójt.-AIFN-^TáPSi^Bl. Página 17 de 67 smaller, 100 g ai / ha smaller, 95 g ai / ha smaller, 90 g ai / ha smaller, B5 g ai / ha smaller, 80 g ai / ha smaller, 75 g ai / ha smaller, 70 g ai / ha smaller, 65 g ai / ha smaller, 60 g ai / ha smaller, 57.5 g ai / ha smaller. 55 g ai / ha the smallest, 52.5 g ai / ha the smallest, 50 g ai / ha the smallest, 47.5 g ai / ha the smallest, 45 g ai / ha the smallest, 42.5 g ai / ha the smallest, 40 g ai / ha the smallest, 38 g ai / ha the smallest, 36 g ai / ha the smallest, 35 g ai / ha the smallest, 34 g ai / ha the smallest, g ai / ha the smallest. 30 g ai / ha the smallest, 28 g ai / ha the smallest, 26 g ai / ha the smallest, 25 g ai / ha the smallest, 24 g ai / ha the smallest, 22 g ai / ha the smallest, 20 g ai / ha the smallest, 19 g ai / ha the smallest, 18 g ai / ha the smallest, 17 g ai / ha the smallest.16 g ai / ha or less, 15 g ai / ha or less, g ai / ha or less, 13 g ai / ha or less, 12 g ai / ha or less, 11 g ai / ha or less, 10 g ai / ha or less, 9 g ai / ha or less, 8 g ai / ha or less, 7 g ai / ha or less, 6 g ai / ha or less, 5 g ai / ha or less, 4 g ai / ha or less, 3 g ai / ha or less, or 2 g ai / ha or less; or in an amount within any defined interval between any pair of the above values, such as from 1 g ai / ha to 300 g ai / ha, from 5 g ai / ha to 159 g ai / ha, from 10 g ai / ha to 200 g ai / ha, from 20 g ai / ha to 75 g ai / ha, or from 40 g ai / ha to 100 g ai / ha. IV. Protected Compositions A protected composition comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt or ester thereof may be mixed with or applied in combination with (b) a protectant comprising cloquintocet or an agriculturally acceptable salt or ester thereof. In some respects, (a) and (b) are used in sufficient quantity to induce an unexpectedly enhanced herbicidal effect (e.g., greater damage or injury to unwanted vegetation) while still exhibiting good crop compatibility (e.g., no greater crop damage or minimal increase in crop damage or injury) compared to the individual application of herbicide compounds (a) or (b). In some respects, the damage or injury to unwanted vegetation caused by the protected compositions and methods described herein is assessed using a scale of 0% to 100%, compared to untreated control vegetation, where 0% indicates no damage to unwanted vegetation. Page 18 of 67 Complete destruction of unwanted vegetation. Similarly, in some respects, the damage or injury to crops caused by the protected compositions and methods described herein is assessed using a scale of 0% to 100%, compared to control crops treated only with the herbicide or protectant, where 0% indicates no damage to the crop and 100% indicates complete destruction of the crop. In some respects, the combined action of (a) the herbicide pyridine carboxylate or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) the protectant cloquintocet or an agriculturally acceptable salt or ester thereof results in an unexpectedly enhanced herbicidal effect against unwanted vegetation, even at application rates below those normally used for the herbicide to have a herbicidal effect on its own. In some respects, the compositions and methods described herein may be used, depending on the individual components, at lower application rates to achieve a herbicidal effect comparable to the effect produced by the individual components at normal application rates.In some respects, the combined action of (a) the herbicide pyridine carboxylate or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) the protectant cloquintocet or an agriculturally acceptable salt or ester thereof results in an unexpected protective effect for the desired crops against crop damage that may be caused by the herbicide alone. In some respects, the weight ratio of (a) the pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof (in g ae / ha) to (b) the cloquintocet protectant or an agriculturally acceptable salt or ester thereof (in g ai / ha) may be 1:5 or greater, such as 1:4.75 or greater, 1:4.5 or greater, 1:4.25 or greater, 1:4 or greater, 1:3.75 or greater, 1:3.5 or greater, 1:3.25 or greater, 1:3 or greater, 1:2.75 or greater, 1:2.5 or greater, 1:2.25 or greater, 1:2 or greater, 1:1.9 or greater, 1:1.5 or greater. 1:1.7 or greater, 1:1.6 or greater, 1:1.5 or greater, 1:1.4 or greater, 1:1.3 or greater, 1:1.2 or greater, 1:1.1 or greater, 1:1 or greater, 1.1:1 or greater, 1.2:1 or greater, 1.3:1 or greater«,Fl242l)4»7W®tJ-^&N-AMP#fl3íí?l 19 Page 19 of 67 1.6:1 or higher, 1.7:1 or higher, 1.8:1 or higher, 1.9:1 or higher, 2:1 or higher, 2.25:1 or higher, 2.5:1 or higher, 2.75:1 or higher, 3:1 or higher, 3.25:1 or higher, 3.5:1 or higher, 3.75:1 or higher, 4:1 or higher, 4.25:1 or higher, 4.5:1 or higher, 4.75:1 or higher, 5:1 or higher, 6:1 or higher, 7:1 or higher, 8:1 or higher, 9:1 or higher, 10:1 or higher, 11:1 or higher, 12:1 or higher, 13:1 or higher, 14:1 or higher, 15:1 or higher, 16:1 or higher, 17:1 or greater, 18:1 or greater, 19:1 or higher, 20:1 or higher, 25:1 or higher, 30:1 or higher, 35:1 or higher, 40:1 or higher The weight ratio of {a} to (b) can be 65:1 or less, such as 60:1 or less, 55:1 or less, 50:1 or less, 45:1 or less, 40:1 or less, 35:1 or less, 30:1 or less, 25:1 or less, 20:1 or less, 19:1 or less, 18:1 or less, 17:1 or less, 16:1 or less, 15:1 or less, 14:1 or less, 13:1 or less, 12:1 or less, 11:1 or less, 10:1 or less, 9:1 or less, 8:1 or less, 7:1 or less, 6:1 or less, or 5:1 or less. 4.75:1 or less, 4.5:1 or less, 4.25:1 or less, 4:1 or less, 3.75:1 or less, 3.5:1 or less, 3.25:1 or less, 3:1 or less. 2.75:1 or less, 2.5:1 or less, 2.25:1 or less, 2:1 or less, 1.9:1 or less, 1.8:1 or less, 1.7:1 or less, 1.6:1 or less, 1.5:1 or less, 1.4:1 or less, 1.3:1 or less, 1.2:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.2 or less, 1:1.3 or less, 1:1.4 or less, 1:1.5 or less, 1:1.6 or less, 1:1.7 or less, 1:1.8 or less, 1:1.9 or less, 1:2 or less, 1:2.25 or less, 1:2.5 or less, 1:2.75 or less, 1:3 or less, 1:3.25 or less, 1:3.5 or less, 1:3.75 or less, 1:4 or less, 1:4.25 or less, 1:4.5 or less, or 1:4.75 or less; or the weight ratio of {a) to (b) may vary from any of the minimum ratios to any of the maximum ratios provided above, such as from 1:5 to 65:1, from 1:2 to 25:1, from 1:1 to 15:1, from 1:3 to 4:1, or from 1:1.5 to 10:1. In some respects, (a) and (b) can independently be used at a purity of 90% to 100% (e.g., 95% to 100%) according to nuclear magnetic resonance (NMR) spectroscopy. V. Formulations This description also includes formulations of the compositions and methods described herein. IF-2020-07208301-APN-ANP#INPI Page 20 of 67 A. Additives The compositions and methods described herein may also be mixed with or applied with an additive. In some aspects, the additive is added sequentially. In some aspects, the additive is added simultaneously. In some aspects, the additive is premixed with the herbicide pyridine carboxylate or N-oxide, or an agriculturally acceptable salt or ester thereof. In some aspects, the additive is premixed with the protectant cloquintocet or an agriculturally acceptable salt or ester thereof. 1. Other pesticides Some aspects of the protected compositions include the addition of one or more additional pesticide active ingredients to the protected compositions. These pesticide active ingredients may include one or more of a herbicide, insecticide, fungicide, nematocide, miticide, arthropodicide, bactericide, plant growth regulator, or combinations thereof compatible with the compositions described herein. In some respects, the additive is an additional herbicide. For example, the compositions described herein can be applied in conjunction with one or more additional herbicides to control unwanted vegetation. The composition can be formulated with the additional herbicide(s), tank-mixed with the additional herbicide(s), or applied sequentially with the additional herbicide(s). Illustrative additional herbicides include, but are not limited to: 4-CPA; 4-CPB; 4-CPP; 2,4-D; 2,4-D choline salt; 2,4-D salts, esters, and amines; 2,4-DB; 3,4-DA; 3,4-DB; 2,4-DEB; 2,4DEP; 2,4-DP; 3,4-DP; 2,3,6-TBA; 2,4,5-T; 2,4.5-TB acetochlor; acifluorphen; achlorphene; acrolein; alachor; alidochlor; aloxidim; allyl alcohol; alorac; ametridione; ametrine; amibuzin; amicarbazone; amidosulfuron; aminocyclopyrachlor; 4-aminopicolinic acid-based herbicides such as halauxifen, halauxifen-methyl, florpyrauxifen, and those described in U.S. patents Nos. 7,314,849 and 7,432,227 to Balko, et al.; aminopyralid; amiprofos-methyl; amitrol; sulfamate d^^Q'^jri(ipr2(DOfpfQ^PTsP-!Aí?:4-R??lf]^3?I 21. Page 21 of 67 asulam; atratona; atrazine; azaphenidine; azimsulfurone; aziprothrin; barban; BCPCrbeflubutamid; benazolin; bencarbazone; benfluralin; benfuresate; bensulide; bensulfuron; benthiocarb; bentazone; benzadox; benzphendizone; benzipram; benzobicidone; benzophenap; benzofluor; benzoylprop; benzthiazurone; bilanaphos; bicyclopyrone; bifenox; bilanaphos; bispyribac; borax; tease it; bromobomlo; whipped bromine: bromofenoxim; bromoxynil; brom pi reason a; butachlor; butafenacil: butamifos; batenachlor; butidazoi; buthiurone; butraline; butroxydim; buturone: butylate; cacodylic acid; cafenstrol; calcium chlorate; calcium cyanamide; cambendichlor; carbasulam; carbetamide; carboxazole; chlorprocarb; carfent