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Method for producing artemisinin by plant cell

A plant cell, artemisinin technology, applied in the production and fermentation of bulk chemicals, can solve the problems of wasting resources, laborious, and difficult to guarantee yield

Inactive Publication Date: 2009-08-12
于荣敏
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, field cultivation techniques are easily affected by seasonal changes, pests, fungi, bacteria and other infections; at the same time, there are also problems such as high cost, long cycle, and difficult to guarantee yield.
In addition, relying solely on natural resources also has many problems such as time-consuming extraction and separation, laborious work, waste of resources, etc.
[0004] In addition, although the chemical total synthesis of artemisinin has been successful in the laboratory, the process is very complicated, and there are many by-products and low yields, so the industrial application value is not great

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Example 1 Take dihydroartemisinic acid, dissolve it with absolute ethanol, add it to the cell suspension of Artemisia annua cultured for 14 days in a sterile ultra-clean workbench, co-cultivate for two days, terminate the reaction, filter with suction, and separate Cultures and media were obtained. The culture was rinsed with distilled water, dried at 55°C to constant weight, pulverized, ultrasonically extracted three times with eight times acetone, half an hour each time, and the extract was evaporated to dryness under reduced pressure to obtain extract I. The culture medium was concentrated to an appropriate amount, extracted with an equal amount of ethyl acetate, and the extract was evaporated to dryness under reduced pressure to obtain extract II. The two extracts were combined, separated by silica gel column chromatography, compared with TLC thin layer, combined with components containing artemisinin, and crystallized with petroleum ether to obtain pure artemisinin...

Embodiment 2

[0014] Example 2 Take artemisinic acid, dissolve it in methanol, and add it to the suspension culture medium of periwinkle cells in the logarithmic growth phase in a sterile ultra-clean bench, co-cultivate for two days, stop the reaction, filter with suction, and obtain culture and culture respectively. base. The culture was rinsed with distilled water, dried at 55°C to constant weight, pulverized, placed in a Soxhlet extractor, extracted three times with ten times ethyl acetate, half an hour each time, and the extract was evaporated to dryness under reduced pressure to obtain the extract I . The culture medium was concentrated to an appropriate amount, extracted with an equal amount of ethyl acetate, and the extract was evaporated to dryness under reduced pressure to obtain extract II. The two extracts were combined, separated by silica gel column chromatography, and compared with TLC thin layer, and the components containing artemisinin were combined and crystallized with e...

Embodiment 3

[0015] Example 3 Take 4,11-amorphadiene, dissolve it with absolute ethanol, add it to the tobacco suspension cell culture medium in the logarithmic growth phase in a sterile ultra-clean bench, co-cultivate for two days, terminate the reaction, and filter with suction , to obtain culture and medium, respectively. The culture was rinsed with distilled water, dried at 55°C to constant weight, pulverized, extracted three times with ethanol under reflux for half an hour each time, and the extract was evaporated to dryness under reduced pressure to obtain extract I. The culture medium was concentrated to an appropriate amount, extracted with an equal amount of ethyl acetate, and the extract was evaporated to dryness under reduced pressure to obtain extract II. The two extracts were combined, separated by silica gel column chromatography, and compared with TLC thin layer, and the components containing artemisinin were combined and crystallized with methanol to obtain pure artemisinin...

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PUM

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Abstract

The invention discloses a method for preparing arteannuin from a vegetable cell. The method comprises the following steps that: an intermediate compound in the process of biologically synthesizing the arteannuin is dissolved, added in the vegetable cell, co-cultured and subjected to suction-filtration to obtain a culture and a culture medium; the culture is subjected to ultrasonic extraction by organic solvent, and the extract is evaporated to dryness to obtain an extractum I; the culture medium is extracted by organic solvent, and the extraction liquid is evaporated to dryness to obtain an extractum II; and the extractum I and the extractum II are mixed and separated to obtain the arteannuin component. The method has the characteristics of quickness, high efficiency, and great industrial application prospect.

Description

technical field [0001] The present invention relates to a method for producing artemisinin by using plant cells, in particular to using Artemisia annua, periwinkle, tobacco, Polygonum multiflorum hairy root as a culture system to biosynthesize artemisinin with artemisinic acid, dihydroartemisinic acid, etc. Pathway intermediate biomanufacture of artemisinin-like compounds. Background technique [0002] Artemisinin (Artemisinin, Arteannuin, Qinghaosu) is derived from the Compositae plant Artemisia annua L., which is a sesquiterpene lactone compound containing a peroxide bridge. It was first isolated from the traditional Chinese medicine Artemisia annua by Chinese scientists in 1972. The obtained effective monomer not only has a significant therapeutic effect on a variety of malaria parasites that are resistant to antimalarial drugs such as chloroquine, mefloquine, and antipyrimethamine, but also has a good therapeutic effect on hepatitis, and inhibits tumor cells. Growth, ki...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P17/18
CPCY02P20/54
Inventor 于荣敏朱建华
Owner 于荣敏