Electrically conductive polymer resin and method for making same
A technology of polymer and polymer sheet, applied in the fields of electromagnetic wave shielding sheet, manufacturing the above-mentioned adhesive polymer sheet, and adhesive polymer sheet
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[0073] Reference will now be made in detail to the following Examples, Comparative Examples and Experimental Examples of the present invention. It should be understood that the present invention is not limited to the following examples.
[0074] The term "part" described below means parts by weight based on 100 parts by weight of a polymer component formed by polymerization of monomers.
Embodiment 1
[0076] 95 parts of 2-ethylhexyl acrylate as acrylic acid monomer, 5 parts of acrylic acid and 0.04 parts of Irgacure-651 (α,α-methoxy-α-hydroxyacetophenone, obtained from Ciba Specialty Chemical, Tarrytown, NY) was introduced into a 1 L glass reactor. Then, the mixture was partially polymerized by light irradiation to obtain a slurry having a viscosity of 300 cps. To 100 parts of the resulting slurry was added as a photoinitiator 0.1 part of Irgacure-819 [(bis(2,4,6-trimethylbenzoyl)phenyl-phosphine oxide obtained from Ciba Specialty Chemical, Tarrytown, NY) and 0.65 parts of 1,6-hexanediol diacrylate (HDDA) as a crosslinking agent, and stir the mixture well. Then, 30 parts of silver-coated hollow glass spheres (SH230S33, Potters Industries Inc., Valley Forger, PA) with a particle size of about 44 μm were mixed with the mixture, and then stirred well to obtain a homogeneous mixture.
[0077] At the same time, if image 3 As shown, a transparent polypropylene film with a thi...
Embodiment 2
[0083] Example 1 was repeated to provide a polymer sheet except that 60 parts by weight nickel-coated graphite fibers from Sulzer Metco Inc., Winterthur, Switzerland were used as the conductive filler.
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