thiozona-ethyl; CDEA; CEPO; chlormethoxyfen; chlorambene; chloranocryl; chlorazifop; chlorazine; chlorobromuron; dorbufam; chloreturone; chlorfenac; chlorfenprop; chlorflurazole; chlorflurenol; chloridazone; dorbufam; chlornitrofen; chloropona; chlorotolurone; chloroxurone; chloroxynil; chlorpropham;clorsdfuron: chlortai; chlorthiamid; cinidon-ethyl; cinmetilina: cinosulfuron; cisanilida; clacifos; cletodim; cliodinate; clodinafop-propargyl; dofop; ctomazona; clomeprop; cloprop; cloproxím; clopyralid; cloransulam-methyl; CMA; copper sulfate; CPMF; CPPC: credazine; cresol; curriilurona; danathrine; cyanazine; cycloate; ciclopyrimorate; ciclosulfa morona; cycloxidim; cycloron; cihalofop-butyl; ciperquat; cyprazine; dprazol; cypromid; daimurona: dalapon; dazomet; delacloro; desmedifam; desmethrin; dkalate; dicamba; dichlobenyl; dichloralurea; didormate; dichlorprop; dichlorprop-P; didofop-met I I; diclosulann; dietamquat; diet; diphenopenten; difenoxurona; difenzoquat; diflufenican; diflufenzopyr; dimefuron; dimepiperate; dinnetadoro; dimethamethrin; dimethenamidum; dimethenamida-P; dimexane, dimidazone; dinitramine: dinophenate: dinoprop; dinosam; dinoseb; dinoterb; difenamida: dipropetrin: diquat; disul; dithiopyr; diuron; DMPA; DNOC; DSMA; EBEP; aegiinazine; endotai; epronaz;EPTC; erbon; esprocarb; etalfJuralina; etametsulfurone; etbenzamide; etametsulfurone; etidimurone; etiolate; etobenzamide; etofumesate; ethoxyphene; ethoxysulfurone; ethinophene; ethnipromid; etobenzanid; EXD; fenasulam; fenoprop; fenoxaprop; fenoxaprop-P-ethyl; fenoxaprop-P-ethyl + isoxadifen-ethyl; fenoxasulfone; phenquinotrione; fenteracol; fenth taprop; fentrazamide; fenurone; ferrous sulfate; flamprop; flampro|EMQlí&f)a§ütf&(i)brt4iptfleAáá&^WI; Page 22 of 67 fluazifop; fluazifop-P-butyl; fluazolate; ftucarbazona; flucetosulfurone; fluchloralin; flufenacet; flufenican; flufenplr-ethyl; flumetsulam; flumezine; flumiclorac-pentyl; flumioxazine: flumipropine; fluometuron a; fluerodifen; fluoroglycophen; fluoromidine: fluoronitrophen: fluothiurona; flupoxam; flupropadlo; flu props born; flupyrsulfurone; fluridona; flurochloridona; fluroxypyr; fluroxypyr-meptyl; flurtamona; flutiacet; fomesafeno: foramsulfurone: phosamine; fumiclorac: furiloxifeno; glufosinate; glufosinate-ammonium; glufosinate-P-amonío¡ sales and esters of glyphosate: halosafeno; halosulfurone; haloxydine; haloxifop; hexadoroacetona; hexaflurate; hexazinona: i maza met abe nz; imazamox: imazapic; imazapir; imazaquln; imazetapyr; imazosulfurone; indanofan; indaziflam; yodobonilo: yodomethane; yodosulfuron: yodosulfuron-ethyl-sodium; i oten sulfuren a; ¡oxinilo; hypazine; ipfencarbazone; iprimidam; isocarbamide; sodium; isomethyozin; isonourona; isopolinate; isopropalin; iseproturona;isourone; isoxabene; isoxachlortol; isoxaflutol; isoxapyrifop: karbutylate: ketospiradox; lactofeno: leñadlo; linurona: MAA; MAMA; MCPA esters and amines: MCPA-thioethyl; MCPB; mecoprop; meooprop-P; medinoterb; mephenacet; mefluidida; yodosulfuron-ethyl-sodium; iofensulfurone; ¡oxinilo; hypazine: ipfenoarbazone; iprimidam; isocarbamide; isocyle; isomethiozine; ¡sonorurone; isopolinate; isopropalin; isoproturona; isourone, isoxabene; isoxadortol; isoxafíutol; isoxapyrifop; karbutylated; ketospiradox; lactophen; leñadlo; linurona; MAA; MAMA; MCPA esters and amines; MCPA-thioethyl; MCPB; mecoprop; mecoprop-P; medinoterb; mephenacet; mefluidida; mesoprazine; mesosulfurone; mesotrione; metam; metamifop; metamitron; metazachlor; metflurazone; metabenzthiazurene; metalpropaline; methazole; methió be ncarb: methiozeline; methiurona; metomethone; metoprotrin; methyl bromide; Methyl sothiocyanate: methyldimrona; methobenzuron; methobromurone; metolacioro; metosulam; methoxurona: metribuzin;metsulfurone: molinate; monalide; monisourone: monochloroacetic acid: monoinurone; monurone; morphamquat: MSMA; naproanilide; napropamide, napropamide-M; naptalam; neburone; nicosulfurone; nipiradofen; nitralin; nitrophene; nitrofluorfen; norflurazone; norurone; CCH; orbencarb; orthochlorobenzene: orthosulfamurone, oryzalin; oxadiargilo; oxadiazone; iF.gg'gjiíoggpgijo ।; Page 23 of 67 oxaziclomefon; oxyfluorfen o; pa raíl ufen-etilo parafl uro na; paraquat; pebuiato; ácido pelargónico; pendimetalina; penoxsulam; pentachlorophenol; penta no chloro; pentoxazone; perfluidona; petoxamide; fenisofam: fenmedifam; fenmedifam-ethyl; phenobenzurone; phenylmercury acetate; picloram; picolinafeno, pinoxadeno; piperophos; potassium arsenite; potassium acid; cyanate of potassium; pretilachloro; primisulfurone; prociazina; prodiamine; profluazol; profluralina; profoxidim; proglinazine; prohexadione-calcio; prometona; prometrina; pronamida; propacloro: prapanilo; propaquizafop, propazina; profam; pro piso el oro; propoxicarbazona: propirisulfurona; propizamida; prosuífaiina; presulfocarb; prosulfurona; proxano; prinacloro; pidanona; piraclonilo; piraflufeno; pyrasulfotol; pirazogilo; pirazona; pi razo I ¡nato; pirazosulfurona; pirazoxifeno: piribenzoxim; piributicarb; piriclor; piridafol; pirídato; piríftalid; piriminobac; pirimisulfano; piritiobac-sodio; píroxasulfona; piroxsulam;quinciorac; quinmerac: quinoclamina; quinonamide; quizalofop; quizaiofop-P-ethyl; qu iza lofop-P-tefu rilo; rodetaniío; rim sulfuren a; saflufenaclo; Smetolacloro; subtilazin; secbumetona; setoxidim; sidurona; सिमाज़िना; simetone; symmetry; SNA: sodium arsenite; sodium acid; sodium chlorate; sulcotrione: sulphalate; sulfentrazone; sulfometurone; sulfosato; sulfosulfurone; sulfuric acid; sulglicapina; sweep; TCA; Tebutam; tebutiurona; tefurilthona; tembotriona; tepraloxidim; terbacílo: terbucarb; terbucloro; terbumetona; terbutíiazina; terbu trina; tetraflurona: te ni icloro; tiameturona; tiazaflurona; tiazopir; tidiazimina; tídiazurona; tiencarbazona; tifensulfurona, tiobencarb; tiafenacilo; tiocarbazilo: tioclorim; tolpiralato; topramezona; traícoxidim; trl alato; triafamona; trlasulfurona; triazíflam; tribenurona; tribenurona; tricamba; sal de colina de triclopir; ásteres y aminas de tridopir; tridifan; trietazina; trifloxisulfurona; trifludimoxazina;trifluralin, triflusulfuron; trifop; trifopsime; trihydroxytriazine; trimeturone; tripropindan; tritac; tritosulfuron; vernolate; xylchlor; and salts, esters, optically active isomers and mixtures thereof.; In some respects, the additional pesticide or an agriculturally acceptable salt or ester thereof is provided in a formulation premixed with (a), (b), or combinations thereof. In some respects, Page 24 of 67 Pyridine carboxylate or an agriculturally acceptable N-oxide, salt, or ester thereof in a formulation premixed with an additional pesticide. In some respects, cloquintocet protectant or an agriculturally acceptable salt or ester thereof is provided in a formulation premixed with an additional pesticide. In some respects, protected compositions may include one or more herbicidal active ingredients in addition to (a). In some respects, protected compositions do not include a herbicidal active ingredient in addition to (a). In some respects, protected compositions may exclude one or more herbicidal active ingredients listed above. In some respects, protected compositions may include one or more herbicidal active ingredients in addition to (a), but may exclude one or more herbicidal ingredients listed above. In some respects, protected compositions may include one or more protectants in addition to (b).In some respects, the protected compositions do not include a protectant other than (b). In some respects, the composition may include other components, such as adjuvants, but does not include a herbicidal active ingredient other than (a) or a protectant other than (b). 2. Adjuvants In some respects, the additive includes an agriculturally acceptable adjuvant. Illustrative agriculturally acceptable adjuvants include, but are not limited to, antifreeze agents, antifoaming agents, compatibility agents, sequestering agents, neutralizing agents and buffers, corrosion inhibitors; colorants, oxidizers, carriers, wetting agents, dispersing agents, thickening agents, freezing point depressants, antimicrobial agents, culture oil, adhesives (e.g., for use in seed formulations), surfactants, protective colloids, emulsifiers, tackifiers, and mixtures thereof. Illustrative agriculturally acceptable adjuvants include, but are not limited to, crop oil concentrates (e.g., 85% mineral oil + 15% emulsifiers); nonylphenol ethoxylates; quaternium-3 ammonium salts <ItáIÍIíI’I 25 Page 25 of 67 combinations of petroleum hydrocarbon, alkyl esters, organic acids and anionic surfactants; Cs-Cn alkyl polyglucoside; alcohol phosphate ethoxylates; natural primary alcohol ethoxylate (C^-Cip); di-sec-butylpheni EO-PO block copolymers; polysiloxane-methyl cap; nonylphenol ethoxylate + ammonium urea nitrates; emulsified motylated seed oils; tridecyl alcohol (synthetic) ethoxylates (e.g., 8 EO); tallow amine ethoxylates (e.g., 15 EO); and PEG(400) dioleate-99. Illustrative surfactants (e.g., wetting agents, scaling agents, dispersants, emulsifiers) include, but are not limited to, alkali metal salts, alkaline earth metal salts, and ammonium salts of fatty acids or aromatic sulfonic acids (e.g., lignosulfonic acids, phenolsulfonic acids, naphthalenesulfonic acids).and dibutylnaphthalenesulfonic acid); alkyl