COMPOSITION AND METHOD FOR FORMING A LIQUID DETERGENT COMPOSITION OR WASHING LIQUOR

Abstract

A composition comprising an anionally modified alkyl and / or alkenyl phenol polyoxyalkylene ether represented by formula (1) is described, wherein R1 is a linear or branched alkyl or alkenyl group having 11 to 21 carbon atoms; each R2 is an oxyalkylene group having 2 to 4 carbon atoms; m is an integer from 1 to 50; E is a group comprising one or more sulfate, phosphate, carboxylate, sulfonate, sulfosuccinate, sulfoacetate, sarcosinate, and phosphonate groups; M is a solubilizing cation selected from sodium, potassium, ammonium, mono-, di-, tri-alkanolamine, and mixtures thereof; and an enzyme.

Description

155,621 COMPOSITION Technical field of the invention The present invention relates to a composition, particularly a detergent composition comprising an anionically modified alkyl and / or alkenyl phenol polyoxyalkylene ether and an enzyme. Background of the invention Enzymes are widely used in the detergent industry due to their function as highly effective low-temperature catalysts in the stain removal process. Commonly used enzymes include amylases (for carbohydrate-containing stains), lipases (for grease and cooking oil stains), proteases (for protein stains), and cellulases (for removing lint and pilling from cotton fabrics). However, the stability of these enzymes in detergent compositions remains a significant challenge, particularly in liquid formulations. They are prone to a decline in enzymatic activity over the shelf life of the detergent composition, leading to reduced stain removal effectiveness. Typically, this loss of activity stems from a number of undesirable interactions between the enzymes and other components of the detergent composition. Anionic surfactants are commonly used in detergent compositions due to their excellent cleaning ability to remove oil and grease. However, formulating anionic surfactants with enzymes presents a challenge, as they interact strongly with enzymes, altering their activity. tertiary structure, which results in the unfolding of proteins and loss of activity. Today, bio-based compounds have gained significant interest due to the growing demand for sustainable alternatives to petroleum-based raw materials. Some consumers prefer compounds with a good environmental profile. For the purposes of environmental sustainability, more environmentally friendly surfactant options can be used, especially those derived from plant-based raw materials. The present invention has been devised in light of the foregoing considerations. It has been found unexpectedly, a composition comprising an anionically modified alkyl and / or alkenyl phenol polyoxyalkylene ether and an enzyme provides improved stability and enzymatic activity under the conditions of storage. Synthesis of the invention In one aspect, the present invention relates to a composition comprising: a) an anionicly modified alkyl and / or alkenyl phenol polyoxyalkylene ether represented by the formula (YO) O(R2)mEM Ri (YO) where R1 is a linear alkyl or alkenyl group or branched having 11 to 21 carbon atoms; each R2 is an oxyalkylene group having 2 to 4 carbon atoms; m is an integer from 1 to 50; E is a group comprising one or more sulfate, phosphate, carboxylate, sulfonate, sulfosuccinate, sulfoacetate, sarcosinate, and phosphonate groups; M is a solubilizing cation selected from sodium, potassium, ammonium, mono-, di-, tri-alkanolamine, and mixtures thereof; and b) an enzyme In a second aspect, the present invention relates to a method for forming a liquid detergent composition or a washing solution by dispersing a dose of the composition according to any embodiment of the first aspect. All other aspects of the present invention will become more evident upon consideration of the detailed description and examples that follow. Detailed description Except in the examples or where explicitly stated otherwise, all numbers in this description that indicate quantities of material or reaction conditions, physical properties of materials and / or use may be optionally understood to be modified by the word "approximately". All quantities are by weight of the final composition unless otherwise specified. It should be noted that when specifying any range of values, any particular upper value may be associated with any particular lower value. To avoid doubts, the The phrase “that understands” is intended It means "that includes" but not necessarily "that consists of" or "is composed of." In other words, the stages or options listed do not need to be exhaustive. It should be considered that the disclosure of the invention as set forth in this document covers all embodiments as set forth in the claims as multiple dependents of each other, regardless of the fact that the claims may be found without multiple dependence or redundancy. When a feature is disclosed with respect to a particular aspect of the invention (e.g., a composition of the invention), such disclosure shall also be deemed to apply to any other aspect of the invention (e.g., a method of the invention) mutatis mutandis. Unless otherwise specified, quantities as used in this document are expressed as a percentage by weight based on the total weight of the composition and are abbreviated as “% w” or “% w / w”. Weight % amounts of enzymes in the composition refer to the weight % of active protein levels, unless otherwise stated. The composition can find use in a variety of cleaning applications. Preferably, the composition is a detergent composition. The composition of the present invention can be in any suitable form, for example, a solid such as a powder, a granulated particle, a shaped solid, or a liquid. Preferably, the composition is a liquid detergent composition. The term "liquid" in the context of the present invention indicates that a continuous phase or predominant part of the composition is liquid and that the composition is flowable at 15°C and above. Accordingly, the term "liquid" may encompass emulsions, suspensions, and compositions having a fluid but more rigid consistency, known as gels or pastes. The viscosity of the composition may appropriately range from approximately 200 to approximately 10,000 mPa·s at 25°C at a shear rate of 21 s⁻¹. This shear rate is the shear rate generally exerted on the liquid when it is poured from a bottle. Pourable liquid detergent compositions generally have a viscosity of 200 to 1,500 mPa-s, measured at 25 °C at a shear rate of 21 s-1 by a HAAKE viscometer. In some embodiments, the composition is a laundry detergent composition. The term "laundry detergent" in the context of the present invention denotes formulated compositions intended and capable of wetting and cleaning household linens such as clothing, bedding, and other domestic textiles. Examples of liquid laundry detergents include heavy-duty liquid detergents for use in the wash cycle of automatic washing machines, as well as delicate wash liquid detergents and color care liquid detergents, such as those suitable for washing delicate garments (e.g., silk or wool), either by hand or in the wash cycle of automatic washing machines. In some embodiments, the composition consists of handwashing detergents, which involve the consumer using their hands to wash the materials. The areas of use primarily involve laundry (i.e., handwashing clothes) and handwashing (i.e., handwashing dishes and similar tasks). Handwashing detergents involve close contact of the detergent liquid with the hands during the washing process, whether for laundry or handwashing dishes. Laundry detergent compositions are particularly preferred. The composition may be concentrated or diluted. A “concentrated” composition refers to a composition comprising up to 50% by weight of water, for example, up to 40%, up to 30%, or up to 20%, based on the total weight of the composition. Preferably, the composition of the present invention is a “diluted” composition. A “diluted” composition refers to a composition comprising more than 50% by weight of water, for example, more than 60%, more than 70%, or more than 80%. anionicly modified alkyl and / or alkenyl phenol polyoxyalkylene ether The anionicly modified alkyl and / or alkenyl phenol polyoxyalkylene ether is represented by formula (I): O(R2)mEM (YO) where R1 is a linear or branched alkyl or alkenyl group having 11 to 21 carbon atoms; each R2 is an oxyalkylene group having 2 to 4 carbon atoms; m is an integer from 1 to 50; E is a group that It comprises one or more of sulfate, phosphate, carboxylate, sulfonate, sulfosuccinate, sulfoacetate, sarcosinate, and phosphonate; M is a cation solubilizing agent selected from sodium, potassium, ammonium, mono-, di-, tri-alkanolamine, and mixtures thereof. Preferably, R1 is a linear or branched alkyl or alkenyl group having 13 to 17 carbon atoms, more preferably R1 is a linear alkyl or alkenyl group having 13 to 17 carbon atoms. It is particularly preferred that R1 be a linear C15 alkyl or alkenyl group, more preferably a linear C15 alkyl or alkenyl group comprising 0 to 3 carbon-carbon double bonds. Preferably, each R2 is an ethylene oxide group or a propylene oxide group. More preferably, each R2 is an ethylene oxide group. Preferably, m is an integer from 1 to 30, more preferably from 2 to 15 and with maximum preference from 3 to 10. E is a terminal group comprising one or more of sulfate, phosphate, carboxylate, sulfonate, sulfosuccinate, sulfoacetate, sarcosinate, and phosphonate, preferably E comprising sulfate, phosphate, or mixtures thereof, more preferably E comprising or being sulfate. M is a solubilizing cation selected from sodium, potassium, ammonium, mono-, di-, tri-alkanolamine, and mixtures thereof, preferably M being sodium, potassium, or ammonium, more preferably M being sodium or ammonium. It will be understood that E is a terminal group that carries a charge anionic, covalently bonded to the R2 group. M is one or more cationic residues that form an ionic bond with E to provide charge balance. Preferably, the anionically modified alkyl and / or alkenyl phenol polyoxyalkylene ether is anionally modified alkyl and / or alkenyl phenol polyoxyethylene ether, more preferably it is anionally modified cardanol polyoxyethylene ether. Preferably, the anionically modified alkyl and / or alkenyl phenol polyoxyalkylene ether is alkyl and / or alkenyl phenol polyoxyalkylene ether sulfate, or alkyl and / or alkenyl phenol polyoxyalkylene ether phosphate; more preferably, the anionally modified alkyl and / or alkenyl phenol polyoxyalkylene ether is alkyl and / or alkenyl phenol polyoxyethylene ether sulfate, or alkyl and / or alkenyl phenol polyoxyethylene ether phosphate. It is particularly preferred that the anionicly modified alkyl and / or alkenyl phenol polyoxyalkylene ether be cardanol polyoxyalkylene ether sulfate or cardanol polyoxyalkylene ether phosphate, preferably cardanol polyoxyethylene ether sulfate or cardanol polyoxyethylene ether phosphate. Cardanol polyoxyethylene ether sulfate is the most preferred. Cardanol is a product obtained by treating cashew shell liquid (CNSL). CNSL is a well-known, non-edible natural oil obtained as a byproduct of the cashew nut (Anacardium occidentale). CNSL is one of the most widely used bio-based resources for providing useful chemicals for various applications. Cardanol is an important chemical derivative. Cardanol is a naturally occurring biomass phenol with a C15 side chain (R) at the meta position of the aromatic ring, represented by formula (II). The R side chain is a linear C15 alkyl or alkenyl group comprising 0 to 3 carbon-carbon double bonds. Therefore, cardanol has four components, each with saturated, monoene, diene, and triene structures, respectively. The double bonds are located at positions 8, 11, and 14 of the R side chain, respectively. The four components of cardanol are approximately 5–8% saturated, approximately 48–49% single-double-bond, approximately 16–17% double-bond, and approximately 29–30% triple-bond. OH (II) The polyoxyethylene ether cardanol, which is represented by formula (III), can be formed by a polymerization-type reaction by reacting cardanol and ethylene oxide in the presence of a catalyst. O(CH2CH2O)nH (III) where R is a linear C15 alkyl or alkenyl group that 9 It comprises 0 to 3 carbon-carbon double bonds as previously defined in formula (II). n is an integer from 1 to 50, preferably from 1 to 30, more preferably from 2 to 15 and most preferably from 3 to 10. The reaction is commonly known as ethoxylation. The reaction mechanism is as follows: cardanol generates negative oxygen ions under alkaline conditions, and polyoxyethylene ether cardanol is obtained by ethoxylation with ethylene oxide. Preferably, the molar ratio of cardanol to ethylene oxide is 1:100 to 20:1, more preferably 1:50 to 10:1, and even more preferably 1:30 to 1:1. Preferred catalysts for this reaction include, for example, potassium hydroxide, sodium hydroxide, barium hydroxide octahydrate, sodium bicarbonate, or mixtures thereof. The amount of catalyst is typically 0.01 to 5% by weight of cardanol, more preferably 0.1 to 3%, even more preferably 0.2 to 1%, and most preferably 0.4 to 0.6%. The reaction temperature is preferably 120 to 180°C and the polymerization reaction time is typically 0.5 to 2 hours.At the end of the polymerization reaction, the reaction product is typically neutralized with acetic acid to obtain cardanol polyoxyethylene ether. Other alkylene oxides, such as propylene oxide, can also react with cardanol via a polymerization reaction to produce various cardanol polyoxyalkylene ethers. Other examples of suitable manufacturing processes for generating the cardanol polyoxyethylene ether described herein are described in documents CN102432440A, CN102391080A, CN102351664A, and CN101941894A. Polyoxyethylene ether cardanol can be further functionalized with an anionic group to form anionicly modified polyoxyethylene ether cardanol. Preferably, the anionic group is sulfate or phosphate, more preferably sulfate. Cardanol polyoxyethylene ether sulfate, which is represented by formula (IV), can be formed by sulfonating cardanol polyoxyethylene ether in the presence of a catalyst. 