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Ferric titanium dull kiln star spot variable composite color material and star spot glaze

A composite color and kiln change technology, applied in the field of ceramics, can solve the problems of difficult to meet the large-scale production of daily ceramic products, the density of star points is uncertain, the appearance effect is difficult to be consistent, etc., to achieve good decorative effect, stable product quality, Color stable effect

Inactive Publication Date: 2007-09-19
SHANDONG ZIBO XINHANG IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The star point glaze products on the market are all glazed by spraying or granule method. The process is cumbersome, the production efficiency is low, and the density of star points is not fixed, so the appearance effect is difficult to be consistent.
[0004] Most of the kiln-changing glaze products of Jun Kiln and Ru Kiln are fired in a reducing atmosphere, which requires high firing and difficult control, and it is difficult to meet the requirements of mass production of daily-use ceramic products.

Method used

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  • Ferric titanium dull kiln star spot variable composite color material and star spot glaze
  • Ferric titanium dull kiln star spot variable composite color material and star spot glaze
  • Ferric titanium dull kiln star spot variable composite color material and star spot glaze

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] See Table 2 for the weight percentage composition and firing conditions of the iron-titanium matte kiln variable star point composite colorant of the present invention.

[0023] sample

Numbering

Raw material ratio (weight percent)

Calcination temperature

Firing atmosphere

Fe 2 o 3

TiO 2

al 2 o 3

ZnO

A1

55%

25%

8%

12%

1260℃

oxidation

[0024] Like the usual pigment preparation, it is obtained after high-temperature calcination. The preparation process is as follows:

[0025] (1) Clinker preparation:

[0026] Ball mill: material: ball stone: water = 1:2:1.5;

[0027] Fineness: 250 mesh sieve residue is less than 0.08%;

[0028] Drying: Use an iron drying box, turn it frequently to avoid sintering;

[0029] Firing: Oxidizing atmosphere, shuttle kiln, maximum temperature 1260°C.

[0030] (2) Fine grinding of clinker:

[0031] ...

Embodiment 2

[0044] Table 4 shows the weight percent composition and firing conditions of the composite color material batching of the present invention.

[0045] sample

Numbering

Raw material ratio (weight percent)

Calcination temperature

Firing atmosphere

Fe 2 o 3

TiO 2

al 2 o 3

ZnO

B3

50%

30%

10%

10%

1280℃

oxidation

[0046] The iron-titanium matt kiln variable star point glaze of the present invention is made of 8% by weight of composite pigment and the rest of the base glaze, wherein the glaze formula of the base glaze is:

[0047]

[0048] Table 5 shows the weight percentage composition of the iron-titanium matte kiln variable star point glaze of the present invention.

[0049] raw material

Albite

quartz

stalactites

Aluminum oxide

barium carbonate

Zinc oxide

Suzhou soil

Talc

Composite colorant...

Embodiment 3

[0053] See Table 6 for the weight percent composition and firing conditions of the composite pigment ingredients of the present invention.

[0054] sample

Numbering

Raw material ratio (weight percent)

Calcination temperature

Firing atmosphere

Fe 2 o 3

TiO 2

Al 2 o 3

ZnO

D5

40%

40%

12%

8%

1300℃

oxidation

[0055] The iron-titanium matte kiln variable star point glaze of the present invention is made of 12% by weight of composite pigment and the rest of the base glaze, wherein the glaze formula of the base glaze is:

[0056]

[0057] Table 7 shows the weight percentage composition of the iron-titanium matte kiln variable star point glaze of the present invention.

[0058] raw material

Albite

quartz

stalactites

Aluminum oxide

barium carbonate

Zinc oxide

Suzhou soil

Talc

Composite colorant ...

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PUM

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Abstract

The invention relates to starred composite pigment material and a starred glaze in a ferrotitanium dark kiln with a composition of composite pigment material by wt.% is: Fe2O3 30-60%, Al2O3 5-20%, TiO2 10-30% and ZnO 5-20%; a composition of material of the starred glaze by wt.% is: albite 30-60%, quartz 5-15%, stalactite 5-15%, alumina 5-15%, barium carbonate 5-20%, zinc oxide 5-15%, SuZhou soil 1-5%, talcum 3-8%, and composite pigment 5-20%. The invention produces the pigment by co-reacting the ferric oxidepigment and titanium oxide and other materials with a low cost. The advantages of pigment are that chemical activity is great and the colour generation is stable. The starred glaze product is made by conventional ceramic glazing system with a good quality and a nice decoration effect. The starred is naturally formed by co-reacting of a seeding agent and other flux material in a high temperature and is baked under the oxidation atmosphere by tunnel kiln so it is simple-produced and simple-controlled.

Description

technical field [0001] The invention relates to an iron-titanium matte kiln variable star-point composite color material and a star-point glaze, belonging to the technical field of ceramics. Background technique [0002] The art of ceramic decoration has a long history like ceramic production, and is an important part of beautifying ceramic products. With the improvement of people's living standards, the decorative requirements for ceramic products are also getting higher and higher. [0003] The star point glaze products on the market are all glazed by spraying or particle method, which is cumbersome, low production efficiency, and the density of star points is variable, so the appearance effect is difficult to be consistent. [0004] The kiln-changing glaze products of Jun kiln and Ru kiln are mostly fired in a reducing atmosphere, which requires high firing and difficult control, and it is difficult to meet the requirements of large-scale production of daily-use ceramic p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C8/22C03C8/04C03C8/20C03C1/00
Inventor 张涛王成刚孙向华贾希文门庆才张汝山张铎
Owner SHANDONG ZIBO XINHANG IND CO LTD