and alkyl aryl sultanates; alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates; salts of sulfated hexa-, hepta-, and octadecanols; salts of glycoethers of fatty alcohols, condensates of sulfated naphthalene and their derivatives with formaldehyde; condensates of naphthalene or naphthalene sulfonic acids with phenol and formaldehyde; polyoxyethylene neoctylphenol ether; isooctyl, octylphenol or nonylphenol ethoxylate, alkylphenyl or tributylphenyl polyglycol ether; polyalkylaryl ether alcohols; isotridecyl alcohol; fatty alcohol / ethylene oxide condensates; ethoxylated castor oil; polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers; lauryl alcohol acetate polyglycol ether; sorbitol esters; residual liquids of lignosulfite and proteins; denatured proteins, polysaccharides (e.g., methylcellulose); hydrophobic modified starches; and polyvinyl alcohols, polycarboxylates, palialkoxyates.polyvinylamines, polyethyleneimine, polyvinylpyrrolidone and copolymers of these. Illustrative thickeners include, but are not limited to, polysaccharides (e.g., xanthan gum), inorganic and organic film minerals, and mixtures thereof. Illustrative antifoaming agents include, but are not limited to, silicone emulsions, long-chain alcohols, fatty acids, fatty acid salts, organofluorine compounds, and mixtures thereof. Illustrative antimicrobial agents include, of Page 26 of 67 dichlorophene base and benzyl alcohol hemiformal; isothiazolinone derivatives, such as alkylisothiazoiinones and benzisothiazolinones and mixtures thereof. Illustrative antifreeze agents include, but are not limited to, propylene glycol, ethylene glycol, urea, glycerol, and mixtures thereof. The illustrative colorants include, but are not limited to, the colorants known by the names Rhodamine B, pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1, pigment blue 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48:1, pigment red 57:1, pigment red 53:1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108, and mixtures thereof. The illustrative adhesives include, but are not limited to, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, tylose, and mixtures thereof. 3. Carriers In some respects, the additive includes a carrier. In some respects, the additive includes a liquid or solid carrier. In some respects, the additive includes an organic or inorganic carrier. Illustrative liquid carriers include, but are not limited to: water, petroleum or hydrocarbon fractions such as mineral oil, aromatic solvents, paraffinic oils, and the like; vegetable oils such as soybean oil, rapeseed oil, olive oil, castor oil, sunflower seed oil, coconut oil, corn oil, cottonseed oil, linseed oil, palm oil, peanut oil, safflower oil, sesame oil, tung oil, and the like, esters of the above vegetable oils; esters of monoalcohols or polyalcohols, dihydric, trihydric or other lower (containing 4-6 hydroxy), such as 2-ethylhexyl stearate, n-butyl oleate, isopropyl myristate, propylene glycol dioleate, dioctyl succinate, dibutyl adipate.dioctil ftalato y similares, ésteres de ácidos mono, di y policarboxílicos y similares; tolueno: xileno; nafta de petróleo; aceite de CiWv0Q3Bc&taoa39ttietiP]StiAl®íÉB^I 27. Página 27 de 67 Cyclohexanone; trichloroethylene; ethylene acetate; amyl acetate; butyl acetate; propylene glycol monomethyl ether and diethylene glycol monomethyl ether; methyl alcohol; ethyl alcohol; isopropyl alcohol; amyl alcohol; ethylene glycol; propylene glycol; glycerin; ΔMethyl-2-pyrrolidone; N,N-dimethyl alkylamides; dimethyl sulfoxide; and liquid fertilizers, as well as mixtures thereof. Illustrative solid carriers include, but are not limited to: silica, silica gels, silicates, talc, kaolin, limestone, lime, chalk, log, loess, clay, dolomite, diatomaceous earth.Calcium sulfate, magnesium sulfate, magnesium oxide, synthetic soil materials, pyrophyllite clay, attapulgite clay, kieselguhr, calcium carbonate, bentonite clay, fuller's earth, cotton hulls, wheat flour, soybean flour, pumice stone, wood flour, walnut shell flour, lignin, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, cereal flour, tree bark flour, sawdust and walnut shell feed, cellulose powders and mixtures thereof. B. Physical states In some respects, the formulation of (a) the pyridine carboxylate herbicide or an agriculturally acceptable carboxylate salt or ester thereof and (b) the cloquintocet protectant or an agriculturally acceptable salt or ester thereof may be present in suspended, emulsified, dissolved, or solid form. Illustrative formulations include, but are not limited to, aqueous solutions, aqueous suspensions, aqueous dispersions, aqueous emulsions, aqueous microemulsions, aqueous suspoemulsions, oily solutions, oily suspensions, oily dispersions, oily emulsions, oily microemulsions, oily suspoemulsions, self-emulsifying formulations, pastes, powders, granules, and spreading materials. In some respects, (a) and (b) are aqueous solutions that can be diluted before use. In several respects, (a) and (b) are provided as a strength formulation such as a concentrate. In some respects, concentrates suitable for dilution with water can be prepared, comprising (a), (b), a wetting agent, a tackifier, and a dispersant or emulsifier. In some respects, the concentrate is stable and retains potency during use. Page 28 of 67. In several aspects, the concentrate is a homogeneous, transparent liquid that is stable at temperatures of 54 °C or higher. In some aspects, the concentrate does not exhibit any precipitation of solids at temperatures of -10 °C or higher. In some aspects, the concentrate does not exhibit separation, precipitation, or crystallization of any of the components at low temperatures. For example, the concentrate remains a clear solution at temperatures below 0°C (e.g., below -5°C, below -10°C, below -15°C). In some respects, the concentrate exhibits a viscosity of less than 50 centipoise (50 megapascals), even at temperatures as low as 5°C. In some respects, the concentrate shows no separation, precipitation, or crystallization of any component during storage for a period of 2 weeks or more (e.g., 4 weeks, 6 weeks, 8 weeks, 3 months, 6 months, 9 months, or 12 months or more). In some respects, oil emulsions, pastes, or dispersions can be prepared by homogenizing (a) and (b) in water using a wetting, tackifying, dispersing, or emulsifying agent. In some respects, concentrates suitable for dilution with water can be prepared, comprising (a), (b), a wetting agent, a tackifying agent, and a dispersing or emulsifying agent. In some respects, powders, spreading materials or dusts can be prepared by concomitantly mixing or grinding {a) and (b) and optionally other additives with a solid carrier. In some respects, granules (e.g., coated granules, impregnated granules, and homogeneous granules) can be prepared by combining (a) and (b) with solid carriers. In some formulations, the formulations comprise 1% to 99% of (a) and 1% to 99% of (b) (e.g., 95% (a) and 5% (b); 70% (a) and 30% (b); or 30% (a) and 70% (b)) by total weight of (a) and (b). In formulations designed for use as concentrates, the total amount of (a) and (b) may be present at a concentration of approximately 0.1% to approximately 98% by weight (% wt), depending on the total weight of the formulation. For example, the Page 29 of 67 be present in a concentration as low as approximately 1% by weight, approximately 2.5% by weight, approximately 5% by weight, approximately 7.5% by weight, approximately 10% by weight, approximately 15% by weight, approximately 20% by weight, approximately 25% by weight, approximately 30% by weight, approximately 35% by weight, approximately 40% by weight, approximately 45% by weight, as high as approximately 50% by weight, approximately 55% by weight, approximately 60% by weight, approximately 65% ​​by weight, approximately 70% by weight, approximately 75% by weight, approximately 80% by weight, approximately 85% by weight, approximately 90% by weight, approximately 95% by weight, approximately 97% by weight, or within any defined interval between any two of the above values, such as from approximately 1% by weight to approximately 97% by weight, from approximately 10% by weight to approximately 90% by weight,between approximately 20% by weight to approximately 45% by weight, and approximately 25% by weight to approximately 50% by weight, depending on the total weight of the formulation. Concentrates may be diluted with an inert carrier, such as water, prior to application. Diluted formulations applied to unwanted vegetation or the locus of unwanted vegetation may contain from 0.0006 to 8.0 percent by weight of the total amount of (a) and (b) (e.g., from 0.001 to 5.0 percent by weight), depending on the total weight of the diluted formulation. C. Packaging In some respects, the formulation may be in the form of a single-package formulation that includes both: (a) the herbicide pyridine carboxylate or an agriculturally acceptable dioxide, salt, or ester thereof; and (b) the protectant cloquintocet or an agriculturally acceptable salt or ester thereof. In some respects, the formulation may be in the form of a single-package formulation that includes (a) and (b) and further includes at least one additive. In some respects, the formulation may be in the form of a formulation