0(CH2CH2O)nS03M (IV) where R is a linear C15 alkyl or alkenyl group comprising 0 to 3 carbon-carbon double bonds as previously defined in formula (II). n is an integer from 1 to 50, preferably from 1 to 30, more preferably from 2 to 15 and most preferably from 3 to 10. M is a solubilizing cation selected from sodium, potassium, ammonium, mono-, di-, tri-alkanolamine and mixtures thereof, preferably M is sodium, potassium or ammonium, more preferably M is sodium or ammonium. The preferred sulfonating agent is sulfamic acid or sodium sulfonate, more preferably sulfamic acid. The molar ratio of cardanol polyoxyethylene ether and sulfonating agent is preferably 1:10 to 10:1, more preferably 1:5 to 5:1, even more preferably 1:3 to 3:1, and most preferably 1:1.2 to 1:1. The preferred catalysts for this reaction include, For example, carbonamide, dicyandiamide, urea, p-toluenesulfonic acid, dimethylformamide, N-methylpyrrolidone, hypophosphite, or mixtures thereof, more preferably carbonamide, dicyandiamide, urea, or mixtures thereof. The molar ratio of polyoxyethylene cardanol ether and the catalyst is preferably 1:10 to 30:1, more preferably 1:5 to 20:1, even more preferably 1:1 to 10:1, and most preferably 1.5:1 to 5:1. It is preferred that a reducing agent be included in the reaction mixture as a color stabilizer to obtain a light-colored polyoxyethylene cardanol sulfate. Preferably, the reducing agent comprises hypophosphorous acid, hypophosphite, or mixtures thereof. The reaction temperature is preferably 100 to 125°C and the reaction time is typically 3 to 6 hours. At the end of the reaction, an alcohol can be added to the reaction mixture to reduce the viscosity in order to obtain cardanol polyoxyethylene ether sulfate. The alcohol is preferably a C1-C4 monohydric alcohol comprising methanol, ethanol, isobutanol, or mixtures thereof. Alternatively, the reaction mixture can be neutralized with sodium hydroxide to obtain cardanol polyoxyethylene ether sulfate. Other examples of suitable manufacturing processes for generating the cardanol polyoxyethylene ether sulfate described herein are described in documents CN114276281A and CN101941926A. document. When sulfamic acid is used as the sulfonating agent, the M counterion for the resulting cardanol polyoxyethylene ether sulfate is ammonium. An example is commercially available under the trade name NSN3003 from Nasurfar. Biomaterial Technology Co. Ltd. The ammonium counterion can be replaced with sodium or potassium ions by ion exchange according to standard processes to produce sodium polyoxyethylene ether cardanol sulfate or potassium polyoxyethylene ether cardanol sulfate. Polyoxyethylene ether cardanol sulfate with a sodium or potassium counterion is preferred, as it may be more stable compared to a corresponding ammonium salt when formulated in a composition of the present invention. The composition of the present invention preferably comprises anionally modified alkyl and / or alkenyl phenol polyoxyalkylene ether in an amount of 0.1 to 30%, more preferably 0.5 to 20%, even more preferably 1 to 15%, and most preferably 2 to 10%, based on the total weight of the composition and including all intervals therein. Enzyme The composition of the present invention comprises an enzyme. Examples of suitable enzymes for use in the composition include protease, lipase, amylase, mannanase, pectatolyase, cellulase, phospholipase, cutinase, peroxidase, oxidase, or mixtures thereof. Protease and amylase are the most preferred. Ideally, the composition includes a protease. Protease enzymes hydrolyze the bonds within peptides and proteins; in the context of detergents, this leads to greater removal of stains containing proteins or peptides. Examples of suitable protease families include aspart proteases, cysteine ​​proteases, and glutamic proteases. Asparagine peptidolyase; serine proteases and threonine proteases. These protease families are described in the MEROPS peptidase database (http: / / merops.sanger.ac.uk / ). Serine proteases are preferred. Subtilase-type serine proteases are the most preferred. The term “subtilases” refers to a subgroup of serine proteases according to Siezen et al., Protein Engineering 4 (1991) 719–737 and Siezen et al., Protein Science 6 (1997) 501-523. Serine proteases are a subgroup of Proteases are characterized by having a serine residue in their active site, which forms a covalent adduct with the substrate. Subtilases can be divided into six subgroups: the Subtilisin family, the Termitase family, the Proteinase K family, and the Lantibiotic family. peptidase, the Kexin family and the Pyrolysin family. Examples of subtilases are those derived from Bacillus such as Bacillus lentus, B. alkalophilus, B. subtilis, B. amyloliquefaciens, Bacillus pumilus and Bacillus gibsonii described in papers US7262042 and WO09 / 021867, and subtilisinase lentus, and subtilisina Novo, Carlsberg, Bacillus licheniformis, subtilisin BPN', subtilisin 309, subtilisin 147 and subtilisin 168 described in paper WO89 / 06279 and protease PD138 described in paper (WO93 / 18140). Preferably, the subsilicine is derived from Bacillus, preferably Bacillus lentus, B. alkalophilus, B. subtilis, B. amyloliquefaciens, Bacillus pumilus and Bacillus gibsonii as described in documents US 6.312.936 B1, US 5.637, US. 7,262,042 and WO09 / 021867. Preferably, subtilisin is derived from Bacillus gibsonii or Bacillus Lentus. The commercially available protease enzymes Suitable products include those sold under the trade names Alcalase®, Blaze®; Duralase™, Durazym™, Relase®, Relase® Ultra, Savinase®, Savinase® Ultra, Primase®, Polarzyme®, Kannase®, Liquanase®, Liquanase® Ultra, Ovozyme®, Coronase®, Coronase® Ultra, Neutrase®, Everlase®, Esperase® and Carnival™ may be sold as Ultra® or Evity® (Novozymes A / S). Carnival™ Evity® is particularly preferred. Those sold under the trade names Maxatase®, Maxacal®, Maxapem®, Properase®, Purafect®, Purafect Prime®, Purafect Ox®, FN3®, FN4®, Excellase® and Purafect OXP® by Genencor International. Those sold under the trade names Maxatase®, Maxacal®, Maxapem®, Purafect®, Purafect Prime®, PreferenzTm, Purafect MA®, Purafect Ox®, Purafect OxP®, Puramax®, Properase®, EffectenzTM, FN2®, FN3®, FN4 ®, Excellase®, Opticlean® and Optimase® (Danisco / DuPont), Axapem™ (Gist-Brocases NV). The available ones from Henkel / Kemira, namely, BLAP (sequence shown in Figure 29 of document US 5,352,604 with the following mutations S99D + SlOl R + S103A + V104I + G159S, hereinafter referred to as BLAP), BLAP R (BLAP with S3T + V4I + V199M + V205I + L217D), BLAP X (BLAP with S3T + V4I + V205I ) and BLAP F49 (BLAP with S3T + V4I + A194P + V199M + V205I + L217D), all from Henkel / Kemira; and KAP (Bacillus alkalophilus subtilisin with mutations A230V + S256G + S259N) from Kao. Ideally, the composition includes an amylase. Amylases are enzymes that catalyze the hydrolysis of starch into sugars; in the context of detergents, this leads to greater stain removal than They contain starch. Suitable amylases (alpha and / or beta) include those of bacterial or fungal origin. Chemically modified or genetically engineered mutant proteins are included. The most preferred amylases include, for example, alpha-amylases obtained from Bacillus, for example, a special strain of B. licheniformis, described in more detail in document GB 1,296,839, or the Bacillus sp. strains described in documents WO 95 / 026397 or WO 00 / 060060. The most preferred (commercially available) amylases are sold under the trade names Duramyl®, Termamyl®, Fungamyl®, Stainzyme®, Stainzyme® Plus, Natalase®, Amplify Prime®, and BAN® (from Novozymes A / S), and Rapidase®, Purastar® / Effectenz™, Powerase™, Preferenz S1000™, Preferenz S1 10™, and Preferenz S100™ (from Genencor International Inc. / DuPont). Amplify® Prime amylase is the most advantageous of the commercially available amylase enzymes. The lipase can be any known lipase used in the technique of detergent compositions. Preferred lipases include those from Humicola (synonym Thermomyces), for example, from other strains of H. lanuginosa (T. lanuginosus) or H. insolens; a lipase from Pseudomonas, for example, from P. alcaligenes or P. pseudoalcaligenes, P. cepacia, P. stutzeri, P. fluorescens, Pseudomonas sp. strain SD 705 (documents WO 95 / 06720 and WO 96 / 27002), P. wisconsinensis; a lipase from Bacillus, for example, from B. subtilis (Dartois et al. (1993), Biochemica et Biophysica Acta, 1131, 253-360), B. stearothermophilus (document JP) 64 / 744992) or B. pumilus (document WO 91 / 16422). Even more preferred (commercially available) lipases are sold under the trade names Lipex®, Lipolase® and Lipolase Ultra®, Lipoprime® and Lipoclean® (from Novozymes A / S), and the bacterial enzyme Lipomax® from Genecor. This is 16 a bacteria-derived lipase, of the M21L variant of the Pseudomonas alcaligenes lipase as described in Gist-Brocades paper WO 94 / 25578 (MMMJ Cox, HBM Lenting, LJSM Mulleners and JM van der Laan). Lipase® is the most preferred. Suitable mananases include mananases of bacterial and fungal origin. More preferred are manasas derived from the genus Aspergillus filamentous fungi, preferably Aspergillus niger or Aspergillus aculeatus (document WO 94 / 25576); Trichoderma reseei (as described in document WO 93 / 24622); Bacillus organisms (for example, as described in Talbot et al., Appl. Environ. Microbiol. Vol.56, No. 11, pp. 3505-3510 (1990), which describes a beta-mannanase derived from Bacillus stearothermophilus, Mendoza et al. 10, No. 5, pp. 551-555 (1994), which describes. a betamannanase derived from Bacillus subtilis, paper JP-A-03047076 describing a betamannanase derived from Bacillus sp., paper JP-A-63056289 describing the production of an alkaline thermostable beta-mannanase, paper JP-A-736 describing the microorganism Bacillus FERM P-8856 producing beta-mannanase and beta-mannosidase, paper JP-A-08051975 describing an alkaline beta-mannanase from Bacillus sp alcalof^lico AM-001, paper WO97 / 11164 describing a purified mannanase from Bacillus sp. 91 / 18974 describing a hemicellulase such as active glucanase, xylanase or mannanase). Alkaline mannanases of family 5 and 26 derived from Bacillus agaradhaerens, Bacillus licheniformis, Bacillus halodurans, Bacillus clausii, Bacillus sp. and Humicola insolens (as described in document WO 99 / 64619). The most bacterial manases preferable are those described in document WO 99 / 64619. The most preferred mananasa (commercially available) is Mannaway® available from Novozymes A / S Denmark. The pectato liasas are also called polygalacturonato liasas. Preference is given to those which are derived from generic bacteria such as Erwinia, Pseudomonas, Klebsiella and Xanthomonas, Bacillus. But preferable are the pectato liasas obtained from Bacillus subtilis (Nasser et al. (1993) FEBS Letts. 335:319-326), Bacillus sp. YA-14 (Kim et al. (1994) Biosci. Biotech. Biochem. 58:947-949); Bacillus pumilus (Dave and Vaughn (1971) J. Bacteriol. 108:166-174), B. polymyxa (Nagel and Vaughn (1961) Arch. Biochem. Biophys. 93:344-352), B. stearothermophilus (Karbassi and Vaughn (1980) Can. J. Microbiol. 26:377-384), Bacillus sp. (Hasegawa and Nagel (1966) J. Food Sci. 31:838-845), Bacillus sp. RK9 (Kelly and Fogarty (1978) Can. J. Microbiol. 24:1164-1172), as disclosed in Heffron et al., (1995) Mol. Plant-Microbe Interact. 8: 331-334, Henrissat et al., (1995) Plant Physiol. 