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Bipolar anti-corrosive coating and preparation thereof

An anti-corrosion coating and bipolar technology, applied in the field of bi-polar anti-corrosion coating and its preparation, can solve the problems of large volume and easy occurrence of defects, and achieve the effects of good application performance, prevention of infiltration, and simple coating process

Inactive Publication Date: 2011-03-23
CHINA UNIV OF PETROLEUM (BEIJING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the charged particles in the coating are ion-exchange resins, which are relatively large in micron size, which makes the interface between them and the substrate prone to defects and form "pinholes". At the same time, the ion-exchange resin has a strong water absorption, which is a fatal flaw for coatings

Method used

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  • Bipolar anti-corrosive coating and preparation thereof
  • Bipolar anti-corrosive coating and preparation thereof
  • Bipolar anti-corrosive coating and preparation thereof

Examples

Experimental program
Comparison scheme
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Embodiment 1

[0050] In the present embodiment, the bipolar anti-corrosion coating of the present invention is coated on the outside of the steel pipeline, and the specific process includes:

[0051] Take 60mL of ethanol in a beaker and place it in a constant temperature water bath at 40°C; take 3g of the cationic surfactant hexadecyltrimethylammonium bromide, add it to the beaker, and keep stirring until it dissolves; take nanoparticles (such as titanium dioxide ) 3g was put into a beaker and stirred continuously, stirred at constant temperature for 2 hours, then put into a drying oven at 90°C and dried to constant weight, then ball milled for 24 hours, and passed through a 350 mesh sieve to obtain powdery positively charged nanoparticles. , the Zeta potential of the obtained powder is: 24mV;

[0052] Get 20g of S850 bisphenol A type epoxy resin (purchased from Wuxi Edison Epoxy Resin Co., Ltd.), after heating in a drying oven until it has good fluidity, take 1g of the above-mentioned posi...

Embodiment 2

[0059] In this embodiment, the bipolar anti-corrosion coating of the present invention is coated on the outside of the steel pipeline, wherein the mechanical spraying method is used to coat the cationic selective layer on the outside of the steel pipeline, and then coat it after it is fully cured. The anion-selective layer is clothed, and the thickness of the coated anion-type bipolar coating (that is, the inner layer is a cation-selective layer, and the outer layer is an anion-selective layer) is 237 μm (the thickness of the anion-selective layer is about 124 μm) , other preparation methods are basically the same as in Example 1.

[0060] The anti-corrosion performance of the coating was tested by electrochemical impedance spectroscopy (EIS). The electrochemical impedance spectroscopy was measured at the open circuit potential with CHI660C electrochemical workstation. The test frequency was 100kHz-0.01Hz and the amplitude was 20mV. The test system is a three-electrode system,...

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Abstract

The invention relates to a composition used for forming a bipolar anti-corrosion coating, the bipolar anti-corrosion coating and the preparation method of the composition. The bipolar anti-corrosion coating is used for metallic material, especially in the corrosion prevention of steely material and a corrosion prevention processing method of the corresponding metallic material. The bipolar anti-corrosion coating comprises an anion selecting layer and a cation selecting layer which can be membranous layers containing charged particles and base material, or charged membranes; wherein, the charged particles are nano-particles at the Zeta electric potential and -50mV-50mV, and the base material is the polymer which has anti-corrosion function and comprises epoxide resin, phenolic resin, daiamids and the like. The anti-corrosion coating can be used as an external anti-corrosion coating of steely material in the corrosion environments which have higher chloride ion content and comprise buried pipelines, ocean platforms, submarine pipelines, steamships, etc.

Description

technical field [0001] The present invention relates to a composition for forming a bipolar anticorrosion coating, a bipolar anticorrosion coating and a preparation method thereof. The bipolar anticorrosion coating is used for anticorrosion of metal materials, especially steel materials. The use in the industry, and the corresponding anti-corrosion treatment method of metal materials. Background technique [0002] One of the most commonly used methods for metal corrosion protection is to apply an anti-corrosion coating on the metal surface. The anti-corrosion performance of the coating is mainly realized by shielding the corrosive medium and preventing its contact with the metal surface (shielding mechanism). However, structural defects such as pores and microcracks in organic coatings make it easy for corrosive media to penetrate the coating to reach the metal surface, causing corrosion. Although macroscopic defects of the coating can be avoided through strict control of ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D5/08C09D163/00C09D161/06C09D179/02C23F15/00
Inventor 周琼苏晓妹董玉华
Owner CHINA UNIV OF PETROLEUM (BEIJING)