in Page 30 of 67 A two-package formulation, wherein one package contains (a) and optionally at least one additive, while the other package contains (b) and optionally at least one additive. In some aspects of the two-package formulation, the formulation including (a) and optionally at least one additive, and the formulation including (b) and optionally at least one additive, are mixed prior to application and then applied simultaneously. In some aspects, the mixing is done as a tank mix (e.g., the formulations are mixed immediately before or after dilution with water). In some aspects, the formulation including (a) and the formulation including (b) are not mixed but are applied sequentially (successively), for example, immediately or within 1 hour, within 2 hours, within 4 hours, within 8 hours, within 16 hours, within 24 hours, within 2 days, or within 3 days of each other. VI. Methods of use The compositions described herein can be applied using any known herbicide application technique. Illustrative application techniques include, but are not limited to, spraying, atomizing, dusting, spreading, or direct application in water. The application method may vary depending on the intended purpose. In some respects, the application method may be chosen to ensure the best possible distribution of the compositions described herein. In some respects, a method for controlling unwanted vegetation comprising bringing the vegetation or its locus into contact with, or applying it to, soil or water to prevent the emergence or growth of vegetation of any of the compositions described herein. The compositions described herein can be applied pre-emergence (before the emergence of unwanted vegetation) or post-emergence (e.g., during or after the emergence of unwanted vegetation). In some respects, the composition is applied post-emergence of unwanted vegetation. In some respects, the herbicide FdBD2weí®ó^oi4Sip <IflÁKBí^WI 31 Page 31 of 67 The cloquintocet protectant is applied simultaneously. In some respects, the pyridine carboxylate herbicide and the cloquintocet protectant are applied sequentially, for example, immediately or with a minimal delay, within approximately 10 minutes, approximately 20 minutes, approximately 30 minutes, approximately 40 minutes, approximately 1 hour, approximately 2 hours, approximately 4 hours, approximately 8 hours, approximately 16 hours, approximately 24 hours, approximately 2 days, or approximately 3 days of each other. In some respects, the pyridine carboxylate herbicide can be applied pre- or post-emergence to the unwanted vegetation, and the cloquintocet protectant can be applied as a seed treatment to the crop seeds.When applied as a seed treatment, cloquintocet protectant is applied at a rate of 0.01 to 10 g ai of protectant per kg (g ai / kg) of crop seed, preferably 0.05 to 1 g ai / kg of crop seed, and in particular, 0.1 to 0.5 g ai / kg of crop seed. If protectant solutions are used to treat seeds, the concentration of the protectant in the solution is, for example, 1 to 10,000 ppm, preferably 100 to 1,000 ppm, depending on the weight. When the compositions are used in crops, they can be applied after sowing and before or after crop emergence. In some respects, the compositions described herein show good crop tolerance even after crop emergence and can be applied during or after crop emergence.In some aspects, when the compositions are used in crops, the compositions can be applied before sowing the crop plants. In some respects, the compositions described herein are applied to vegetation or an area adjacent to vegetation, or are applied to soil or water to prevent the emergence or growth of vegetation by spraying (e.g., foliar spraying). In some respects, spraying techniques use, for example, Page 32 of 67 Spray volume dosages range from 2 liters per hectare (L / ha) to 2000 L / ha (e.g., 10-1000 L / ha or 50-500 L / ha). In some aspects, the compositions described herein are applied by low-volume or ultra-low-volume methods, where the application is in the form of microgranules. In some aspects, where the compositions described herein are less tolerated by certain crop plants, the compositions may be applied using spraying devices in such a way that they make little contact, if any, with the leaves of the sensitive crop plants while reaching the leaves of unwanted vegetation growing below or on the bare soil (e.g., post-directed or dormant). In some aspects, the compositions described herein may be applied as dry formulations (e.g., granules, powders, or fine powders). In some cases where unwanted vegetation is treated after emergence, the compositions described herein are applied via foliar application. In other cases, herbicidal activity is exhibited by the compounds in the mixture when applied directly to the plant or to the plant site at any stage of growth or prior to planting or emergence. The observed effect may depend on the type of unwanted vegetation being controlled, the growth stage of the unwanted vegetation, the application parameters (dilution and spray droplet size), the particle size of the solid components, the environmental conditions at the time of use, the specific compound used, the specific adjuvants and carriers used, the soil type, and similar factors, as well as the amount of chemical applied.In some respects, these and other factors can be adjusted to promote non-selective or selective herbicidal action. The compositions and methods described herein can be used to control unwanted vegetation in a variety of applications. These compositions and methods can be used to control unwanted vegetation in areas including, but not limited to, farms, lawns, pastures, rangelands, meadows, grasslands, rights-of-way, aquatic environments, and trees. Page 33 of 67 Wild or grassland areas. In some respects, unwanted vegetation can be controlled in row crops. Illustrative crops include, but are not limited to, wheat, barley, triticale, rye, teff, oats, corn, cotton, soybeans, sorghum, rice, millet, sugarcane, and pastures (e.g., grasslands). In some respects, the compositions and methods described herein can be used to control unwanted vegetation in corn, wheat, barley, rice, sorghum, millet, or oats, or combinations thereof. In some respects, the compositions and methods described herein can be used to control unwanted vegetation in broadleaf crops. In some respects, the compositions and methods described herein can be used to control unwanted vegetation in canola, flax, sunflower, soybeans, or cotton. In some respects, the compositions and methods described herein can be used in industrial vegetation management (IVM).(by its acronym in English) or for utility, pipeline, roadway, and railroad right-of-way applications. In some respects, the compositions and methods described herein may also be used in forestry (e.g., for site preparation or to control unwanted vegetation in plantation forests). In some respects, the compositions and methods described herein may be used to control unwanted vegetation on Conservation Reserve Program (CRP) lands, trees, vines, prairies, and grasses grown for seed. In some respects, the compositions and methods described herein may be used in gardens (e.g., residential, industrial, and institutional), golf courses, parks, cemeteries, sports fields, and turf. The compositions and methods described herein can also be used in crop plants that are resistant to, for example, herbicides, pathogens, or insects. In some respects, the compositions and methods described herein can be used in crop plants that are resistant to one or more herbicides due to genetic engineering or seeding. In some respects, the compositions and methods described herein can be used in crop plants that are resistant to one or more herbicides due to genetic engineering or seeding. Page 34 of 67 such as plant pathogenic fungi due to genetic engineering or seeding. In some respects, the compositions and methods described herein may be used in crop plants that are resistant to insect attack due to genetic engineering or seeding. Illustrative resistant crops include, but are not limited to, crops that are resistant to photosystem II inhibitors or crop plants that, due to the introduction of the gene for Bacillus thuringiensis (or Bf) toxin by genetic modification, are resistant to attack by certain insects. In some respects, the compositions and methods described herein may be used in conjunction with glyphosate, glufosinate, drcamba, phenoxy auxins, etc.Pyridyloxy auxins, aryloxyphenoxypropionates, acetyl CoA carboxylase (ACCase) inhibitors, imidazolinones, acetolactate synthase (ALS) inhibitors, 4-hydroxyphenylpinjate dioxygenase (HPPD) inhibitors, protoporphyrinogen oxidase (PPO) inhibitors, triazines, and bromoxynil are used to control weeds in crops tolerant to glyphosate, glufosinate, dicamba, phenoxy auxins, pyridyloxy auxins, aryloxyphenoxypropionates, ACCase inhibitors, imidazolinones, ALS inhibitors, HPPD inhibitors, PPO inhibitors, triazines, bromoxynil, or combinations thereof. In some respects, unwanted vegetation is controlled in crops tolerant to glyphosate, glufosinate, dicamba, and phenoxy auxins.Pyridyloxy auxins, aryloxyphenoxypropionates, ACCase inhibitors, ALS inhibitors, HPPD inhibitors, PPO inhibitors, triazines, and bromoxynil have