107: 963-976, as described in the documents WO 99 / 27083, WO 99 / 27084, US 6,284,524 (document incorporated herein by reference), WO 02 / 006442 (particularly as described in the Examples, document incorporated herein by reference). Even more preferred are the commercially available pectate lyases BioPrep®, Scourzyme® L, and XPec® from Novozymes A / S, Denmark. The pectate lyase XPec® is the most preferred. Suitable cellulases include those of bacterial, fungal, insect, and / or mammalian origin. Chemically modified or genetically engineered mutant proteins are also included. Cellulases from the genera Bacillus, Pseudomonas, Humicola, and Fusarium are preferred. Thielavia, Acremonium, for example, fungal cellulases produced from Humicola insolens, Thielavia terrestris, Myceliophthora thermophila and Fusarium oxysporum described in documents US 4,435,307, US 5,648,263, US 5,691,178, US 5,776,757, WO 89 / 09259, WO 96 / 029397 and WO 98 / 012307. Even more preferred (commercially available) cellulases are Celluzyme®, Carezyme®, Endolase™, Renozyme®, Celluclean® (Novozymes A / S), Clazinase™ and Puradax HA™ (Genencor International Inc.), and KAC-500(B)™ (Kao Corporation). Celluclean® cellulase is the most preferred. Phospholipases are classified as EC 3.1.1.4 and / or EC 3.1.1.32. As used in this document, the term phospholipase refers to an enzyme that is active against phospholipids. Phospholipids, such as lecithin or phosphatidylcholine, consist of glycerol esterified with two fatty acids at an external (sn-1) and a middle (sn-2) position and esterified with phosphoric acid at the third position; the phosphoric acid, in turn, may be esterified to an amino alcohol. Phospholipases are enzymes that participate in the hydrolysis of phospholipids. Several types of phospholipase activity can be distinguished, including phospholipases A1 and A2, which hydrolyze a fatty acyl group (at the sn-1 and sn-2 positions, respectively) to form lysophospholipid; and lysophospholipase (or Phospholipase B) can hydrolyze the remaining fatty acyl group in the lysophospholipid. Phospholipase C and phospholipase D (phosphodiesterases) release diacylglycerol or phosphatidic acid, respectively. Cutinases are classified in EC 3.1.1.74. The cutinase used according to the invention can be of any origin. Preferably, the cutinases are of microbial origin and 19 most preferably of bacterial, fungal or yeast origin. Suitable peroxidases / oxidases are of bacterial, fungal, or mammalian origin, and preferably of bacterial origin. Chemically modified or genetically engineered protein mutants are included. Preferably, the peroxidases / oxidases are derived from Aeromonas sp. The composition of the present invention preferably comprises from 0.00001 to 1% by weight of the enzyme, more preferably from 0.0001 to 0.5%, even more preferably from 0.0005 to 0.4%, even more preferably from 0.001 to 0.3%, and most preferably from 0.001 to 0.2%, based on the total weight of the composition and including all intervals therein. The weight percentages of enzymes in the composition refer to the weight percentage of active protein levels. The enzymes may be added to the composition in liquid, granular, or encapsulated form, but are preferably not encapsulated. The composition may also comprise enzyme stabilizers, for example, a polyol such as propylene glycol or glycerol, a sugar or sugar alcohol, lactic acid, boric acid, or a boric acid derivative, for example, an aromatic borate ester, or a phenylboronic acid derivative such as 4-formylphenylboronic acid, and the composition may be formulated as described, for example, in WO 92 / 19709 and WO 92 / 19708. Surfactant The composition may comprise surfactants other than the anionicly modified alkyl and / or alkenyl phenol polyoxyalkylene ether. Suitable surfactants comprise anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants, or mixtures thereof; preferably, the surfactants comprise anionic surfactants, nonionic surfactants, or mixtures thereof. A preferred class of anionic surfactant for use in the invention includes alkyl benzenesulfonates, particularly linear alkyl benzenesulfonates (LAS) with an alkyl chain length of 10 to 18 carbon atoms. Commercial LAS is a mixture of closely related alkyl chain isomers and homologs, each containing a sulfonated aromatic ring in the "para" position and attached to a linear alkyl chain at any position except the terminal carbons. The linear alkyl chain typically has a chain length of 11 to 15 carbon atoms, with the predominant materials having a chain length of approximately C12. Each alkyl chain homolog consists of a mixture of all possible sulfophenyl isomers except the 1-phenyl isomer. LAS is normally formulated in acidic compositions (i.e., HLAS) and then at least partially neutralized in situ.Examples of alkyl benzenesulfonate include the sodium salt of linear alkyl benzenesulfonate, alkyl toluenesulfonate, alkyl xylenesulfonate, alkyl phenolsulfonate, alkyl naphthalenesulfonate, and ammonium diamylmahthalenesulfonate. sodium dinonylnaphthalenesulfonate and mixtures with olefin sulfonates. An alkyl sulfate surfactant (PAS) can be used, such as non-ethoxylated primary and secondary alkyl sulfates with an alkyl chain length of 10 to 18. Another anionic surfactant commonly used in compositions is the alkyl ether sulfate, which has a linear or branched alkyl group with 10 to 18, more preferably 12 to 14 carbon atoms and contains an average of 1 to 3 EO units per molecule. A preferred example is sodium lauryl ether sulfate (SLES), in which the C12 alkyl lauryl group is predominantly ethoxylated with an average of 2 EO units per molecule. Alkyl ether sulfates may be present in the composition. Preferably, the composition is substantially free of alkyl ether sulfates. “Substantially free of,” as used herein, means less than 1.5%, preferably less of 1.0%, more preferably less than 0.75%, plus Preferably even less than 0.5% and even more Preferably less than 0.1% and, with maximum preference, from 0 to 0.01% by weight, based on the total weight of the composition, including all intervals within it. It is preferred that the composition not contain alkyl ether sulfates. When the composition comprises other anionic surfactants besides the anionicly modified alkyl and / or alkenyl phenol polyoxyalkylene ether, the amount of total anionic surfactants in the composition preferably ranges from 0.1 to 60%, more preferably from 1 to 55% and even more Preferably, from 3 to 50%, based on the total weight of the composition and including all intervals within it. The composition may also comprise nonionic surfactants. The nonionic surfactants for use in the invention include, for example, a) polyoxyalkylene compounds, i.e., the reaction product of alkylene oxides (such as ethylene oxide or propylene oxide or mixtures thereof) with initiator molecules having a hydrophobic group and a reactive hydrogen atom that is reactive with the alkylene oxide. Such initiator molecules include alcohols, acids, amides, or alkylphenols. When the initiator molecule is an alcohol, the reaction product is known as an alcohol alkoxylate. Polyoxyalkylene compounds may have a variety of block and heterotic (random) structures. For example, they may comprise a single alkylene oxide block, or they may be diblock alkoxylates or triblock alkoxylates.Within the block structures, the blocks may all be ethylene oxide or all propylene oxide, or the blocks may contain a heterotic mixture of alkylene oxides. Examples of such materials include C8 to C22 alkylphenol ethoxylates with an average of 5 to 25 moles of ethylene oxide per mole of alkyl phenol; and alkyl alcohol ethoxylates such as C8 to C18 primary or secondary linear or branched alcohol ethoxylates with an average of 2 to 40 moles of ethylene oxide per mole of alcohol; b) fatty acid amides; c) alkoxylated glycerol esters; d) alkyl polyglycosides; e) rhamnolipids; or a mixture thereof. A preferred class of nonionic surfactant for use in The present invention includes C8 to C18 alkyl alcohol ethoxylates, more preferably C12 to C15 primary linear alcohol ethoxylates with an average of 3 to 20, more preferably 3 to 10 moles of ethylene oxide per mole of alcohol. Lauryl alcohol condensed with 3, 5, 7, and 9 moles of EO (AEO-3, AEO-5, AEO-7, and AEO-9) is particularly preferred. Another preferred class of nonionic surfactant for use in the invention includes fatty acid amides. Preferably, the fatty acid amide contains at least 6 carbon atoms. The suitable fatty acid preferably contains from 8 to 24 carbon atoms, preferably from 12 to 20 carbon atoms, and most preferably from 12 to 18 carbon atoms. In the most preferred embodiment of the invention, amides of essential fatty acids are employed. The amides suitable for use in the present invention may be simple amides (i.e., those containing a -CONH2 group), N-alkylamides, N,N-dialkylamides, mono-alkanol amides, and di-alkanol amides. The suitable alkyl or alkanol groups contain from 1 to 30 carbon atoms, preferably from 1 to 20 carbon atoms, and most preferably from 1 to 8 carbon atoms. The preferred amides included in the present invention are mono- and di-alkanol amides, particularly of essential fatty acids.Alkanolamides are more readily available than alkylamides. Preferably, the fatty acid amides are fatty alkanolamides, more preferably C1 to C8 alkanolamides of fatty acids C8 to C20. The preferred fatty acid amides are selected from mono- and diethanolamides of linoleic acid, palmitic acid, and coconut oil. More preferably, the amide fatty acid comprises cocamide MEA, cocamide DEA, lauramide DEA, palm kernel amide DEA, stearamide MEA, myristamide DEA, stearamide DEA, oleylamide DEA, seboamide DEA, seboamide MEA, isostearamide DEA, isostearamide MEA, cocamide MIPA or a mixture thereof. Palm kernel amide DEA is particularly preferred. Another preferred class of nonionic surfactant is the alkoxylated glycerol ester. The alkoxylated glycerol ester is represented by formula (V): — H n L * / O 1 3 IL (V) where each of R1 to R6 is independently a hydrogen or methyl group; each of R7 to R9 is independently a linear or branched alkyl or alkenyl group having from 5 to 30 carbon atoms, preferably from 8 to 22 carbon atoms, more preferably from 10 to 18 carbon atoms; m, n, p, x, y, z are independently a number from 1 to 30, preferably from 5 to 25 and more preferably from 12 to 21. The sum of m, n, p, x, y, z is in the range of 3 to 90. Preferably, the alkoxylated glycerol ester comprises esters of coconut fatty acids. Coconut or coco fatty acids include about 82% by weight of saturated fatty acids, and of the total fatty acid content, lauric acid is the most common at about 48% by weight of the fatty acid content. Myristic acid (16% by weight) and palmitic acid (9.5% by weight) are the The following are the most common. Oleic acid is the most common unsaturated fatty acid, present at around 6.5% by weight of the fatty acid content. Preferably, the alkoxylated glycerol ester comprises fatty acid esters from palm oil. Palm oil has a balanced fatty acid composition in which the level of saturated fatty acids is almost equal to that of unsaturated fatty acids. Palmitic acid (44%–45%) and oleic acid (39%–40%) are the main acid components, with linoleic acid (10%–11%) and only a small amount of linolenic acid. Palm kernel oil contains more saturated fatty acids compared to palm oil. The main fatty acids in palm kernel oil are approximately 48% lauric acid, 16% myristic acid, and 15% oleic acid. The most preferred alkoxylated glycerol ester is palm kernel oil ethoxylates. An example is commercially available under the trade name SOE-N-60 from Sinolight Surfactant Technology Co., Ltd. Other alkoxylated glyceryl esters are commercially available from Kao under the trade name Levenol. Variants include Levenol F-200, which has an average EO of 6 and a glycerol-to-coconut fatty acid molar ratio of 0.55; Levenol V501 / 2, which has an average EO of 17 and a glycerol-to-coconut fatty acid molar ratio of 1.5; and Levenol C201, which is also known as glycereth-17 cocoate. Another class of nonionic surfactants that can be used according to this invention are glycoside surfactants. Alkyl polyglycoside surfactants suitable for use according to the present invention 26 These include those with a formula: RO-(R2O)y-(Z)x where R is a monovalent organic radical containing from approximately 6 to approximately 30 (preferably from approximately 8 to approximately 18) carbon atoms; R2 is a divalent hydrocarbon radical containing from approximately 2 to 4 carbon atoms; O is an oxygen atom, and is a number that can have an average value from 0 to approximately 12 but is most preferably zero; Z is a residue derived from a reducing saccharide containing 5 or 6 carbon atoms; and x is a number that has an average value from 1 to 10 (preferably from 1 1 / 2 to 10). A particularly preferred group of glycoside surfactants for use in the practice of this invention includes those of the above formula wherein R