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Preparation method of polypropylene millipore filtration sheet material

A technology of microporous filtration and polypropylene, which is applied in the direction of flat products, applications, household appliances, etc., can solve the problem that it is difficult to meet the requirements of polypropylene microporous filter pore density and gas transmission rate, and the micropores are easy to form closed micropores , High production cost and other issues, to achieve the effect of controlling air permeability and pressure bearing performance, low production cost, and short production cycle

Inactive Publication Date: 2009-05-13
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Generally speaking, compared with the extrusion method, it is more economical to use the pressing method to produce polypropylene microporous filter sheets. However, the existing physical foaming-pressing method still has its unsatisfactory places: such as many processes , that is, the raw materials must be granulated, impregnated, washed, dried, pre-foamed, matured, and pressed to produce products, which has a long cycle and high production costs; secondly, because it is produced after pre-foaming and aging, Therefore, the obtained polypropylene microporous filter sheet is relatively soft, which cannot meet the requirement of bearing a certain pressure when used as a filter material, and because the pre-foamed particles are easily compacted during the compression molding process, the resulting micropores are easy to form Closed micropores are also difficult to meet the requirements for pore density, pore size and distribution, and gas permeability of polypropylene microporous filters during use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] (1) Add 85 parts of homopolypropylene powder with a particle size of 10 to 150um and a melt flow rate (MFR) of 1.0g / 10min and 7 parts of n-octane into a high-speed mixer, at 1400 rpm Stir and mix at a rotating speed until the temperature rises to 80°C, stop stirring, and cool to obtain polypropylene powder containing a low-boiling liquid foaming agent;

[0038] (2) Add 2.5 parts of azodicarbonamide, 2.0 parts of polyoxypropylene stearate, 1.5 parts of calcium stearate, 0.5 parts of stearic acid, 0.48 parts of sodium benzoate, and 1.0 parts of liquid paraffin into a three-roll mill (or ball mill) for 5 minutes to form a uniform and fine paste;

[0039] (3) Add the obtained paste to a high-speed mixer equipped with polypropylene powder containing a low-boiling liquid foaming agent, and continue to stir and mix for 5 minutes at a speed of 1400 rpm to make the paste Evenly adhere to the surface of polypropylene powder containing low boiling point liquid foaming agent;

[00...

Embodiment 2

[0043] (1) 45 parts of homopolypropylene powder with particle size of 10-150um and MFR of 1.0g / 10min, 41 parts of homopolypropylene powder with particle size of 10-150um and MFR of 6.5g / 10min, Add 5.0 parts of n-pentane and 3.0 parts of Vaseline into a high-speed mixer, stir and mix at a speed of 1800 rpm until the temperature rises to 70°C, stop stirring, and cool to obtain polypropylene powder containing a low-boiling point liquid foaming agent material;

[0044] (2) 2.0 parts of potassium azocarboxamide formate, 0.5 parts of fatty alcohol polyoxyethylene ether, 1.5 parts of urea, 1.0 parts of stearic acid, 0.02 parts of dicumyl peroxide, 1.0 parts of maleic anhydride, 0.5 parts of liquid paraffin Add the three-roller mill (or ball mill) and grind for 10 minutes to form a uniform and fine paste;

[0045] (3) Add the obtained paste to a high-speed mixer equipped with polypropylene powder containing a low-boiling liquid foaming agent, and continue to stir and mix for 5 minute...

Embodiment 3

[0049] (1) Add 80 parts of homopolypropylene powder with a particle size of 100-200um and an MFR of 2.5g / 10min and 10 parts of n-decane into a high-speed mixer, and stir at a speed of 1800-2000 rpm Mix until the temperature rises to 75-90°C, stop stirring, and cool down to obtain polypropylene powder containing low-boiling liquid foaming agent;

[0050] (2) 2.0 parts of N, N'-dinitropentamethylenetetramine, 2.0 parts of fatty alcohol polyoxyethylene ether, 1.5 parts of zinc stearate, and 2.0 parts of superfine calcium carbonate with a particle size of 1 to 100um, 0.48 parts of potassium hydrogen terephthalate, 0.02 parts of 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane, 1.0 parts of maleimide, 2.5 parts of methylphenyl silicone oil Together, add it to a three-roller mill (or ball mill) and grind for 15 minutes to form a uniform and fine paste;

[0051] (3) Add the obtained paste to a high-speed mixer equipped with polypropylene powder containing a low-boiling liquid foaming ag...

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PUM

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Abstract

The invention makes pubic a method to make polypropylene tiny hole filtering board. First, mix and churn up polypropylene powder and frothing agent for low boiling point liquid at a high speed so that the mixture temperature will goes up to 70~115 DEG C. Stop churning and cool the mixture. Pour chemical frothing agent, surface active agent, froth activator, and removing model agent, which all are milled and in paste state, into the mixture and then churn the mixture at a higher speed again. Put the mixture in the heated model cavity. Close the model and hot press it between the fixed model board and the movable model board of the pressing machine with force 0.5~10 MPa for 5~15 min. cool it until the temperature is same as room temperature. Remove the model and trim the edge, get the polypropylene tiny hole filtering board finally. Because the invention uses both chemical frothing agent and physic frothing agent and other assistant agent, it reduces working procedure, saves production period, cuts down the device investment and the cost. It can be used to make filtering unit for chemical purification, water purifying, air filter, exhausting auto wasted gas, mechanic appliance and battery.

Description

1. Technical field [0001] The invention belongs to the technical field of preparation of plastic microporous filter sheets, in particular to a method for pressing and preparing polypropylene microporous filter sheets. The microporous filter sheet produced by this preparation method can be used as filter sheet products in the fields of chemical purification, water purification treatment, air filtration, automobile exhaust emission, medical equipment and batteries. 2. Background technology [0002] Polypropylene (PP) is a general-purpose engineering plastic widely used. It has the characteristics of chemical corrosion resistance, non-toxic, odorless, good heat resistance (long-term use temperature of 120°C), excellent comprehensive mechanical properties and processability, and low cost. . In recent years, microporous filter sheets based on polypropylene have a tendency to replace polytetrafluoroethylene, ultra-high molecular weight polyethylene, polyvinyl chloride, and polyet...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C69/00B29C44/02B29C43/02B29K23/00B29L7/00
Inventor 吴智华姜向新孟兵陈涛陈虹
Owner SICHUAN UNIV