unique, multiple, or stacked traits that confer tolerance to single or multiple chemical compositions or multiple modes of action. In some respects, unwanted vegetation can be controlled in a crop that is ACCase-tolerant, ALS-tolerant, or a combination of these. The combination of (a) and (b) can be used in combination with one or more herbicides selected for the crop being treated and that complement the spectrum of weeds controlled by these compounds at the application rate employed. In some respects, the compositions described herein and other complementary herbicides are applied simultaneously, either as a combination formulation, as a tank mix, or in sequential applications. Page 35 of 67 methods can be used to control unwanted vegetation in crops that possess agronomic stress tolerance (including, but not limited to, drought, cold, heat, salt, water, nutrients, fertility, and pH), pest tolerance (including, but not limited to, insects, fungi, and pathogens), and crop improvement traits (including, but not limited to, yield; protein, carbohydrate, or oil content; protein, carbohydrate, or oil composition; plant height; and plant architecture). In some respects, the compositions described herein may be used to control unwanted vegetation, including, but not limited to, Polygonum species, Amaranthus species, Chenopodium species, Sida species, Ambrosia species, Cyperus species, Setaria species, Sorghum species, Acantbospermum species, Anthemus species, Atriplex species, Brassica species, Cirsium species, Convolvulus species, Conyza species, Cassia species, Commelina species, Datura species, Euphorbia species, Geranium species, Galinsoga species, Ipomoea species, Lamium species, Lolium species, Malva species, Matricaria species, Prosopis species, Rumex species, Sisymbrium species, Soianum species, and Trifolium species. species Xanthium, species Veronica, and species Viola.In some respects, the undesirable 20 vegetation includes common alside (Stellarla media), Chinese jute (Abutillon theophrastl), hemp sesbania (Sesbanfe exaitata Gory), Anoda cristata, Bidens pilosa. Brassica have, shepherd's bag (Capsella bursa-pastoris). acyan (Centaurea cyanus or Cyanus segetum), bastard hemp (Galeopsls tetrahit). horticultural love (Galium apanine), common sunflower (Hetianthus annuus), Desmodium tortuosum, Italian ballioo (Lolium 25 multifiorum). kochia (Kochla scopana), Medicago arabica, Mercurialis annua, Myosotis arven sis, common poppy (Papaver rhoeas), Raphanus raphanistrum, broadleaf dock (Rumex obtusifolius), Russian thistle (Salsola kali), wild mustard (Sinapis arven sis). Sonchus arvensis, Arven in the moon. Tagetes. Page 36 of 67 Piantago major, Piantago lanceotata, bird's-eye speedwell (Veronica persica), bledo (Amaranthus re tro flex us), rapeseed (Brassica napus), cenizo (Chenopodium album), cardo canadienses (Cirsium arvense), chufa (Cyperus escufentus), poinsettia (Euphorbia heterophylla).spiny lettuce (Lactuca semola), red nettle (Lamium purpureum), wild chamomile (Matricaria chamomilla), odorless chamomile (Matricaria inodora), field chamomile (Anthemis arvensis), common buckwheat (Fagopyrum esculentum), wild buckwheat (Polygonum convolves), giant foxtail (Setaria faberi), green foxtail (Setaria viridis), common sorghum (Sorghum vulgare), wild pansy (Viola tricolor), blackgrass (Alopecuros myosuroides), wild oat (Avena fatua), dew guard (Digitaria sangeinalis), barnyardgrass (Echinochloa crus-galli), Canadian butcher's weed (Erigeron canadensis), volunteer soybean (Glycine max), ivyleaf morning glory (Ipomoea hederacea), morning glory ivy (Leptochloa chinensis), and Johnson grass (SQRHA, Sorghum hatepense). or combinations of these. The compositions described herein can be used to control herbicide-tolerant or resistant weeds. The methods employing the compositions described herein can also be used to control herbicide-tolerant or resistant weeds. Illustrative tolerant or resistant weeds include, but are not limited to, biotypes resistant or tolerant to acetolactate synthase (ALS) or acetohydroxy acid synthase (AHAS) inhibitors (e.g., imidazolinones, sulfonylureas, pyrimidinylthiobenzoates, triazopyrimidines, sulfonylaminocarbonyl-triazolinones), photosystem II inhibitors (e.g., phenylcarbamates, pyridazinones, triazines, triazinones, uracils, amides, ureas, benzothiadiazines, nitriles, phenylpyridazines), acetyl CoA carboxylase (ACCase) inhibitors (e.g., aryloxyphenoxypropionates, cyclohexanediones, phenylpyrazolines), and synthetic auxins (e.g.,benzoic acids, phenoxycarboxylic acids, pyridine carboxylates, quinoline carboxylic acids), auxin transport inhibitors (e.g., phthalates, semicarbazones), photosystem I inhibitors (e.g., bipyridyls), 5-enolpyruvylshikimate-3'fosfytQO2((&6>^0^3®Ínía5é-AípP#Bf.PI 37. Page 37 of 67 glyphosate), glutamine synthetase inhibitors (e.g., glyphosate, biafos), microtubule assembly inhibitors (e.g., benzamides, benzoic acids, dinitroanilines, phosphoramidates, pyridines), mitosis inhibitors (e.g., carbamates), very long-chain fatty acid (VLCFA) inhibitors (e.g., acetamides, chloroacetamides, oxyacetamides, tetrazolinones), lipid and fatty acid synthesis inhibitors (e.g., phosphorodithioates, thiocarbamates, benzofurans, otocarbamic acids), protoporphine oxidase (PPO) inhibitors (e.g., diphenyl ethers, N-phenylphthalimides, oxadiazoles, oxazolidinediones, phenylpyrazoles, pyrimidinidiones, thiadiazolones, triazolinones), carotenoid biosynthesis inhibitors (e.g., clomazon, amitrol, aclonifen), phytoene desaturase (PDS) inhibitors (e.g., amides, anilidex, furanones, phenoxybutanamides, pyridiazinones, pyridines), 44-didroxyphenoxy-pyruvate-dioxygenase (HPPD) inhibitors (e.g.Illustrative tolerant or resistant weeds include, but are not limited to, biotypes with resistance or tolerance to multiple herbicides, biotypes with resistance or tolerance to multiple chemical classes, biotypes with resistance or tolerance to multiple herbicide modes of action, and biotypes with multiple tolerance or resistance mechanisms (e.g., targeted resistance or metabolic resistance). Examples of herbicides that may exhibit tolerant or resistant behavior include, but are not limited to, biotypes with resistance or tolerance to multiple herbicides, biotypes with resistance or tolerance to multiple chemical classes, biotypes with resistance or tolerance to multiple herbicide modes of action, and biotypes with multiple tolerance or resistance mechanisms (e.g., targeted resistance or metabolic resistance). For illustrative purposes only, the following are examples of certain aspects of this disclosure. Parts and percentages are by weight unless otherwise stated. Examples Greenhouse trials - Methodology - Evaluation of herbicide protection after emergence in crops Seeds of the test plant species Head3Oe0172ü®(MeAelIá-d^D©WI were planted Page 38 of 67 % v / v (volume / volume) of PRO-MIX® BX planting mix (Premier Tech Horticulture, Quakertown, PA, USA) and PROFILE® GREENS GRADE™ (Profile Products LLC, Buffalo Grove, IL, USA), which typically has a pH of 5.2 to 6.2 and an organic matter content of at least 50 percent, in plastic pots with a surface area of ​​103.2 square centimeters (cm2). When necessary to ensure good germination and healthy plants, fungicide and / or other chemical or physical treatment was applied. The plants were grown for 7–36 days (d) in a greenhouse with a photoperiod of approximately 14 hours (h) maintained at approximately 23°C during the day and 22°C at night. Nutrients and water were added regularly, and supplemental lighting was provided from above with 1000-watt metal halide lamps as needed. The plants were used for testing when they reached the second or third true leaf stage.Emulsifiable concentrates of each pyridine carboxylate herbicide (Compound A or Compound B) were prepared at 100 grams of acid equivalent per liter (g ae / l). An aliquot of each emulsifiable concentrate was placed in a 25 ml glass vial and diluted with an aqueous mixture of 1.25% (v / v) esterified rapeseed oil ACTIROB® B (Bayer Crop Science, Research Triangle Park, NC, USA) or MSO® Concentrate with soybean oil met I a do Le ci-Tech® (Loveland Products, Loveland, CO, USA) to obtain concentrated stock solutions at the highest application rate for each herbicide, based on an application volume of 12 milliliters (ml) at a rate of 187 liters per hectare (L / ha). The concentrated stock solutions were diluted additionally with an aqueous mixture of 1.25% v / v of ACTIROB® B Concentrate or MSO® with LECI-TECH® to obtain stock solutions at reduced application rates for each herbicide.Spray solutions of two herbicide combinations (Compound A or Compound B plus protectant) were prepared by adding weighted amounts or aliquots of the protectant to stock solutions of Compound A or Compound B to form 12 ml spray solutions in bidirectional combinations. IF-2020-07208301-APN-ANP#INPI. Page 39 of 67 Spray solutions were applied to plant material using a Mandel trail overhead sprayer equipped with 8002E nozzles calibrated to deliver 187 L / ha over an application area of ​​0.503 square meters (m2) at a spray height of 18 inches (43 centimeters (cm)) above the average plant canopy. Control plants were similarly sprayed with the solvent blank. All herbicide (component a) application rates are given as “gae / ha” and all protectant (component b) application rates are given as “gai / ha”. The treated and control plants were placed in a greenhouse, as described above, and irrigated by subirrigation to avoid washing off the test compounds. After 20–22 days, the condition of the test plants was visually assessed relative to that of the control plants and scored on a scale of 0 to 100 percent, where 0 corresponds to no damage and 100 corresponds to total death. Details of the protected compositions and crops analyzed are specified in the following examples. Example 1 A protected composition comprising cloquintocet acid (CQC-a) and compound A was evaluated in spring wheat (TRZAS), winter wheat (TRZAW), durum wheat (TRZDU), spring barley (HORVS), winter barley (HORVW), and common oats (AVESA), and the phytotoxicity of the protected composition was measured in each crop. In addition, the efficacy of the protected compositions was measured against unwanted vegetation, including field chamomile (ANTAR, Anthemis atvensis), winter rapeseed (BRSNW, Brassica napas), false chamomile (MATIN, Matricaria inodora), and wild mustard (SINAR, Sinapis arvensis). The results are summarized in Tables 1-4 below. Table 1. Safety of effects (% of visual damage) Nil Page 40 of 67 and Compound A in grain crops. Application dose tgiha) Compound A 40 0 ​​40 CQC-a 0 40 i 40 Herbicide Re (ation: Protector 1:1 TRZAS Ob 45 0 0 Ex — 45 Δ -45 TRZAW Oh 35 : 0 5 Ex — 35 Δ 0 0 -30 TRZDU Ob 45 0 0 Ex — 45 Δ '45 HOftVS Ob 20 0 5 Ex — 20 Δ -15 HORVW Ob 40 0 ​​10 Ex — 40 -1Ó“ Δ AVESA Ob 0 0 0 Ex “ — 0 Δ 0 g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) TRZAW = Triticum aestivum (winter wheat) TRZDU = Triticum aestivum (durum wheat) HCRVS = Hordeum vulgare (spring barley) HORVW = Hordeum vulgare (winter barley) AVESA = Avena sativa (common oats) IF-2020-07208301-APN-ANP#INPI Page 41 of 67 Table 2. Safety of the effects {% of visual damage} of cloquintocet-acid (CQC-a) and Compound A on grain and weed crops. Application rate (g / ha) Compound A 40 0 ​​0 I 0 0 40 40 40 40 CQC-a 0 10 20 40 80 10 20 40 80 Herbicide: Protectant Ratio 4:1 2:1 1:1 1:2 TRZAS Ob 40 0 ​​0 0 0 0 0 0 0 Ex — — — — — 40 40 40 40 Δ -40 -40 -40 -40 TRZAW Ob 35 0 0 0 0 0 0 0 0 Ex — — — 35 35 35 35 Δ -35 -35 -35 -35 HORVS Ob 40 0 ​​0 0 0 10 10 0 0 Ex — — — 40 40 40 40 Δ -30 -30 -40 -40 HORVW Ob 3 0 0 0 0 0 5 0 0 0 Ex — — — 30 30 30 30 Δ -25 -30 -30 -30 MATIN Ob 100 0 0 0 0 97 99 99 97 Ex - — — - 100 100 100 too Δ -3 -2 -2 -3 SINAR Ob 99 0 to 0 0 100 99 97 100 Ex - — - — 99 99 99 99 Δ I 2 0 -2 2 g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) TRZAW = Triticum aestivum (winter wheat) HORVS = Hordeum vulgar# (spring barley) HORVW = Hordeum vulgare# (winter barley) IF-2020-07208301-APN-ANP#INPI Page 42 of 67 MATIN = Odorless Matricaria (false chamomile) SINAR - Sinapis arvensís (wild mustard) Table 3. Safety of the effects (% of visual damage) of cloquintocet-acid (CQC-a) and Compound A on grain crops. Application Rate (g / ha) Compound A 40 0 ​​0 0 0 40 40 40 40 CQC-a 0 20 40 30 120 20 40 B0 120 Herbicide:Protectant Ratio 2:1 1:1 1:2 1:3 TRZAS Ob 23 0 0 0 0 0 0 0 0 Ex — — — — 23 23 23 23 Δ -23 -23 -23 -23 TRZAW Ob 25 0 0 0 0 3 3 2 0 Ex -- — — — 25 25 25 25 Δ Ί -22 -22 -23 -25 HORVS Ob 17 0 0 0 0 0 0 0 0 Ex — — - 17 17 17 17 Δ -17 17 -17 I -17 g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) TRZAW = Triticum aestivum (winter wheat) HORVS = Hordeum vulgare (spring barley) Table 4. Safety of the effects (% of visual damage) of cloquintocet-acid (CQC-a) and Compound A on grain and weed crops. Application dose (g / ha) Compound A 20 0 0 0 0 20 Π20 20 20 CQC-a 0 5 10 20 40 —tP-20 5 20-072( 10 9901-A 20 .PN-AN 40 -P#INPI Page 43 of 67 Herbicide Ratio: Protector 4:1 2:1 1:1 1:2 TRZAS Ob 15 0 0 0 0 D 0 0 0 Ex — -- — — — 15 15 15 15 Δ -15 -15 -15 -15 TRZAW Ob 20 0 0 0 7 — 7 — 0 — 7 20 20 20 Δ -15 -13 -13 -20 HORVS Ob 20 0 0 0 0 10 0 0 0 Ex -- — — — 20 20 20 2D Δ -10 -20 -20 -20 HORVW Ob 15 0 0 0 0 0 -0 - 15 — 15 — 15 — 15 Δ -15 -15 -15 -15 ANTAR Oh 95 0 F o 0 0 90 95 100 80 Ex — — — — 95 95 95 95~ Δ -5 0 0 5 -15 BRSNW Ob 70 0 0 0 0 70 70 35 - Ex 35 — 75 — 70 —7 70 70 Δ 0 5 15 15 g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) TRZAW = Triticum aeslivum (winter wheat} HQRVS = Hordeum vuigare (spring barley) HCRVW = Hordeum vuígare (winter barley) ANTAR = Anthemis an / ensis (field chamomile) BRSNW = Brass / ca napas (winter rapeseed) Example 2 A protected composition comprising Page 44 of 67 (CQC-DMA) and Compound A were applied to spring barley (HORVS), winter wheat (TRZAW), winter barley (HQRVW), spring wheat (TRZAS), durum wheat (TRZDU), and common oats (A VES A), and the phytotoxicity of the protected composition was measured in each crop. In addition, the efficacy of the protected compositions against unwanted vegetation, including wild chamomile (MATCH, Matricaria manzanilla), Russian thistle (SASKR, Salsola kali), and winter rapeseed (BRSNW, Brass / ca napas), was measured. The results are summarized in Tables 5-6 below. Table 5. Safety of the effects (% of visual damage) of cloquintocetdimethylammonium salt (CQC-DMA) and Compound A on grain crops. Application rate (g / ha) Compound A 40 0 ​​40 40 N-ANP#INPI CQC-DMA 0 1 40 Herbicide: Protector Ratio 1:1 HORVS Ob 20 0 0 Ex - - 20 Δ -20 TRZAW Ob 35 0 5 Ex ·- 35 -30 Δ 0 0 HORVW Ob 40 0 10 Ex — — 40 - -3O— Δ TRZAS Ob 45 0 0 Ex — 45 Δ -45 TRZDU Ob 45 D 0 Ex — - 45 Δ 1 -45 11-2020-0720 U01-AP Page 45 of 67 Oh 0 0 ; 0 AVESA Ex — 0 Δ 0 g / ha = grams per hectare HORVS = Hordeum vuigare (spring barley) TRZAW = Triticum aestivum (winter wheat) HORVW = Hordeum vuigare (winter barley) TRZAS = Triticum aestivum (spring wheat) TRZDU = Triticum aestivum (durum wheat) AVESA = Avena sativa (common oats) Table 6. Safety of the effects (% of visual damage) of cloquintocet10 dimethylammonium salt (CQC-DMA) and Compound A on grain and weed crops. Application dose (gitia) Compound A 20 0 0 0 20 20 20 CQC-DMA 0 10 20 40 10 20 1 40 Herbicide Ratio: Protectant 2:1 1:1 1:2 HORVS Ob 0 0 0 0 0 0 — 0 0 — 0 0 Δ 0 TRZAS Ob 25 0 0 0 0 0 Ex — — - 25 25 25 Δ -25 -25 -25 MATCH Oh 50 0 0 0 65 50 Ex — — 50 50 Δ 15 0 SASKR Ob eo 0 0 0 eo 60 Ex - 0 Γ — 60 Γ BRSNW Ob . 95 or 0 0 100 95 IF-2020-072083 01 -APN -AN P#1N Pí Page 46 of 67 Ex — — -- ! 95 95 Δ I 5 a g / ha = grams per hectare HORVS - Hordeum vulgare (spring barley) TRZAS = Triticum aestivum (spring wheat) MATCH =· Chamomile matrix (wild chamomile) SASKR = Salsola kali (cardo ruso) BRSNW = Brass / ca ñapos (winter rape) Example 3 A protected composition comprising cloquintocet-triethylamine salt 10 (CQC-TEA) and Compound A was evaluated on spring barley (HORVS), winter barley (HORVW), spring wheat (TRZAS), winter wheat (TRZAW), durum wheat (TRZDU), and common oats (AVESA), and the phytotoxicity of the protected composition was measured in each crop. In addition, the efficacy of the protected compositions against unwanted vegetation, including wild chamomile (MATCH, Matricaria manzanilla), Russian thistle (SASKR, Salsola kall), and winter rapeseed (BRSNW, Brassica napus), was measured. The results are summarized in Tables 7-8 below. Table 7. Safety of the effects (% of visual damage) of cloquintocettriethylamine salt (CQC-TEA) and Compound A on grain crops. Application rate (g / ha) Compound A 40 I 0 40 COC-TEA 0 40 40 Herbicide: Protectant ratio 1:1 HORVS Ob 20 D 3 Ex — — 20 Δ -10 HORVW Ob 40 0 ​​5 Ex IF-202C -07208; 40 01-APF -ANP#INPI Page 47 of 67 Δ a 0 -35 Ob 45 0 0 TRZAS Ex — — 45 Δ -45 Ob 35 0 10 TRZAW Ex — 35 Δ -25 Ob 45 0 0 TRZDU Ex — — 45 Δ -45 Ob 0 0 0 AVESA Ex — - 0 Δ 0 g / ha = grams per hectare HORVS = Hordeum vulgare (spring barley) HQRWV = Hordeum vulgaro (winter barley) TRZAS - Triticum aestivum (spring wheat) TRZAW = Triticum aestivum (winter wheat) TRZDU = Triticum aestivum (durum wheat) AVESA = Avena sativa (common oats) Table 8. Safety of the effects (% of visual damage) of cloquintocet10 triethylamine sat {CQC-TEA} and Compound A on grain and weed crops. Application dose (g / ha) Compuesla A 20 0 0 0 20 20 20 CQC-TEA 0 10 20 40 10 20 40 Herbicide-Protector Ratio 2:1 1:1 1:2 HORVS Ob Γ 0 to 0 to 0 0 0 Ex — — — — 0 0 0 Δ 0 | 0 0 IF-2020-07208301-APN-ANP#INPI Page 48 of 67 TRZAS Ob 25 0 0 0 0 0 0 Ex — — — 25 25 25 Δ -25 -25 -25 MATCH Ob 50 0 0 0 65 60 Ex — — 50 50 Δ 15 10 SASKR Ob 60 0 0 0 60 60 Ex — — - 60 60 Δ D 0 BRSNW Ob 95 0 0 0 B0 90 96 Ex — — — — 95 Δ -15 -5 g / ha = grams per hectare HORVS = Hordeum vulgar# (spring barley) TRZAS = Triticum aestivum (spring wheat) MATCH = Matricaria chamomile (wild chamomile) SASKR = Sa / so / a kali (Russian thistle) BRSNW = Brassica napus (winter rape) Example 4 A protected composition comprising cloquintocet-triethylamine salt (CQC-TEA) and Compound B was evaluated in spring barley (HORVS), winter barley (HORVW), spring wheat (TRZAS), winter wheat (TRZAW), durum wheat (TRZDU), and common oats (AVESA), and the phytotoxicity of the protected composition was measured in each crop. The results are summarized in Table 9 below. Table 9. Safety of the effects (% of visual damage) of cloquintocettriethylamine salt (CQC-TEA) and Compound B on grain crops. IF-2020-07208301-APN-ANP#INPI Page 49 of 67 Application rate (g / ha) Compound β 40 0 ​​40 CQC-TEA 0 40 40 Herbicide Ratio: Protector 1:1 HORVS Ob 25 0 8 Ex — -- 25 Δ -13 HORVW Ob 38 Γ o 6 Ex — — 38 Δ 0 0 -30 TRZAS Ob 48 0 5 48— Ex Δ -43 TRZAW Ob 50 0 13 Ex — — 50 Δ -38 TRZDU Ob 40 0 ​​0 Ex — 40 Δ -40 AVESA Ob 0 0 0 Ex — 0 Δ 0 g / ha = grams per hectare HORVS = Hordeum vulgare (spring barley) HORVW = Hordeum vulgare (winter barley) TRZAS = Tnticum aestivum (spring wheat) TRZAW = Triticum aestivum (winter wheat) TRZDU = Triticum aestivum (durum wheat) AVESA = Averia sativa (common oats) Example 5 A proleg.da composition was evaluated that Page 50 of 67 Triisopropanolamine (CQC-TIPA) and Compound A were applied to spring barley (HORVS) and spring wheat (TRZAS), and the phytotoxicity of the protected composition was measured in each crop. In addition, the efficacy of the protected compositions against unwanted vegetation, including wild chamomile (MATCH, Matricaria manzanilla), Russian thistle (SASKR, Sa / sofá kali), and winter rapeseed (BRSNW, Brassica napus), was measured. The results are summarized in Table 10 below. Table 10. Safety of the effects (% of visual damage) of cloquintocettriisopropanolamine salt (CQC-TIPA) and Compound A on grain and weed crops. Application Rate (g / l·a) Compound A 20 0 0 0 20 20 | 20 CQC-TIPA 0 10 20 40 10 20 i 40 Herbicide:Protector Ratio 2:1 1:1 1:2 HORVS Ob 0 0 0 0 0 0 0 Ex — 0 0 0 Δ 0 0 0 TRZAS Ob 1 25 0 0 0 0 0 0 Ex — — 25 25 25 Δ -25 -25 -25 MATCH Ob 50 0 0 0 50 ' 60 Ex — — — 50 50 Δ 0 10 SASKR Ob 60 0 0 0 60 60 Ex — — — — 60 60 Δ 0 0 BRSNW Ob 35 0 0 0 _ 90 95 Ex — - - 95 95 Δ _j_o -5 0 g / ha = grams per hectare HORVS = Hordeum vuigare (spring barley) IF-2020-07208301-APN-ANP#INPI Page 51 of 67 TRZAS = Triticum aestivum (spring wheat) MATCH = Matricaria chamomitla (wild chamomile) SASKR = Sa / so / a kali (Russian thistle) BRSNW = Brass / ca napus (winter rape) Example 6 A protected composition comprising cloquintocet-methyl salt (CQCmethyl) and Compound A was evaluated in spring barley (HORVS) and spring wheat (TRZAS), and the phytotoxicity of the protected composition was measured in each crop. In addition, the efficacy of the protected compositions against unwanted vegetation, including wild chamomile (Matricaria manzanilla), Russian thistle (Saskar), and winter rapeseed (Brassica napus), was measured. The results are summarized in Table 11 below. Table 11. Safety of the effects (% of visual damage) of cloquintocet-methyl (CQCmethyl) and Compound A on grain and weed crops. Application rate (g / ha) Corrí puesto A 20 0 0 0 20 20 20 CQC-metito 0 10 20 40 10 20 40 Herbicide: Protectant Ratio 2:1 1:1 1:2 Ob 0 0 0 0 0 0 0 HORVS Ex — — - - 0 0 0 ώ 0 0 0 TRZAS Ob 25 0 0 (1 0 0 0 Ex — — — 25 25 25“ Δ -25 -25 -25 MATCH Ob 50 0 0 0 65 40 Ex — - 50 50 Δ 15 -10 1F-2020-072083 01 -APN -AN P#1N P1 Page 52 of 67 Ob so 0 0 0 eo 50 SASKR Ex — — — — 60 60 ú 0 -10 Ob 95 0 0 0 85 80 BRSNW Ex — — — 95 95 Δ -10 -15 g / ha = gramos por hectárea HORVS = Hordeum vulgare {spring cebada) TRZAS = Tfilicum aestivum (spring trigo) MATCH = Matricaria chamomitla (Sylvatic manzanilla) SASKR = Salsola kali (ruso thistle) BRSNW = Brassrca napas (winter rapeseed) Example 7 A protected composition comprising cloquintocet-mexyl salt (CQCmexyl) and Compound B was evaluated on spring barley (HORVS), winter barley (HORVW), spring wheat (TRZAS), winter wheat (TRZAW), durum wheat (TRZDU), and common oats (AVESA), and the phytotoxicity of the protected composition was measured in each crop. In addition, the efficacy of the protected compositions was measured on unwanted vegetation, including winter rapeseed (BRSNW, Firass / ca Napas), common buckwheat (FAGO, Fagopyrum esculentum), wild buckwheat (POLCO, Polygonum convulvus), Russian thistle (SASKR, Salsola kail), and wild mustard (SINAR, S / nap / s arvensis). The results are summarized in Tables 12-13 below. Table 12. Safety of the effects (7° of visual damage) of cloquintocet-mexyl (CQCmexyl) and Compound B on grain crops. Application dose (g / ha) Compound B 40 0 ​​40 CQC-mexyl Γ 0 40 40 IF-2020-07208301-APN-ANP#INPI Page 53 of 67 Herbicide Ratio: Protector 1:1 Ob 25 0 13 HORVS Ex 1- 25 Δ -12 Ob 30 0 13 HORVW Ex — 38 Δ D 0 -25 Ob 48 0 0 TRZAS Ex — - 40 Δ -40 Ob 50 0 10 TRZAW Ex — 50 Δ -40 Ob 40 0 0 TRZDU Ex - — 40 Δ -40 Ob 0 □ 0 AVESA Ex - - 0 Δ 0 g / ha = grams per hectare HORVS = Hordeum vuigare (spring barley} HORVW = Hordeum vuigare (winter barley) TRZAS = Tñticum aestivum (spring wheat) TRZAW = Thticum aestivum (winter wheat) TRZDU = Triticum aestivum (durum wheat) AVESA = Avena sativa (common oats) Table 13. Safety of the effects (% of visual damage) of cloquintocet-mexyl {CQC10 mexyl} and Compound B on grain and weed crops. Compound B Dosage ' 20 | 0 I 0 0 0 20 20 - ------------L ______________ ___|___._______ _________________ 20 20 IF-2020-07208301 -APN-ANP#1NPÍ Page 54 of 67 application (gtoa) CQC-in axilla 0 5 10 20 40 5 10 20 40 Herbicide Relationship; Protector 4:1 2:1 1:1 1:2 TRZAS Ob 28 0 0 0 0 20 15 10 0 Ex -- — — 20 28 28 28 Δ 4 -13 -18 -23 HORVS Ob 30 0 0 0 0 23 8 1 — 1 — 5 — 3 — 3 — Ex 30 30 Δ -a -23 -15 -20 BRSNW Ob 100 0 0 0 0 98 100 99 100 Ex — — — — — 100 100 100 100 Δ -3 0 -2 0 FAGES Ob 78 0 0 83 83 — 83 — 83 — 83 78 78 78 Δ 5 3 5 5 POLCO Oh 100 0 0 0 0 100 100 100 100 Ex -- — -- 100 100 100 100 cT— Δ 0 0 0 SASKR Ob 70 0 0 0 73 70 70 — 73 — 73 — 70 70 70 Δ 3 8 3 “3 RAYS Ob 80 0 0 0 0 75 80 83 75 30 Ex — — 00 80 60 Δ I -5 0 3 -5 g / ha = grams per hectare TRZAS = Triticum aeslivum (spring wheat) HORVS = Hordeum vuígare (spring barley) BRSNW = Brassica napas (winter rape) PAGES = Fagepyrum esculentum (common alforfon) POLCO = Polygonum convulvus L. (alforfon silvestre) IF-2020-07208301-APN-ANP#INPI Page 55 of 67 SASKR = Salsola kali (Russian thistle) SINAR = Srnapis arvensis (wild mustard) Example 8 A protected composition comprising cloquintocet-mexyl salt (CQCmexilc) and Compound A was evaluated on spring barley (HORVS), winter barley (HORVW), spring wheat (TRZAS), winter wheat (TRZAW), durum wheat (TRZDU), and common oats (AVESA), and the phytotoxicity of the protected composition was measured in each crop. In addition, the efficacy of the protected compositions was measured against unwanted vegetation, including field chamomile (ANTAR, Anthemis arvensis), winter rapeseed (BRSNW, Brassica napas), false chamomile (MATIN, Matricaria inodora), and wild mustard (SINAR, Sinapis arvensis). The results are summarized in Tables 14-16 below. Table 14, Safety of the effects (% of visual damage) of cloquintocet-mexyl (CQCmexyl) and Compound A on grain crops. Application rate (g / ha) Compound A 40 0 ​​40 CQC-mexyl 0 40 40 Herbicide: Protectant ratio 1:1 HORVS Ob 20 0 0 Ex 20 Δ -20 HORVW Ob 40 0 ​​13 Ex 40 Δ 0 0 -28 TRZAS Ob 45 0 0 Ex — - 45 Δ -45 1F-2U2U-U / 2Ü83U1-APN-ANP#INPI Page 56 of 67 Ob 35 0 a TRZAW Ex — — 35 Δ -28 Ob 45 0 0 TRZDU Ex — — 45 Δ -45 Ob 0 0 0 BIRD A Ex — — 0 Δ 0 g / ha - grams per hectare HORVS = Hardenm vulgare (spring barley) HORVW = Hordeum v algara (winter barley) TRZAS = Triticum aestívum (spring wheat) TRZAW = Triticum aestivum (winter wheat) TRZDU = Triticum aestivum (durum wheat) AVESA = Averia sativa (common oats) Table 15. Safety of the effects (% of visual damage) of cloquintocet-mexyl (CQC10 mexyl) and Compound A on grain and weed crops. Application Rate (g / ha) Compound A 20 0 0 0 0 20 20 20 20 40 CQC-mexyl 0 5 10 20 40 5 10 20 Herbicide: Protectant Ratio 4:1 2:1 1:1 1:2 Ob 15 0 0 0 0 0 0 0 0 TRZAS Ex — — — — 15 15 15 15 Γ δ -15 -15 -15 -15 TRZAW Ob 20 0 0 0 0 5 5 5 0 _ _ Ex -* -- — 20 20 20 20 IF-2020-07208301-APN-ANP#INPI Page 57 of 67 Δ I -15 -15 -15 -20 HORVS Ob 20 0 0 0 0 0 0 0 0 Ex -- — — - 20 20 20 20 Δ -20 -20 -20 -20 HORVW Ob 15 0 0 0 0'0 0 0 0 Ex — — 15 15 15 15 Δ -15 -15 -15 -15 antar Ob ' 95 0 0 0 0 99 95 100 100 Ex — — — 95 95 95 95 Δ 4 0 5 5 BRSNW Ob 70 0 0 0 0 70 65 75 75 Ex — — — - - - ' 70 70 70 70 Δ 0 -5 5 5 I g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) TRZAW = Triticum aestivum (winter wheat) HORVS = Hordeum vulgare (spring barley) HORVW = Hordeum vulgare (winter barley) ANTAR = Ant hernia arvensis (field chamomile) BRSNW = Brassica napus (winter rape) Table 16. Safety of the effects (% of visual damage) of ctoquintocet-mexyl (CQC10 mexyl) and Compound A on grain and weed crops. Application rate (g / ha) Compound A 40 0 ​​0 0 0 40 40 40 40 CQC-mexilü 0 10 20 40 80 10 20 40 00 Herbicide: Protectant Ratio 4:1 2:1 1:1 1:2 TRZAS Ob 40 0 ​​0 0 0 0 0 0 0 IF-2020-07208301-APN-ANP#INPI Page 58 of 67 Ex -- -- — — 40 40 40 40 Δ -40 -40 -40 -40 TRZAW Ob 35 0 0 0 0 0 0 0 0 Ex — — — ' — 35 35 35 35 Δ -35 -35 -35 -35 HORVS Ob 40 0 ​​0 0 0 10 10 0 0 Ex — — - — 40 40 40 40 Δ -30 -30 -40 -40 — HORVW Ob 30 0 0 0 0 10 10 0 0 Ex — — — 30 30 30 30 Δ 20 -20 -30 -30 Ob 100 0 0 0 0 98 100 9& 95 MATIN Ex — — — — — 100 100 100 100 Δ -3 or -3 -5 SINAR Ob 99 0 0 0 0 100 100 97 99 Ex — — — - - 99 99 99 99 Δ 2 2 -2 0 g / ha = grams per hectare TRZAS = Triticum aestivum (spring wheat) TRZAW = Triticum aestivum (winter wheat) HORVS = Hordeum vulgare# (spring barley) 5 HORVW = Hordeum vulgare# (winter barley) MATIN = Odorless Matricaria (false chamomile) SINAR = Sinapis atvensis (wild mustard) Example 9 A protected composition comprising cloquintocet-mexyl (CQC-mexyl) and Compound A was evaluated in maize (ZEAMX), and the phytotoxicity of the protected composition was measured in the crop. Additionally, the efficacy of the protected compositions was measured against unwanted