is a monovalent organic radical (linear or branched) containing from about 6 to about 18 (especially from about 8 to about 18) carbon atoms; y is zero; z is glucose or a residue derived therefrom; x is a number having a mean value from 1 to 4 (preferably from 1 1 / 2 to 4). Preferably, the nonionic surfactant comprises alkyl alcohol ethoxylates. Mixtures of two or more of the nonionic surfactants may be used. When the composition comprises nonionic surfactants, the nonionic surfactant is normally present at a level of 0.01 to 30%, more preferably 0.1 to 20%, and most preferably 1 to 10%, based on the total weight of the composition and including all the intervals included therein. The composition may also include one or more types of cationic surfactants. Many cationic surfactants are known in the art, and almost any cationic surfactant having at least one long-chain alkyl group of approximately 10 to 24 carbon atoms may be present as an auxiliary component of the surfactant system. Such compounds are described in “Cationic Surfactants”, Jungermann, 1970, incorporated by reference. Specific cationic surfactants include C8 to C18 alkyl dimethyl ammonium halides and derivatives thereof, in which one or two hydroxyethyl groups replace one or two of the methyl groups, and mixtures thereof. Further cationic surfactants that may be used as surfactants are described in detail in U.S. Patent No. 4,497,718, which is incorporated herein by reference. As with nonionic and anionic surfactants, the compositions of the invention may use cationic surfactants alone or in combination with any of the other surfactants known in the art. The cationic surfactant, when included, may be present in an amount ranging from 0 to 5%, depending on the total weight of the composition. It is preferred that the composition not contain any cationic surfactant. The composition may also include one or more types of amphoteric surfactants. Specific amphoteric (zwitterionic) surfactants include alkylamine oxides, alkylbetaines, alkylamidopropylbetanes, alkylsulfobetaines (sultaines), alkyl glycinates, Alkyl carboxyglycinates, alkyl amphoacetates, alkyl amphopropionates, alkyl amphoglycinates, alkyl amidopropylhydroxysultanas, acyl taurates, and acyl glutamates having alkyl radicals containing from approximately 8 to approximately 22 carbon atoms, the term “alkyl” being used to include the alkyl portion of higher acyl radicals. Amphoteric (zwitterionic) surfactant, when included, may be present in an amount ranging from 0 to 5% based on the total weight of the composition. It is preferred that the composition not contain any amphoteric surfactant. Adjuvants Surfactants improve or maintain the cleaning effectiveness of surfactants, primarily by reducing water hardness. This is achieved through sequestration or chelation (keeping hardness minerals in solution), precipitation (forming an insoluble substance), or ion exchange (exchange of electrically charged particles). Suitable surfactants can be organic, inorganic, or a mixture of both. Suitable inorganic detergent aids include hydroxides, carbonates, sesquicarbonates, bicarbonates, silicates, zeolites, and mixtures thereof. Specific examples of such materials include sodium potassium hydroxide, sodium potassium carbonate, sodium potassium bicarbonate, sodium sesquicarbonate, sodium silicate, and mixtures thereof. Suitable organic adjuvants include polycarboxylates, in acid and / or salt form. When used in salt form, alkali metal salts (e.g., sodium and potassium) or alkanolammonium salts are preferred. Specific examples of such materials include citrates of sodium and potassium, sodium and potassium tartrates, the salts sodium and potassium salts of tartaric acid monosuccinate, sodium and potassium salts of tartaric acid disuccinate, sodium and potassium ethylenediaminetetraacetates, sodium and potassium N-(2-hydroxyethyl)-ethylenediamine triacetates, sodium and potassium nitrilotriacetates, and sodium and potassium N-(2-hydroxyethyl)-nitrilodiacetates. Polymeric polycarboxylates, such as polymers of unsaturated monocarboxylic acids (e.g., acrylic, methacrylic, vinylacetic, and crotonic acids) and / or unsaturated dicarboxylic acids (e.g., maleic, fumaric, itaconic, mesaconic, and citraconic acids and their anhydrides), can also be used. Specific examples of Such materials include polyacrylic acid, polymaleic acid, and acrylic-maleic acid copolymers. Polymers can be in acidic, salt, or partially dissolved form neutralized and may suitably have a molecular weight (Mw) in the range of approximately 1,000 to 100,000, preferably from approximately 2,000 to approximately 85,000 and most preferably from approximately 2,500 to approximately 75,000. It is particularly preferred that the adjuvants be phosphate sequestrants. Examples of suitable phosphate sequestrants for use in the composition include 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP), diethylenetriaminepenta(methylenephosphonic) acid (DTPMP), hexamethylenediaminetetra(methylenephosphonic) acid (HDTMP), aminotris(methylenephosphonic) acid (ATMP), ethylenediaminetetra(methylenephosphonic) acid (EDTMP), tetramethylenediaminetetra(methylenephosphonic) acid (TDTMP), acid phosphonobutanetricarboxylic acid (PBTC) or mixtures thereof, preferably 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP), diethylenetriaminepenta(methylenephosphonic acid) (DTPMP) or mixtures thereof. Diethylenetriaminepenta(methylenephosphonic acid) (DTPMP) is particularly preferred. The sequestering agent may be in the form of an acid or a corresponding salt. Preferably, the sequestering agent is in the form of a corresponding salt, more preferably an alkali metal salt, and even more preferably a sodium salt. Mixtures of any of the following can also be used materials described above. The composition of the present invention preferably comprises the adjuvants in an amount of 0.01 to 10%, more preferably from 0.1 to 5%, even more preferably from 0.25 to 4% and, most preferably, from 0.5 to 2.5%, based on the total weight of the composition and including all intervals within. Hydrotropes A composition of the invention may preferably comprise non-aqueous carriers such as hydrotropes, cosolvents, and phase stabilizers. Such materials are typically low molecular weight organic liquids, soluble in water or miscible in water, such as C1 to C5 monohydric alcohols (such as ethanol and n- or i-propanol); C2 to C6 diols (such as monopropylene glycol and dipropylene glycol); C3 to C9 triols (such as glycerol); polyethylene glycols having a weight-average molecular weight (Mw) in the range of approximately 200 to 600; C1 to C3 alkanolamines such as mono-, di- and triethanolamines; and alkylaryl sulfonates having up to 3 carbon atoms in the alkyl group lower (such as xylene, toluene, ethylbenzene and isopropylbenzene (cumene) sodium and potassium sulfonates). Mixtures of any of the materials described above can also be used. Non-aqueous carriers, when included, may be present in amounts ranging from 0.01 to 50% by weight of the composition, preferably from 0.05 to 30%, more preferably from 0.1 to 15%, and even more preferably from 0.2 to 5% based on the total weight of the composition, including all intervals within that range. The level of hydrotrope used is linked to the level of surfactant, and it is desirable to use the hydrotrope level to manage viscosity in such compositions. Preferred hydrotropes are monopropylene glycol, glycerol, triethanolamines, or mixtures thereof. Dirt-releasing polymers Soil-releasing polymers (SRPs) help improve soil separation from fabric by modifying the fabric surface during washing. The adsorption of an SRP onto the fabric surface is promoted by an affinity between the chemical structure of the SRP and the target fiber. The composition of the invention preferably comprises SRPs. The SRPs for use in the invention may include a variety of charged (e.g., anionic) as well as uncharged monomeric units, and the structures may be linear, branched, or star-shaped. The SRP structure may also include protecting groups to control molecular weight or to alter The polymer properties, such as surface activity. The weight average molecular weight (Mw) of the SRP can suitably range from approximately 1000 to approximately 20,000 and preferably ranges from approximately 1500 to approximately 10,000. The SRPs for use in the invention can be suitably selected from copolyesters of dicarboxylic acids (e.g., adipic acid, phthalic acid, or terephthalic acid), diols (e.g., ethylene glycol, or propylene glycol) and polydiols (e.g., polyethylene glycol or polypropylene glycol). The copolyester may also include monomeric units substituted with anionic groups such as, for example, sulfonated isophthaloyl units. Examples of such materials include oligomeric esters produced by transesterification / oligomerization of poly(ethylene glycol) methyl ether, dimethyl terephthalate (“DMT”), propylene glycol (“PG”), and poly(ethylene glycol). (“PEG”); partially and fully anionic end-terminated oligomeric esters such as ethylene glycol (“EG”), PG, DMT and Na-3,6-dioxa-8- oligomers hydroxyoctanesulfonate; oligomeric compounds of block polyester with non-ionic coating, such as those produced from DMT, PEG and EG and / or PG coated with Me, or a combination of DMT, EG and / or PG, PEG coated with Me and dimethyl-5-sulfoisophthalate of sodium and ethylene terephthalate copolymeric blocks or propylene terephthalate with polyethylene oxide or polypropylene oxide terephthalate. Other types of SRP for use in the invention include cellulosic derivatives such as hydroxyether cellulosic polymers, C1-C4 alkyl celluloses and C4 hydroxyalkyl celluloses; polymers with hydrophobic segments of 33 poly(vinyl ester) such as poly(vinyl ester) graft copolymers, for example, Ci-Ce vinyl esters (such as poly(vinyl acetate)) grafted onto polyalkylene oxide backbones; poly(vinylcaprolactam) and related copolymers with monomers such as vinylpyrrolidone and / or dimethylaminoethyl methacrylate; and polyester-polyamide polymers prepared by condensing adipic acid, caprolactam and polyethylene glycol. The preferred SRPs for use in the invention include copolyesters formed by condensation of terephthalic acid ester and diol, preferably 1,2-propanediol, and further comprising an end cap formed from repeating alkylene oxide units terminated with an alkyl group. Examples of such materials have a structure corresponding to the general formula (VI): (VI) where R14 and R15 are, independently of each other, X-(OC2H4)q-(OC3H6)s; where X is C1-4 alkyl and preferably methyl; q is a number from 12 to 120, preferably from 40 to 50; s is a number from 1 to 10, preferably from 1 to 7; and i is a number from 4 to 9. Because they are averages, q, sei are not necessarily whole numbers for the bulk polymer. Also Mixtures of any of the materials described above. The overall level of SRP, when included, can range from 0.1 to 10% by weight of the composition, depending on the level of polymer intended to be used in the final composition, and is desirable to be between 0.3 and 7%, more preferably between 0.5 and 5%, based on the total weight of the composition and including all intervals within. Suitable SRPs are described in greater detail in US Patents Nos. 5,574,179; 4,956,447; 4,861,512; 4,702,857, WO 2007 / 079850 and WO2016 / 005271. If used, the SRPs will typically be incorporated into the composition hereof at concentrations ranging from 0.01 to 10%, more preferably from 0.1% to 5% by weight of the composition. Polymeric cleaning boosters To further improve the environmental profile of the composition, it may be preferable in some cases to reduce the volume of composition dosed per wash load and add several weight-efficient ingredients to enhance the cleaning capacity. In addition to the soil-releasing polymers of the invention described above, a composition of the invention will preferably contain one or more additional polymeric cleaning boosters such as anti-redeposition polymers. Anti-redeposition polymers stabilize the dirt in the washing solution, thus preventing redeposition. The appropriate anti-redeposition polymers for your The materials used in the invention include alkoxylated polyethyleneimines. Polyethyleneimines are materials composed of ethyleneimine units -CH2CH2NH- and, when branched, the hydrogen on the nitrogen is replaced by another chain of ethyleneimine units. The alkoxylated polyethyleneimines preferred for use in the invention have a polyethyleneimine backbone of approximately 300 to approximately 10,000 weight average molecular weight (Mw). The polyethyleneimine backbone may be linear or branched. It may be branched to the extent that it is a dendrimer. The alkoxylation may typically be ethoxylation or propoxylation, or a mixture of both. When a nitrogen atom is alkoxylated, a preferred average degree of alkoxylation