Colored curable resin composition, color filter, liquid crystal display device, and organic el display
A technology of curable resin and composition, applied in optical filters, electro-solid devices, nonlinear optics, etc., can solve the problems of impairing the stability of inkjet ejection, reducing the surface tension of the ink, and reducing the swelling property, etc. The effect of good pixel flatness and low cost
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[0527] [2] Preparation method of colored curable resin composition
[0528] Next, a method for preparing the colored curable resin composition of the present invention will be described.
[0529] In addition, the colored curable resin composition of this invention can be prepared by previously preparing a pigment dispersion liquid, and mixing other components in it, and can also prepare it by mixing all components together. Hereinafter, the case of preparing according to the former method is taken as an example for illustration, but it is not limited thereto.
[0530] First, weigh predetermined amounts of (a) colorant, (c) organic solvent, and (e) dispersant as an optional component when (a) colorant contains pigment, and in the dispersion treatment process, use (a) The pigment in the color material is dispersed to prepare a pigment dispersion liquid. In this dispersing treatment process, the pigment can be micronized by using a Paint Conditioner, a sand mill, a ball mill, a...
Embodiment
[0560] The present invention will be described more specifically with reference to Examples and Comparative Examples below, but the present invention should not be construed as being limited to the following Examples unless the gist is exceeded.
Synthetic example 1
[0561] (Synthesis example 1: corresponding to (e-2) acrylic block copolymer containing nitrogen atoms)
[0562] An acrylic A-B block copolymer having a tertiary amino group was synthesized according to Example 1 of JP-A-1-229014 except that the amino group (dimethylamino group) in the copolymer was not quaternized. The weight average molecular weight Mw of the obtained copolymer was 9000, the amine value was 121 mgKOH / g, and the acid value was 0 mgKOH / g.
[0563] In addition, the amine value is represented by the weight of the KOH equivalent amount per 1 g of solid content after removing a solvent, and it measures it by the following method.
[0564] 0.5 to 1.5 g of the dispersant synthesized above was accurately weighed in a 100 mL beaker, and dissolved in 50 mL of acetic acid. Using an automatic titration device with a pH electrode, using 0.1mol / L HClO 4 The acetic acid solution was used for neutralization titration of the dissolved solution. Using the inflection point of...
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Abstract
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