vegetation, including amaranth (Amaranthus retrofiexus) and tiger nuts. IF-2020-07208301-APN-ANP#INPI 59 Page 59 of 67 (CYPES, Cyperus escutentus), and common sunflower (HELAN, Helianthus annuusj. The results are summarized in Table 17 below. Table 17. Safety of the effects (% of visual damage) of cloquintoceLmexil (CQC5 mexil) and Compound A on corn and weeds. □osis of Compound A 40 0 ​​0 0 0 40 Γ 40 40 40 application (g / ha) CQC-mexilo 0 20 40 80 120 20 40 80 120 Herbicide Ratio: Protector 2:1 1: 1: 1: 10: 15 3 0 0 15 8 5 0 ZEAMX Ex — — — — 55 55 55 55 Δ -40 -43 -50 -55 Ob 100 0 0 0 0 100 100 08 94 AMARE Ex - — - - 100 100 100 100 03 -07 -3 0 0 0 55 58 75 65 CYPES Ex — — — — 73 73 73 73 Δ -18 -15 3 -8 Ob 100 0 0 0 0 100 100 100 100 HE LAN Ex — — — — 0 0 g / ha = grams per hectare ZEAMX = Zea mays (corn) BEAUTIFUL - Amaranthus mtroflexus (amaranth) CYPES = Cyperus esculentus (chufa) HELAN = Heíianthus annuus (common sunflower) Example 10 A protected composition comprising cloquintocet-acid (CQC-a) and the IF-2020-07208301-APN-ANP#INPI Page 60 of 67 Compound A was applied to maize (ZEAMX), and the phytotoxicity of the protected composition was measured in the crop. Additionally, the efficacy of the protected compositions was measured on unwanted vegetation, including pigweed (AMARE, Amaranthus retrofiexus), tiger nut (CYPES, Cyperus esculentus), and common sunflower (HELAN, Hetianthus annuus). The results are summarized in Table 18 below. Table 18. Safety of the effects (% of visual damage) of cloquintoceLácido (CQCa) and Compound A on corn and weeds. Compound Dose A 40 D 0 0 I 0 40 40 40 40 application (g / ha} CQC-a 0 20 40 30 120 20 40 80 120 Herbicide Ratio; Protector 2.1 1:1 1:2 1:3 Ob 55 0 0 0 0 15 10 3 8 ZEAMX Ex — — — — 55 55 55 55 Δ -40 -45 -43 -43 Ob 100 0 0 0 0 93 100 100 99 AMARE Ex — — — — 100 100 100 100 Δ -8 0 0 -1 Ob 73 0 0 0 0 65 aa 73 90 CYPES Ex — — — — 73 73 73 73“ Δ -3 15 0 ia Ob 100 0 0 0 0 100 100 100 100 HELAN Ex — — — 100 100 100 100 _ _ Δ i 0 0 0 I 0 gfha = grams per hectare ZEAMX = Zea mays (corn) AMARE = ​​Amaranthus retrofíexus (amaranth) CYPES = Cyperus escutentus (chufa) IF-2020-07208301-APN-ANP#INPI Page 61 of 67 H ELAN = Heltanthus annuus (common sunflower) Example 11 A protected composition comprising cloquintocet-mexyl (CQC-mexyl) and Compound A was evaluated in winter wheat (TRZAW), rice (ORYSA), and maize (ZEAMX), and the phytotoxicity of the protected composition was measured in the crop. In addition, the effectiveness of the protected compositions was measured against unwanted vegetation, including Chinese jute (ABUTH, Abutilon theophrasti), blackgrass (ALOMY, Alopecuros myosuroides), amaranth (AMARE, Amaranthus retrofiexus), wild oat (AVEFA, Avena fatua), winter rapeseed (BRSNW, Brassica napus), lamb's quarters (CHEAL, Chenopodium album L.), Canadian thistle (GIRAR, Cirsium arvense), tiger nut (CYPES, Cyperus esculentus), dew guard (DIGSA, Digitada sanguinalis), barnyardgrass (ECHCG, Echinochloa crus-gallty), Canadian butcher's weed (ERICA, Erigeron canadensis), soybean (GLXMA, Glycine max), common sunflower (HELAN, Helianthus annuus), morning glory ivy (IPOHE, Ipomoea hederacea), and kochia (KCHSC, Kochia scoparia).Chinese sprangletop (LEFCH, Leptochloa chinensis), Italian ryegrass (LOLMU, Lolium multiflorum), wild buckwheat (POLCO, Polygonum convolvulus), giant foxtail (SETFA, Setaria faberi). Johnson grass (SORHA. Sorghum halepense), and wild pansy (VIOTR, Viola tricolor). The results are summarized in Table 19 below. Table 19. Safety of the effects (% of visual damage) of cioquintocet-mexyl (CQCmexifo) and Compound A on corn and weeds. Application rate (g / ha) Compound A 20 0 0 0 20 20 20 CQC-mexyl 0 20 40 80 20 40 80 Herbicide: Protectant Ratio 1:1 1:2 1:¿ TRZAW Oh 25 0 0 0 0 0 0 Ex — — -- 25 25 25 11-2020-0 / 2 08301-7 Ipn-ab IPtflNPf Page 62 of 67 Δ -25 -25 -25 ORYSA üb 10 0 0 0 5 20 10 Ex — — — 10 10 10 Δ -5 10 0 ZEAMX Ob 13 0 0 0 0 5 Ex — - S -13 ABU Δ - 13 . 95 0 0 0 93 95 95 Ex — — — - 95 95 95 Δ -2 0 0 ALOMY Ob 0 0 0 0 0 0 Ex - — ' — 0 0 0 Δ 0 0 0 AMARE Ob 93 — 1-0 0 93 93 Δ 7 7 7 AVEFA Ob 0 0 0 0 0 0 Ex - — — -- 0 0 0 Δ 0 0 D BRSNW Ob 35 0 0 0 90 90 80 Ex - 10 80 85 Ob -0 CHE 5 5 . 100 100 Ex — — -- is 88 33 Δ 12 12 12 CIRAR Ob 95 0 0 0 70 70 100 Ex — - — -- 95 95 95 Δ -25 -25 5 — 0 3 --10 Ob 3 — 30 Ex 0 0 30 Δ 1 0 0 -2Ó 1P-2L J2U-U idbS-íUl-A lPN-ANP#INPF Page 63 of 67 DIGS A Ob 30 0 0 0 40 40 40 Ex ' — — - 30 30 30 Δ 10 10 10 ECHCG Ob 05 0 0 a 90 80 85 Ex — — — — 85 85 85 Δ 5 -5 0 ERICA Ob 95 0 0 0 97 97 95 Ex — — — -- 95 95 95 Δ 2 2 0 GLXMA Ob IDO 0 0 6 100 100 100 Ex — — ÍOO 100 100 A 0 0 0 HE LAN Ob 95 0 0 0 100 100 100 Ex — — — 95 95 95 Δ 5 5 5 IPOHE Ob 0 0 0 0 0 0 0 From — — - 0 0 0 Δ 0 0 0 KCHSC Ob 97 0 0 0 97 97 95 Ex - — — — 97 97 97 Δ 0 0 -2 LEFCH Ob 60 0 0 0 20 10 50 Ex — - -- -- 60 60 60 Δ -40 -50 -10 LOLMU Ob 5 0 0 0 5 5 5 Ex — — — 5 5 5 Δ 0 0 0 POLCO Ob 100 0 0 0 100 100 100 Ex — — -- — 100 100 100 Δ 0 0 0 SETFA Ob 65 0 0 0 95 70 75 1P-2 120-0 72Ό8301-APN-ANP4INPI Page 64 of 67 Ex — — — -- 65 65 65 Δ 30 5 10 SORHA Ob D 0 0 0 0 0 0 Ex - — - 0 0 0 Δ 0 0 0 VIOTR Oh 30 0 0 0 10 5 5 Ex — -- — — 30 30 30 Δ -20 -25 -25 g / ha = grams per hectare TRZAW = Triticum aestivum (winter wheat) ORYSA = Rice sativa (arroz común) ZEAMX = Zea mays (corn) ABUTH = Abutilon theophrasti (yute chino) ALOMY = Alopecuros myosuroides (hierba negra) AMARE = ​​Amaranth's retrofíexus (amaranto) AVEFA = Avena fatua (avena silvestre) BRSNW = Brassica napus (winter colza) CHEAL = Chenopodium album L. (cenizo) CIRAR = Cirsrum arvense (cardo canadiense) CYPES = Cyperas e sedentes (chufa) DIGSA = Digitaria s anguín atis (guard rocío) ECHCG = Echinochloa crus-gallí (herba of granero) E RIC A = Erigeron cana tfens / s (hie rba ca rn i cera ca na d ¡en se) GLXMA = Glycine max (soja) HELAN = Helianthus annuus (common sunflower) IROHE = ipomoea hederacea (Hiedra gloria of the morning) KCH8C = Kocliia acoparía (kochia) LEFCH = Leptochloa chinensis (Strangietep chino) LOLMU = Lolium mulliflorum (baliteo italiano) IF-2020-07208301-APN-ANP#INPI Página 65 de 67 POLCO = Polygonum convolvulus {alforfon silvestre) SETFA = Setaria faberi (giant cola de zorro) SCRHA = Sorghum halepense {hierba Johnson) VIOTR = Viola tricolor (sylvatic thought) The compositions and methods of the appended claims are not limited in scope by the specific compositions and methods described herein, which are intended to illustrate some aspects of the claims, and any functionally equivalent composition and method is intended to be within the scope of the 10 claims. Several modifications of the compositions and methods, in addition to those shown and described herein, are intended to be within the scope of the appended claims. Furthermore, although only certain representative compositions and method steps disclosed herein are specifically described, other combinations of the compositions and method steps are also intended to be within the scope of the appended claims, even if not specifically mentioned.Therefore, a combination of steps, elements, components, or constituents of the methods may be explicitly mentioned in this document; however, other combinations of steps, elements, components, and constituents of the methods are included even if they are not explicitly stated. The expression “comprising” and its variations, as used herein, are used synonymously with the expression “including” and its variations and are open, non-limiting expressions. Although the terms “comprising” and “including” are used herein to describe different aspects, the terms “essentially consisting of” and “consisting of” may be used instead of “comprising” and “including” to provide more specific aspects and are also disclosed.Apart from the examples, or where otherwise noted, all numbers expressing quantities of ingredients, reaction conditions, and the like used in the memory and claims are understood to be interpreted as eiF-2i©Modeé8Wl·^. Page 66 of 67 significant and usual rounding methods and not as an attempt to limit the application of the doctrine of equivalents with respect to the scope of the claims. IF-2020-07208301-APN-ANP#INPI Page 67 of 67 Argentine Republic - National Executive Branch 2020 - Year of General Manuel Belgrano Additional Signature Sheet Graphic Report Number: IF-2020-07208301-APN-ANP#INPI CITY OF BUENOS AIRES Friday, January 31, 2020 Reference: 20190103248 The document was imported by the GEDO system with a total of 67 page(s). Digitally signed by GESTION DOCUMENTAL ELECTRONICA- GDE Date: 2020.01.31 20:27:03 -03:00 Mariela Flavia Gonnet Administrative Advisor National Patent Administration National Institute of Industrial Property Digitally signed by DOCUMENTAL MANAGEMENT ELECTRONICS-GDE Date: 2020.01.31 20:27:29-03:00

Claims

1. A composition characterized in that it comprises: (a) a pyridine carboxylate herbicide defined by Formula (I): Formula (I) wherein: R1 is cyanomethyl or propargyl; R2 and R2' are independently hydrogen; R3, R3', R3'', and R3''' are independently hydrogen; or an agriculturally acceptable salt thereof; and (b) a protectant comprising cloquintocet or an agriculturally acceptable salt or ester thereof, wherein the weight ratio of the pyridine carboxylate herbicide (in g ae / ha) to the protectant (in g ai / ha) is from approximately 1:5 to approximately 65:

1. 17 Claims follow