is 10 to 30, preferably 15 to 25 alkoxy groups per modification.A preferred material is ethoxylated polyethyleneimine, with an average degree of ethoxylation of 10 to 30, preferably 15 to 25 ethoxy groups per ethoxylated nitrogen atom in the polyethyleneimine main chain. Mixtures of any of the materials described above can also be used. When included, a composition of the invention shall preferably comprise from 0.025 to 8% by weight of one or more anti-redeposition polymers such as, for example, the alkoxylated polyethyleneimines described above. Preservative The composition preferably comprises a preservative or a mixture of preservatives. Preferably, the preservative is selected from benzoic acid and its salts, alkyl esters of p-hydroxybenzoic acid and its salts, acid Sorbic acid, diethyl pyrocarbonate, dimethyl pyrocarbonate, preferably benzoic acid and its salts, more preferably sodium benzoate. The preservative is preferably present in an amount of 0.01 to 3% by weight of the composition, preferably from 0.3% to 1.5%. The weights are calculated for the protonated form. Fluorescent agent It may be advantageous to include fluorescent agents (optical brighteners) in the compositions. Usually, these fluorescent agents are supplied and used in the form of their alkali metal salts, for example, sodium salts. The total amount of the fluorescent agent or agents used in the composition is generally from 0.005 to 2%, more preferably from 0.01 to 0.5% by weight of the composition. The preferred classes of fluorescent agents are: di-styryl biphenyl compounds, for example, Tinopal (trade name) CBS-X, di-aminestilbenodisulfonic acid compounds, for example, Tinopal DMS pure Xtra, Tinopal 5BMGX and Blankophor (registered trademark) HRH, and pyrazoline compounds, for example, Blankophor SN. The preferred fluorescent agents are: sodium 2-(4-styryl-3-sulfophenyl)-2H-naphthol[1,2-d]triazole, disodium 4,4'-bis{[(4-anilino-6-(N-methyl-N-2-hydroxyethyl)amino-1,3,5-triazin-2-yl)]amino}stilbene-2,2'-disulfonate, 4,4'- bis{[(4-anilino-6-morpholino-1,3,5)-triazin-2-yl)]amino}stilbene-2,2'-disulfonate disodium and 4,4'-bis(2-sulfostyryl)biphenyl disodium. Most preferably, the fluorescing agent is a di-styryl biphenyl compound, preferably 2,2'-([1,1'-biphenyl]-4,4'-diylbis(ethen-2,1-diyl))dibenzenesulfonate sodium (CAS No. 27344-41-8). Antifoam The composition may also include an antifoaming agent. Antifoaming materials are well known in the art and include silicones, fatty acids, fatty alcohols, and EO-PO block copolymers. Preferably, when present, the fatty acid antifoam is present at 1.3 to 3.0% by weight of the composition, more preferably from 1.4 to 2.0% and the most preferably from 1.6 to 1.65%. Suitable fatty acids in the context of this invention include aliphatic carboxylic acids of formula R12COOH, where R12 is a linear or branched alkyl or alkenyl chain containing 6 to 24, more preferably 10 to 22, most preferably 12 to 18 carbon atoms and 0 or 1 double bonds. Preferred examples of such materials include C12-18 saturated fatty acids such as lauric acid, myristic acid, palmitic acid, or stearic acid; and mixtures of fatty acids in which 50 to 100% (by weight based on the total weight of the mixture) consists of C12-18 saturated fatty acids. Such mixtures may typically be derived from natural fats and / or optionally hydrogenated natural oils (such as coconut oil, palm kernel oil, or tallow). Fatty acids may be present in the form of their sodium, potassium or ammonium salts and / or in the form of soluble salts of organic bases, such as mono-, di- or triethanolamine. The appropriate fatty alcohols in the context of this The invention includes aliphatic alcohol of the formula R13OH, wherein R13 is a linear alkyl or alkenyl chain or 38 2279571 38 of 77 branched containing from 6 to 24, more preferably from 10 to 22, most preferably from 12 to 18 carbon atoms. The EO-PO block copolymers suitable in the context of the present invention include a polymer with repeating units of ethylene oxide and propylene oxide and with a hydrophilic-lipophilic equilibrium (HLB) value equal to or less than 4. Mixtures of any of the materials described above can also be used. For formula accounting purposes, in the formulation, fatty acids and / or their salts (as defined above) are not included in the surfactant level or the adjuvant level. Shading dyes A shading dye can be used to improve the performance of compositions. The preferred dyes are violet or blue. It is believed that applying a low level of a dye in these shades to fabrics masks the yellowing of the fabrics. Another advantage of shading dyes is that they can be used to mask any yellow tint in the composition itself. Shading dyes are well known in the technique of the liquid formulation for washing clothes. Suitable and preferred dye classes are described below. continuation. Direct dyes: Direct dyes (also known as substantive dyes) are a class of water-soluble dyes that have an affinity for fibers and are absorbed directly. Direct violet and direct blue dyes are preferred. Bis-azo or tris-azo dyes are preferably used. Ideally, the direct dye is a direct violet of the following structures: n(NaO3S) where: Rings D and E can independently be naphthyl or phenyl as shown; Ri is selected independently from: hydrogen and C1-C4 alkyl, preferably hydrogen; R2 is selected from: hydrogen, C1-C4 alkyl, phenyl substituted or unsubstituted and substituted or unsubstituted naphthyl, preferably phenyl; R3 and R4 are selected independently from: hydrogen and C1-C4 alkyl, preferably hydrogen or methyl; X and Y are independently selected from: hydrogen, C1-C4 alkyl and C1-C4 alkoxy; preferably, the dye has X = methyl; and Y = methoxy and n is 0, 1 or 2, preferably 1 or 2. The preferred dyes are direct violet 7, direct violet 9, direct violet 11, direct violet 26, direct violet 31, direct violet 35, direct violet 40, direct violet 41, direct violet 51, and direct violet 99. Dyes containing bis-azo copper, for example, direct violet 66, may be used. Benzidene-based dyes are less preferred. Preferably, the direct dye is present at 0.000001 to 1%, more preferably 0.00001% to 0.0010% by weight of the composition. In another embodiment, the direct dye can be covalently bonded to the photobleach, for example, as described in document WO 2006 / 024612. Acid dyes: Substantive acid dyes for cotton offer benefits to garments containing cotton. Dyes and blends The preferred dyes are blue or violet. The preferred acidic dyes are: (i) azine dyes, wherein the dye has the following central structure: Yo Rb N'Rc Yo Rd wherein Ra, Rb, Rc and Rd are selected from: H, a branched or linear C1 to C7 alkyl chain, benzyl, phenyl and naphthyl; the dye is substituted with at least one SO3- or -COO- group; ring B does not bear a negatively charged group or a salt thereof; and Ring A can be further substituted to form a naphthyl; the dye is optionally substituted with selected groups of: amine, methyl, ethyl, hydroxyl, methoxy, ethoxy, phenoxy, Cl, Br, I, F and NO2. The preferred azine dyes are: acid blue 98, acid violet 50 and acid blue 59, most preferably acid violet 50 and acid blue 98. Other preferred non-azine acid dyes are acid violet 17, acid black 1, and acid blue 29. Preferably, the acid dye is present in an amount of 0.0005% to 0.01% by weight of the premix. Hydrophobic dyes: The composition may comprise one or more hydrophobic dyes selected from benzodifurans, methine, triphenylmethanes, naphthalimides, pyrazole, naphthoquinone, anthraquinone, and chromophores of monoazo or diazo dyes. Hydrophobic dyes are dyes that do not contain any water-solubilizing charged group. Hydrophobic dyes may be selected from the groups of disperse and solvent dyes. Anthraquinone blue and violet and monoazo dye are preferred. Preferred dyes include solvent violet 13, disperse violet 27, disperse violet 26, disperse violet 28, disperse violet 63, and disperse violet 77. Preferably, the hydrophobic dye is present in an amount of 0.0001% to 0.005% by weight of the composition. Basic dyes: Basic dyes are organic dyes that have a net positive charge. They are deposited onto cotton. They are particularly useful for use in compositions that predominantly contain cationic surfactants. The dyes can be selected from the basic violet and basic blue dyes listed in the Colour Index International. Preferred examples include basic triarylmethane dyes, basic methane dye, basic anthraquinone dyes, basic blue 16, basic blue 65, basic blue 66, basic blue 67, basic blue 71, basic blue 159, basic violet 19, basic violet 35, basic violet 38, basic violet 48; basic blue 3, basic blue 75, basic blue 95, basic blue 122, basic blue 124, basic blue 141. Reactive dyes: Reactive dyes are dyes that contain an organic group capable of reacting with cellulose and bonding the dye to the cellulose with a covalent bond. They are deposited onto cotton. Preferably, the reactive group is hydrolyzed, or the reactive group of the dyes is reacted with an organic species, for example, a polymer, to bind the dye to this species. The dyes can be selected from the reactive violet and reactive blue dyes listed in the Colour Index International. Preferred examples include reactive blue 19, reactive blue 163, reactive blue 182, and reactive blue 96. Dyes combinations: Dye conjugates are formed by bonding direct, acidic, or basic dyes to polymers or particles through physical forces. Depending on the choice of polymer or particle, they are deposited onto cotton or synthetic materials. A description is provided in WO 2006 / 055787. The particularly preferred dyes are: direct violet 7, direct violet 9, direct violet 11, direct violet 26, direct violet 31, direct violet 35, direct violet 40, direct violet 41, direct violet 51, direct violet 99, acid blue 98, acid violet 50, acid blue 59, acid violet 17, acid black 1, acid blue 29, solvent violet 13, disperse violet 27, disperse violet 26, disperse violet 28, disperse violet 63, disperse violet 77 and mixtures of the same. A shading dye may be used in the absence of fluorescent agents, but it is especially preferred to use a shading dye in combination with a fluorescent agent, for example, to reduce yellowing due to chemical changes in the adsorbed fluorescent. External structuring elements Compositions can have their rheology further modified by the use of a material or materials that form a structuring network within the composition. Examples of such materials include hydrogenated castor oil, microfibrous cellulose, and citrus pulp fiber. The presence of an external structuring agent can provide a shear-thinning rheology and can also allow materials such as encapsulants and visual cues to be stably suspended in the liquid. Fragrances Fragrances are well known in the art and can be incorporated into the compositions described herein. Preferably, the fragrance is provided as a fragrance oil and, more preferably, the fragrance oil is used as a carrier for the additional antioxidant when employed. Preferably, the fragrance comprises a phenolic and / or ketonic species. Microcapsules One type of microparticle suitable for use in the invention is a microcapsule. Microencapsulation can to be defined as the process of surrounding or enveloping a A substance is encapsulated within another substance on a very small scale, producing capsules that range from less than one micron to several hundred microns in size. The encapsulated material may be called the core, active ingredient or agent, filler, payload, or internal phase. The material that encapsulates the core may be called the coating, membrane, shell, or wall material. Microcapsules typically have at least one continuous, usually spherical, shell surrounding the core. The shell may contain pores, vacancies, or interstitial openings depending on the encapsulation materials and techniques used. Multiple shells may be made of the same or different encapsulating materials and may be arranged in layers of varying thicknesses around the core. Alternatively, microcapsules may have an asymmetric and variable shape with a number of smaller droplets of core material embedded along the microcapsule. The coating can have a barrier function, protecting the core material from the external environment of the microcapsule, but it can also act as a means to modulate the release of core materials such as fragrance. Therefore, a coating can be water-soluble or water-swellable, and fragrance release can be activated in response to the microcapsules' exposure to a humid environment. Similarly, if a coating is temperature-sensitive, a microcapsule could release fragrance in response to elevated temperatures. Microcapsules can also release fragrance in response to shear forces applied to their surface. microcapsules. A preferred type of polymeric microparticle suitable for use in the invention is a polymeric core-shell