Additive for preparing polysilicon etching chemical suede

An additive and silicic acid technology, which is applied in the field of additives for the preparation of chemical suede by polysilicon acid etching, can solve problems such as inconvenience of control, and achieve the effects of reducing energy consumption, moderating corrosion rate and improving suede quality.

Inactive Publication Date: 2009-11-25
HANWHA SOLARONE QIDONG +1
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  • Abstract
  • Description
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Problems solved by technology

[0014] The reaction rate is to

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  • Additive for preparing polysilicon etching chemical suede

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Embodiment Construction

[0028] An additive for preparing polysilicon acid etching chemical suede, comprising an acid etching solution, in which the following components by volume percentage are added:

[0029] (1) Nitrogen-containing inorganic salts: 0.1-2%

[0030] (2) Silicon-based surfactant: 0.1-0.5%

[0031] The volume percentage is relative to the volume of the acidic corrosion solution.

[0032] The acidic etching solution is an etching solution composed of hydrofluoric acid, nitric acid and water.

[0033] The volume ratio of hydrofluoric acid, nitric acid and water in the acidic corrosion solution is 3:6:4.

[0034] The solution temperature of the additive is 8-20°C.

[0035] Nitrogen-containing inorganic salts are nitrates, nitrites or ammonium salts (such as sodium nitrate, sodium nitrite, potassium nitrate, potassium nitrite, ammonium sulfate, ammonium nitrate, ammonium nitrite, etc.); One or more of base siloxane and its derivatives.

[0036] When in use, the temperature of the addi...

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Abstract

The invention discloses an additive for preparing polysilicon chemical etching suede, including acid etching solution added with inorganic salt containing nitrogen, silica-based surfactant. The invention make etched color of polysilicon uniformly, the reducing thickness meets to the requirments, no-pinhole, no-reticulated mottles, and polysilicon suede without obvious color aberration. Preparing silicon nitride film on back surface of the polysilicon suede without obvious crystal boundary when observed with naked eyes.

Description

Technical field: [0001] The invention relates to an additive for preparing polysilicon acid-etching chemical suede. Background technique: [0002] In polysilicon acidic texturing, the main components of the acidic solution are hydrofluoric acid, nitric acid and water. In large-scale production, pitting, pinholes, and chromatic aberrations are prone to occur in the same proportion of acidic etching solution and suede preparation. In the initial solution, sometimes the amount of corrosion is not enough. These series of problems have seriously affected the conversion efficiency and yield of polycrystalline silicon cells. The problem now is that for the acidic solution with the same ratio, within the service life, the suede surface of polysilicon is continuous, uniform, dense, free of pinholes, and pitting corrosion. The color of the surface of the silicon wafer is uniform, without obvious color difference. [0003] Contents: When the acidic etching solution is initially pre...

Claims

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Application Information

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IPC IPC(8): C23F1/24
Inventor 马跃杨雷王玉亭戴燕华张薛丹
Owner HANWHA SOLARONE QIDONG
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