microcapsule, wherein at least one continuous, generally spherical shell of polymeric material surrounds a core containing the fragrance formulation (f2). The shell typically comprises at most 20% by weight based on the total weight of the microcapsule. The fragrance formulation (f2) typically comprises from approximately 10% to approximately 60% and, preferably, from approximately 20% to approximately 40% by weight based on the total weight of the microcapsule. The amount of fragrance (f2) can be measured by taking a suspension of the microcapsules, extracting them in ethanol, and measuring by alquid chromatography. The core-shell polymeric microcapsules for use in the invention can be prepared using methods known to those skilled in the art, such as coacervation, interfacial polymerization, and polycondensation. The coacervation process typically involves the encapsulation of a core material, usually insoluble in water, by precipitating colloidal material or materials onto the surface of droplets of the core material. Coacervation can be simple, for example, using a colloid such as gelatin, or complex, where two or possibly more colloids of opposite charge, such as gelatin and gum arabic or gelatin and carboxymethylcellulose, are used under carefully controlled conditions of pH, temperature, and concentration. Interfacial polymerization typically proceeds with the Formation of a fine dispersion of oil droplets (the oil droplets containing the core material) in a continuous aqueous phase. The dispersed droplets form the core of the future microcapsule, and their dimensions directly determine the size of subsequent microcapsules. The shell-forming materials of the microcapsules (monomers or oligomers) are contained in both the dispersed phase (oil droplets) and the continuous aqueous phase and react together at the phase interface to form a polymer wall around the oil droplets, encapsulating them and forming core-shell microcapsules. An example of a core-shell microcapsule produced by this method is a polyurea microcapsule with a shell formed by the reaction of diisocyanates or polyisocyanates with diamines or polyamines. Polycondensation involves forming a dispersion or emulsion of the core material in an aqueous solution of a precondensate of polymeric materials under appropriate stirring conditions to produce capsules of a desired size, and adjusting the reaction conditions to cause condensation of the precondensate by acid catalysis, resulting in the condensate separating from the solution and surrounding the dispersed core material to produce a coherent film and the desired microcapsules. An example of a core-shell microcapsule produced by this method is an aminoplast microcapsule with a shell formed from the polycondensation product of melamine (2,4,6-triamino-1,3,5-triazine) or urea with formaldehyde. Suitable crosslinking agents (e.g., toluene diisocyanate, divinylbenzene, butanediol diacrylate) and 48-wall polymers can also be used secondary as appropriate, for example, anhydrides and their derivatives, particularly polymers and copolymers of maleic anhydride. An example of a preferred polymeric core-shell microcapsule for use in the invention is an aminoplast microcapsule with an aminoplast shell surrounding a core containing the fragrance formulation (f2). More preferably, said aminoplast shell is formed from the polycondensation product of melamine with formaldehyde. The polymeric microparticles suitable for use in the inventions will generally have an average particle size between 100 nanometers and 50 microns. Particles larger than this are entering the visible range. Examples of particles in the submicron range include latex and miniemulsions with a size range of typical size range of 100 to 600 nanometers. The size range of The preferred particle size is in the micron range. Examples of particles in the micron range include polymer core-shell microcapsules (such as those described above) with a typical size range of 1 to 50 microns, preferably 5 to 30 microns. The mean particle size can be determined by light scattering using a Malvern Mastersizer, taking the mean particle size as the mean value of the particle size D(0.5). The particle size distribution can be narrow, broad, or multimodal. If necessary, such microcapsules As they were initially produced, they can be filtered or sieved to produce a product with greater uniformity in size. The polymeric microparticles suitable for use in the The invention can be provided with a deposition aid on the outer surface of the microparticle. The deposition aids serve to modify the properties of the microparticle's exterior, for example, to make the microparticle more suitable for a desired substrate. Desired substrates include cellulosics (including cotton) and polyesters (including those used in the manufacture of polyester fabrics). The deposition aid can be adequately provided on the outer surface of the microparticle by means of covalent bonding, cross-linking, or strong adsorption. Examples include polymeric core-shell microcapsules (such as those described in more detail above) in which a deposition aid is attached to the outer shell, preferably by means of covalent bonds. While it is preferred that the deposition aid adhere directly to the outer shell, it can also be attached by some type of bond. The deposition aids for use in the invention can be suitably selected from polysaccharides that have an affinity for cellulose. Such polysaccharides can be of natural or synthetic origin and can have an intrinsic affinity for cellulose or can have been derivatized or otherwise modified to have an affinity for cellulose. Suitable polysaccharides have a 1-4 linkage p-glycan (generalized sugar) backbone structure with at least 4, and preferably at least 10, backbone residues linked to p-14, such as a glucan backbone (consisting of glucose residues linked to p-14), a mannan backbone (consisting of residues of mannose linked to pi-4) or a xylan backbone (consisting of xylose residues linked to pi-4). Examples of such pi-4-linked polysaccharides include xyloglucans, glucomannans, mannans, galactomannans, p(1-3),(1-4)glucan, and the xylan family incorporating glucurono-, arabino- and glucuronoarabinoxylans. The preferred pi-4 linked polysaccharides for use in the invention may be selected of plant-derived xyloglucans, such as pea xyloglucan and tamarind seed xyloglucan (TXG) (which has a pi-4 linked glucan backbone with αD-xylopyranose and pD- side chains) galactopyranosyl-(1-2)-aD-xylopyranose, both linked 1-6 to the main chain); and plant-derived galactomannans such as locust bean gum (LBG) (which has a mannan main chain of mannose residues linked to pi-4, with single-unit galactose side chains linked to ai-6 with the main chain). Also suitable are polysaccharides that can gain affinity for cellulose after hydrolysis, such as cellulose monoacetate; or modified polysaccharides with affinity for cellulose, such as hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylmethylcellulose, hydroxypropylguar, hydroxyethylcellulose and methylcellulose. The deposition aids for use in the invention may also be selected from phthalate-containing polymers that have an affinity for polyester. Such phthalate-containing polymers may have one or more nonionic hydrophilic segments comprising oxyalkylene groups (such as oxyethylene, polyoxyethylene, oxypropylene, or polyoxypropylene groups) and one or more hydrophobic segments comprising terephthalate groups. Typically, the oxyalkylene groups will have a degree of polymerization of 51 from 1 to approximately 400, preferably from 100 to approximately 350, more preferably from 200 to approximately 300. A suitable example of a phthalate-containing polymer of this type is a copolymer having random blocks of ethylene terephthalate and polyethylene oxide terephthalate. Mixtures of any of the materials described above may also be suitable. The deposition aids for use in the invention will generally have a weight mean molecular weight (Mw) in the range of approximately 5 kDa to approximately 500 kDa, preferably from approximately 10 kDa to approximately 500 kDa and more preferably from approximately 20 kDa to approximately 300 kDa. An example of a particularly preferred polymeric core-shell microcapsule for use in the invention is an aminoplast microcapsule with a shell formed by polycondensation of melamine with formaldehyde, surrounding a core containing the fragrance formulation (f2), wherein a deposition aid is attached to the exterior of the shell by means of a covalent bond. The preferred deposition aid is selected from pi-4-linked polysaccharides and, in particular, xyloglucans of plant origin, as further described above. The present inventors have surprisingly observed that it is possible to reduce the total level of fragrance included in the composition of the invention without sacrificing the overall fragrance experience provided to the consumer at key stages of the washing process. A reduction in the Total fragrance level is advantageous for environmental and cost reasons. Accordingly, the total amount of fragrance formulation (f1) and fragrance formulation (f2) in the concentrated laundry composition of the invention varies appropriately from 0.5 to 1.4%, preferably from 0.5 to 1.2%, more preferably from 0.5 to 1%, and most preferably from 0.6 to 0.9% (by weight based on the total weight of the concentrated laundry composition). The weight ratio of fragrance formulation (f1) to fragrance formulation (f2) in the composition of the invention preferably varies from 60:40 to 45:55. Particularly good results have been obtained with a weight ratio of fragrance formulation (f1) to fragrance formulation (f2) of approximately 50:50. The fragrance (f1) and fragrance (f2) are typically incorporated at different stages of the composition formation of the invention. Normally, the discrete polymeric microparticles (for example, Microcapsules that trap the fragrance formulation (f2) are added as a suspension to a heated base formulation comprising other composition components (such as surfactants and solvents). The fragrance (f1) is typically post-dosed later, after the base formulation has cooled. Other ingredients The composition may contain additional optional ingredients to improve performance and / or consumer acceptability. Examples of such Ingredients include foam-boosting agents, 53 Polyelectrolytes, anti-shrink agents, anti-wrinkle agents, antioxidants, sunscreens, anti-corrosion agents, drape-imparting agents, anti-static agents, ironing aids, colorants, pearlescent agents, and / or opacifiers. Each of these ingredients will be present in an amount effective to achieve its purpose. In general, these optional ingredients are included individually in an amount of up to 5% based on the total weight of the composition. Many of the ingredients used in the embodiments of the invention can be obtained from so-called carbon black sources or a more sustainable, green source. A list of alternative sources for several of these ingredients and how they can be converted into the raw materials described herein is provided below. SLES and PAS SLES and other anionic alkali metal alkyl ether sulfate surfactants of this type are typically obtained via sulfating alcohol ethoxylates. These alcohol ethoxylates are typically obtained by ethoxylation of linear alcohols. Similarly, primary alkyl sulfate (PAS) surfactants can be obtained from linear alcohols by directly sulfated. Therefore, the formation of the linear alcohol is a central step in the preparation of both PAS and alkali metal alkyl ether sulfate surfactants. Linear alcohols are suitable as an intermediate step in the manufacture of alcohol ethoxylates and, therefore, anionic surfactants such as lauryl Sodium ether sulfate can be obtained from many different sustainable sources. These include: Primary sugars Primary sugars are obtained from sugarcane or sugar beets, etc., and can be fermented to form bioethanol. The bioethanol is then dehydrated to form bioethylene, which subsequently undergoes olefin metathesis to form alkenes. These alkenes are then processed into linear alcohols by either hydroformylation or oxidation. An alternative process can also be used that employs primary sugars to form linear alcohols, where the primary sugar undergoes microbial conversion by algae to form triglycerides. These triglycerides are then hydrolyzed to linear fatty acids and subsequently reduced to form linear alcohols. Biomass Biomass, such as forest products, rice husks, and straw, to name a few, can be processed into synthesis gas through gasification. Through a Fischer-Tropsch reaction, these are processed into alkanes, which are then dehydrogenated to form olefins. These olefins can be processed in the same way as the alkenes described earlier [primary sugars]. An alternative process converts the same biomass into polysaccharides by steam explosion, which can be enzymatically degraded into secondary sugars. These secondary sugars are then fermented to form bioethanol, which, in turn, is dehydrated to form bioethylene. Bioethylene is then processed into linear alcohols as previously described [primary sugars]. Plastic waste The waste plastic is pyrolyzed to form pyrolysis oils. These are then fractionated to form linear alkanes, which are dehydrogenated to form alkenes. These alkenes are processed as previously described [primary sugars]. Alternatively, the pyrolyzed oils are cracked to form ethylene, which is then processed to form the required alkenes via olefin metathesis. These are then processed into linear alcohols as previously described [primary sugars]. Urban solid waste (MSW) Municipal solid waste (MSW) is converted into synthesis gas by gasification. From the synthesis gas, it can be processed into alkanes as previously described (primary sugars) or converted into ethanol via enzymatic processes before being dehydrogenated into ethylene. The ethylene can then be converted into linear alcohols via the Ziegler process. Municipal solid waste (MSW) can also be converted into pyrolysis oil by gasification and then fractionated to form alkanes. These alkanes are then dehydrogenated to form olefins and then linear alcohols. Marine carbon There are several sources of carbon from marine flora, such as algae and seaweed. From this marine flora, triglycerides can be separated from the source and then... hydrolyze to form fatty acids which are reduced to linear alcohols in the usual way. Alternatively, the raw material can be separated into polysaccharides that are enzymatically degraded to form secondary sugars. These can then be fermented to form bioethanol and subsequently processed as previously described [primary sugars]. Waste oils Waste oils, such as used cooking oil, can be physically separated into triglycerides which are further broken down to form linear fatty acids and then linear alcohols as previously described. Alternatively, used cooking oil can be subjected to the Neste Process, whereby the oil is catalytically cracked to form bioethylene. It is then processed as described above. Methane capture Methane capture methods capture methane from landfills or fossil fuel production. The methane can be converted into synthesis gas by gasification. The synthesis gas can be processed as previously described, whereby the synthesis gas is converted to methanol (Fischer-Tropsch reaction) and then to olefins before being converted to linear alcohols by oxidation via hydroformylation. Alternatively, the synthesis gas can be converted into alkanes and then olefins by Fischer-Tropsch and then dehydrogenation. Carbon capture Carbon dioxide can be captured by any of a variety of well-known processes. Carbon dioxide can be converted to carbon monoxide via a reverse water-gas exchange reaction, which, in turn, can be converted to synthesis gas using hydrogen gas in an electrolytic reaction. The synthesis gas is then processed as previously described and converted to methanol and / or alkanes before reacting to form olefins. Alternatively, the captured carbon dioxide is mixed with hydrogen gas before being enzymatically processed to form ethanol. This is a process that has been developed by Lanzatech. From there, the ethanol is converted into ethylene and then processed into olefins and finally into linear alcohols as previously described. The above processes can also be used to obtain the C16 / 18 chains of the C16 / 18 alcohol ethoxylate and / or the C16 / 18 ether sulfates. Packaging and dosing The composition may be formulated in any suitable physical form, including powders, granules, tablets, liquids, etc. Preferably, the composition is provided in liquid form. More preferably, the composition is a liquid detergent composition such as a liquid laundry detergent or a liquid dishwashing liquid; even more preferably, the composition is a liquid laundry detergent. The composition of the invention can be supplied in multi-dose plastic containers with a top closure or lower. A dosage measure can be supplied with the package as part of the cap or as an integrated system. Alternatively, the composition of the invention can be packaged as unit doses in a water-soluble polymeric film. The unit-dose composition of the invention is contained within a pouch formed by a water-soluble film. Preferably, the pouch has from one to four compartments. More preferably, the pouch has three compartments. It is preferred that the pouch be a unit dose of product and may have a weight of 10 to 50 g to represent one unit dose. Such compositions of water-soluble films, the optional ingredients for use in them, and the methods for making them are well known in the art, whether they are used to make relatively thin water-soluble films (e.g., as bag materials) or otherwise. In one class of embodiments, the water-soluble film includes a water-soluble material. Such preferred materials include polyvinyl alcohol (PVOH), including homopolymers thereof (e.g., comprising substantially only monomeric units of vinyl alcohol and vinyl acetate) and copolymers thereof (e.g., comprising one or more monomeric units in addition to the vinyl alcohol and vinyl acetate units). PVOH is a synthetic resin generally prepared by alcoholysis, generally referred to as hydrolysis or saponification, of polyvinyl acetate. Fully hydrolyzed PVOH, in which Virtually all acetate groups have been converted to alcohol groups. It is a highly crystalline polymer, strongly hydrogen-bonded, that dissolves only in hot water, above approximately 140 degrees Fahrenheit (60 degrees Celsius). If a sufficient number of acetate groups are allowed to remain after the hydrolysis of polyvinyl acetate, the PVOH polymer is known as partially hydrolyzed. It has weaker hydrogen bonds, is less crystalline, and is soluble in cold water below 50 degrees Fahrenheit (10 degrees Celsius). A cold- or intermediate-hot-water-soluble film may include, for example, intermediate partially hydrolyzed PVOH (e.g., with degrees of hydrolysis of approximately 94 percent to approximately 98 percent), and is readily soluble only in warm water, for example, dissolving rapidly at temperatures around 40 degrees Celsius and above.Both the fully and partially hydrolyzed PVOH types are commonly known as PVOH homopolymers, although the partially hydrolyzed type is technically a copolymer of vinyl acetate and vinyl alcohol. The degree of hydrolysis (DH) of the PVOH polymers and PVOH copolymers included in the water-soluble films of this disclosure may be in the range of approximately 75 percent to approximately 99 percent (e.g., approximately 79 percent to approximately 92 percent, approximately 86.5 percent to approximately 89 percent, or approximately 88 percent, as for cold water-soluble compositions; approximately 90 percent to approximately 99 percent, approximately 92 percent to approximately 99 percent, or approximately 95 percent to approximately 99 percent). As the degree of hydrolysis decreases, a film made of resin will have reduced mechanical strength but faster solubility at temperatures below about 20 degrees Celsius. As the degree of hydrolysis increases, a film made of polymer will tend to be mechanically stronger, and thermoformability will tend to decrease. The degree of hydrolysis of PVOH can be chosen so that the water solubility of the polymer depends on the temperature, and therefore the solubility is also influenced. of a film made of the polymer, any compatibilizer polymer, and additional ingredients. In one option, The film is soluble in cold water. A film soluble in cold water, soluble in water at a temperature below 10 degrees Celsius, may include PVOH with a degree of hydrolysis in the range of approximately 75 percent to approximately 90 percent, or in the range of approximately 80 percent to approximately 90 percent, or in the range of approximately 85 percent to approximately 90 percent. Alternatively, the film is soluble in hot water. A hot water-soluble film, soluble in water at a temperature of at least about 60 degrees Celsius, may include PVOH with a degree of hydrolysis of at least 98 percent. Other water-soluble polymers for use in addition to PVOH polymers and PVOH copolymers in the mixture may include, but are not limited to, modified polyvinyl alcohols, polyacrylates, water-soluble acrylate copolymers, polyvinylpyrrolidone, polyethyleneimine, pullulan, and natural water-soluble polymers including, but not limited to, guar gum, gum arabic, xanthan gum, carrageenan, and starch derivatives of Water-soluble polymers include, but are not limited to, modified starches, ethoxylated starch, and hydroxypropyl starch, copolymers of the foregoing, and combinations thereof. Other water-soluble polymers may include polyalkylene oxides, polyacrylamides, polyacrylic acids and salts thereof, celluloses, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts thereof, polyamino acids, polyamides, gelatins, methylcelluloses, carboxymethylcelluloses and salts thereof, dextrins, ethylcelluloses, hydroxyethylcelluloses, hydroxypropyl methylcelluloses, maltodextrins, and polymethacrylates. Such water-soluble polymers, whether PVOH or otherwise, are commercially available from a variety of sources. Any of the above water-soluble polymers is generally suitable for use as film-forming polymers.In general, the water-soluble film may include copolymers and / or mixtures of the above resins. Water-soluble polymers (e.g., PVOH resin alone or in combination with other water-soluble polymers) may be included in the film in amounts ranging from approximately 30 or 50 percent by weight to approximately 90 or 95 percent by weight, for example. The weight ratio of the amount of all water-soluble polymers to the combined amount of all plasticizers, compatibilizers, and secondary additives may range from approximately 0.5 to approximately 18, approximately 0.5 to approximately 15, approximately 0.5 to approximately 9, or approximately 0.5 to approximately 5, from approximately 1 to approximately 3, or from approximately 1 to approximately 2, for example. The specific quantities of plasticizers and other non-polymeric components can be selected in a particular embodiment based on an intended application of the water-soluble film to adjust the film's flexibility and impart processing benefits in view of the desired mechanical properties of the film. Water-soluble polymers for use in the film described herein (including, but not limited to, PVOH polymers and PVOH copolymers) can be characterized by a viscosity in a range of approximately 3.0 to approximately 27.0 cP, of approximately 4.0 to approximately 24.0 cP, of approximately 4.0 to approximately 23.0 cP, of approximately 4.0 cP approximately 15 cP, or of approximately 6.0 to approximately 10.0 cP, for example. The viscosity of a polymer is determined by measuring a freshly prepared solution using a Brookfield LV-type viscometer with a UL adapter as described in the Brookfield test method, British Standard EN ISO 15023-2:2006 Annex E. It is an international practice to establish the viscosity of 4 percent aqueous solutions of polyvinyl alcohol at 20 degrees Celsius. Polymer viscosities specified herein in cP should be understood as the viscosity of a 4 percent aqueous solution of water-soluble polymer at 20 degrees Celsius, unless otherwise specified. It is well known in the art that the viscosity of a water-soluble polymer (PVOH or other type) is correlated with the weight average molecular weight (W) of the same polymer, and viscosity is often used as a proxy for Mw. Therefore, the weight-average molecular weight of water-soluble polymers, including the first PVOH copolymer and the second PVOH polymer, may be in the range of approximately 30,000 to approximately 175,000, or approximately 30,000 to approximately 100,000, or approximately 55,000 to approximately 80,000, for example. The water-soluble film may contain other auxiliary agents and processing agents, such as, but not limited to, plasticizers, plasticizer compatibilizers, surfactants, lubricants, release agents, fillers, extenders, crosslinking agents, antiblocking agents, antioxidants, anti-adherents, antifoaming agents, nanoparticles such as layered silicate-type nanoclays (e.g., sodium montmorillonite), bleaching agents (e.g., sodium metabisulfite, sodium bisulfite, or others), aversive agents such as bittering agents (e.g., denatonium salts such as denatonium benzoate, denatonium saccharide, and denatonium chloride; sucrose octaacetate; quinine; flavonoids such as quercetin and naringin; and quassinoids such as quassin and brucine) and pungent agents (e.g., capsaicin, piperine, allyl isothiocyanate, and resinferatoxin), and other functional ingredients, in quantities appropriate for their intended purpose.Embodiments including plasticizers are preferred. The amount of such agents may be up to approximately 50% by weight, 20% by weight, 15% by weight, 10% by weight, 5% by weight, 4% by weight and / or at least 0.01% by weight, 0.1% by weight, 1% by weight, or 5% by weight, individually or collectively. The plasticizer may include, but is not limited to, glycerin, diglycerin, sorbitol, ethylene glycol, diethylene glycol, triethylene glycol, dipropylene glycol, Tetraethylene glycol, propylene glycol, polyethylene glycols up to 400 MW, neopentyl glycol, trimethylolpropane, polyether polyols, sorbitol, 2-methyl-1,3-propanediol, ethanolamines, and a mixture thereof. A preferred plasticizer is glycerin, sorbitol, triethylene glycol, propylene glycol, dipropylene glycol, 2-methyl-1,3-propanediol. trimethylolpropane or a combination thereof. The total amount of plasticizer may range from approximately 10 percent by weight to approximately 40 percent by weight, or from approximately 15 percent by weight to approximately 35 percent by weight, or from approximately 20 percent by weight to approximately 30 percent by weight, for example, approximately 25 percent by weight, based on the total weight of the film. Combinations of glycerin, dipropylene glycol, and sorbitol may be used. Optionally, glycerin may be used in an amount from approximately 5 percent by weight to approximately 30 percent by weight, or from approximately 5 percent by weight to approximately 20 percent by weight, for example, approximately 13 percent by weight. Optionally, dipropylene glycol may be used in an amount of approximately 1 percent by weight to approximately 20 percent by weight, or from approximately 3 percent by weight to approximately 10 percent by weight, for example, from 6 percent by weight. Optionally, sorbitol may be used in an amount of approximately 1 percent by weight to approximately 20 percent by weight, or from approximately 2 percent by weight to approximately 10 percent by weight. 65 For example, approximately 5 percent by weight. The specific amounts of plasticizers can be selected for a particular embodiment based on the desired film flexibility and the processability characteristics of the water-soluble film. At low levels of plasticizer, films may become brittle, difficult to process, or prone to tearing. At high levels of plasticizer, films may be too soft, weak, or difficult to process for a desired use. In a preferred embodiment, the composition comprises an aversive taste such as denatonium benzoate and / or a pungent agent such as capsaicin. Examples Example 1 Materials Protease: Carnival Evity 16L Amylase: Amplify Prime 100L Lipase: Lipex 100L Pectate lyase: Xpect 1000L / T Cellulase: Celluclean 5000L Cardanol polyoxyethylene ether sulfate: Nasurfar NSN3003 Biomaterial Technology Co. Ltd Preparation of compositions Linear alkylbenzene sulfonate (LAS) and cardanol polyoxyethylene ether sulfate (CES) surfactants were dissolved in deionized water (DI) to prepare a 15 wt% aqueous solution. Pure DI water was used as Control. All solutions were freshly prepared and checked to ensure complete dissolution of the surfactants. The compositions were prepared by adding various enzymes to the previously mentioned aqueous solutions. The enzyme dosages are shown in Table 1. Table 1 Enzyme Guy % by weight in the composition Carnival Event 16L Protease 0.5 Amplify Prime 100L Amylase 0.2 Lipex 100L Lipase 0.3 Xpect 1000L / T Pectate lyase 0.2 Celluclean 5000L Cellulase 0.3 Method for measuring enzyme activity Protease activity Protease activity was measured using a method that employed the substrate Suc-AAPF-PNA. Suc-AAPF-PNA is an abbreviation for N-Succinyl-Alanine-Alanine-Proline- Phenylalanine-p-Nitroanilide (PNA) is a latent peptide that can be cleaved by endoproteases. After cleavage, a free PNA molecule is released, which is yellow and can therefore be measured by visible spectrophotometry at a wavelength of 405 nm. The increase in absorbance due to PNA formation is proportional to the protease activity in the sample. The reaction is monitored in situ, and the change in absorbance at 405 nm per unit time is calculated. The protease activity is automatically calculated with reference to a calibration curve of a corresponding reference standard. Amylase activity Amylase activity was measured using a method that employed the substrate G7-pNP. G7-pNP, which is an abbreviation for 4,6-ethylidene (G7)-p-nitrophenyl (G1)-a, D- maltoheptaoside (ethylidene-G7pNP), an oligosaccharide blocked that can be cleaved by an endoamylase, such as α-amylase. The hydrolyzed substrate further reacts with α-glucosidase to release a free pNP molecule that is yellow and can therefore be measured by visible spectrophotometry at a wavelength of 405 nm. The increase in absorbance, due to the formation The absorbance of pNP is proportional to the amylase activity in the sample. The reaction is monitored in situ, and the change in absorbance at 405 nm per unit time is calculated. Amylase activity is automatically calculated with reference to a calibration curve of a corresponding reference standard. Lipase activity Lipase activity was measured using a method that employs the p-nitrophenylacyl ester substrate, which can be cleaved by lipase to release a free p-nitrophenol molecule. The p-nitrophenol molecule is yellow and can therefore be measured by visible spectrophotometry at a wavelength of 405 nm. The increase in absorbance, due to the formation of p-nitrophenol, is proportional to the lipase activity in the sample. The reaction is monitored in situ, and the change in absorbance at 405 nm per unit time is calculated. Amylase activity is automatically calculated with reference to a calibration curve of a corresponding reference standard. Pectate lyase Pectate lyase activity was measured using a method that employs polygalacturonic acid as a substrate. Pectate lyase cleaves polygalacturonic acid via a trans elimination mechanism. This means that it leaves a carbon-carbon double bond after each cleavage of the substrate. This bond absorbs at 235 nm, allowing for the direct detection of pectate lyase activity in soluble polygalacturonic acid by measuring the absorbance at that wavelength. The absorbance at 235 nm was measured using a microtiter spectrometer (e.g., Molecular Devices, SpectraMAX 190). The absorbance readings were They correct for background absorbance by subtracting the absorbance of a control sample, processed without added enzyme, from all measured values. Cellulase Cellulase activity was measured using a method that employed carboxymethylcellulose as a substrate. The carboxymethylcellulose substrate was hydrolyzed with cellulase at pH 7.5 and 50 °C for 30 min. The reaction was stopped with an alkaline reagent containing 4-hydroxybenzhydrazide (PAHBAH) and bismuth, which forms complexes with the reducing sugar. Complex formation resulted in the production of a color that could be read at 405 nm using a spectrometer. The increase in absorbance due to complex formation was proportional to the cellulase activity in the sample. The reaction was monitored in situ, and the change in absorbance at 405 nm per unit time was calculated. Cellulase activity was automatically calculated with reference to a calibration curve of a corresponding reference standard. The enzymatic activities for the control after preparation (T0) were set at 100%. The compositions were then incubated at 37 °C for two weeks, and the residual enzymatic activities were measured (compared to a T0 time for the control, whose enzymatic activity was set at 100%). The results are shown in Table 2. Table 2 Enzyme Compositions A (water) B (LAS) 1 (CES) Protease 15% 121% 152% Amylase 54% 0% 57% Lipase 23 % 1% 28% Pectate lyase 48% 0% 70% Cellulase 60% 1% 85% The results show that composition 1 (according to the invention) provided much better enzymatic activities compared to other compositions, indicating improved enzymatic stability during storage conditions. CLAIMS 1. A composition characterized in that it comprises: a) an alkyl and / or alkenyl phenol polyoxyalkylene ether anionically modified represented by formula (I) O(R2)mEM (YO) wherein R1 is a linear or branched alkyl or alkenyl group having 11 to 21 carbon atoms; each R2 is an oxyalkylene group having 2 to 4 carbon atoms; m is an integer from 1 to 50; E is a group comprising one or more sulfate, phosphate, carboxylate, sulfonate, sulfosuccinate, sulfoacetate, sarcosinate, and phosphonate groups; M is a solubilizing cation selected from sodium, potassium, ammonium, mono-, di-, tri-alkanolamine, and mixtures thereof; and b) an enzyme 2. The composition according to claim 1, characterized in that R1 is a linear or branched alkyl or alkenyl group having from 13 to 17 carbon atoms, preferably a linear alkyl or alkenyl group having from 13 to 17 carbon atoms. 3. The composition according to claim 1 or claim 2, characterized in that R1 is a linear C15 alkyl or alkenyl group, preferably a linear C15 alkyl or alkenyl group comprising from 0 to 3 carbon-carbon double bonds. 4. The composition according to any of the preceding claims, characterized in that each R2 is an ethylene oxide group. 5. The composition according to any of the preceding claims, characterized in that m is an integer from 1 to 30, preferably from 2 to 15, more preferably from 3 to 10. 6. The composition according to any of the preceding claims, characterized in that the anionically modified alkyl and / or alkenyl phenol polyoxyalkylene ether is anionally modified cardanol polyoxyethylene ether. 7. The composition according to any of the preceding claims, characterized in that the anionically modified alkyl and / or alkenyl phenol polyoxyalkylene ether is cardanol polyoxyethylene ether sulfate, cardanol polyoxyethylene ether phosphate or mixtures thereof, preferably cardanol polyoxyethylene ether sulfate. 8. The composition according to any of the preceding claims, characterized in that the enzyme comprises protease, lipase, amylase, mannanase, pectate lyase, cellulase, phospholipase, cutinase, peroxidase, oxidase or mixtures thereof. 9. The composition according to any of the preceding claims, characterized in that the composition comprises the anionically modified alkyl and / or alkenyl phenol polyoxyalkylene ether in an amount of 0.1% to 30% by weight of the composition, preferably from 0.5% to 20%. 10. The composition according to any of the preceding claims, characterized in that the composition comprises the enzyme in an amount of 0.00001 to 1%, preferably 0.0001 to 0.5%. 11. The composition according to any of the preceding claims, characterized in that the composition further comprises linear alkyl benzenesulfonates. 12. The composition according to any of the preceding claims, characterized in that the composition is substantially free of alkyl ether sulfates. 13. The composition according to any of the preceding claims, characterized in that the composition is a detergent composition, preferably a liquid detergent composition, more preferably a liquid detergent composition for washing clothes. 14. The composition according to any of the preceding claims, characterized in that the composition is in a unit dose format. 15. A method for forming a liquid detergent composition or washing liquor characterized in that it disperses a dose of the composition according to any of the preceding claims in water. Buenos Aires, May 2023 pp UNILEVER GLOBAL IP LIMITED SUMMARY A composition comprising an anionically modified alkyl and / or alkenyl phenol polyoxyalkylene ether is described. represented by formula (I) O(R2)mEM Ri (YO) where R1 is an alkyl or alkenyl group, linear or branched, having 11 to 21 carbon atoms; each R2 is an oxyalkylene group having 2 to 4 carbon atoms; m is an integer from 1 to 50; E is a group comprising one or more of sulfate, phosphate, carboxylate, sulfonate, sulfosuccinate, sulfoacetate, sarcosinate, and phosphonate; M is a solubilizing cation selected from sodium, potassium, ammonium, mono-, di-, tri-alkanolamine, and mixtures thereof; and an enzyme. RICARDO DANIEL RICHELET - 20042804046 Digitally signed by PORTALTRAMITES - INPI Date: 2023.05.24 15:22:36 -03:00 Reason: Digitally Signed by the INPI Location: Buenos Aires, Argentina

Claims

1. A composition characterized in that it comprises: a) an anionally modified alkyl and / or alkenyl phenol polyoxyalkylene ether represented by formula (I) wherein R1 is a linear or branched alkyl or alkenyl group having from 11 to 21 carbon atoms; each R2 is an oxyalkylene group having from 2 to 4 carbon atoms; m is an integer from 1 to 50; E is a group comprising one or more sulfate, phosphate, carboxylate, sulfonate, sulfosuccinate, sulfoacetate, sarcosinate, and phosphonate groups; M is a solubilizing cation selected from sodium, potassium, ammonium, mono-, di-, tri-alkanolamine, and mixtures thereof; and b) an enzyme. 14 Claims follow