Unlock instant, AI-driven research and patent intelligence for your innovation.

Ca-Zn liquid composite stabilizing agent and application thereof

A composite stabilizer, liquid technology, applied in rigid pipes, mechanical equipment, pipes/pipe joints/fittings, etc., can solve the problems of narrow processing range, poor thermal stability, application limitations of zinc soap and zinc-based composite products, etc. To achieve the effect of simple method, excellent performance and effective thermal stability

Inactive Publication Date: 2010-06-23
杭州三叶新材料股份有限公司
View PDF1 Cites 8 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, zinc soap often causes "zinc burning" of products, so the thermal stability is poor and the processing range is narrow
The application of zinc soap and zinc-based composite products is limited to some extent in the occasions where the performance of the product is required to be high.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Ca-Zn liquid composite stabilizing agent and application thereof
  • Ca-Zn liquid composite stabilizing agent and application thereof
  • Ca-Zn liquid composite stabilizing agent and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] Calcium-zinc liquid composite stabilizer, the liquid composite stabilizer consists of the following components by weight percentage:

[0059] 35% overbased liquid calcium carboxylate with a calcium metal content of 10% by weight

[0060] Zinc carboxylate 10% with a zinc metal content of 15% by weight

[0061] Phosphite-Phenyl Diisooctyl 20%

[0062] Epoxidized soybean oil 7.5%

[0063] Dibenzoylmethane 4.0%

[0064] Antioxidant 1076 2.5%

[0065] Pentaerythritol esters 6.0%

[0066] Diethylene glycol methyl ether 15%.

[0067] The above-mentioned components are mixed and stirred uniformly to prepare the calcium-zinc liquid composite stabilizer.

Embodiment 2

[0069] Calcium-zinc liquid composite stabilizer, the liquid composite stabilizer consists of the following components by weight percentage:

[0070] 30% overbased liquid calcium carboxylate with a calcium metal content of 10% by weight

[0071] Zinc carboxylate 15% with a zinc metal content of 15% by weight

[0072] Bisphosphite 15%

[0073] Epoxidized soybean oil 16%

[0074] Stearoylformylmethane 5.5%

[0075] Antioxidant 1076 1.5%

[0076] Pentaerythritol Ester 8.0%

[0077] Diethylene glycol methyl ether 10%.

[0078] The above-mentioned components are mixed and stirred uniformly to prepare the calcium-zinc liquid composite stabilizer.

Embodiment 3

[0080] Calcium-zinc liquid composite stabilizer, the liquid composite stabilizer consists of the following components by weight percentage:

[0081] 20% overbased liquid calcium carboxylate with a calcium metal content of 10% by weight

[0082] Zinc carboxylate 12% with a zinc metal content of 15% by weight

[0083] Bisphosphite 8.0%

[0084] Diphenylisodecyl phosphite 10.0%

[0085] Epoxidized soybean oil 15%

[0086] Stearoylformylmethane 3.5%

[0087] Dibenzoylmethane 3.5%

[0088] Bisphenol A 4.5%

[0089] Dipentaerythritol Ester 8.5%

[0090] Diethylene glycol methyl ether 15%.

[0091]The above-mentioned components are mixed and stirred uniformly to prepare the calcium-zinc liquid composite stabilizer.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a PVC heat stabilizing agent, in particular to a liquid composite stabilizing agent used by PVC tubing and pipe fitting and application thereof. Ca-Zn liquid composite stabilizing agent is composed of the following components in percentage by weight: 25-40% of calcium carboxylate containing 8-12 wt% of excess alkali, 5-20% of zinc carboxylate containing 10-20 wt% of zinc, 10-30% of phosphite ester, 5-30% of epoxidized soybean oil, 2-8% of beta-diketone, 1-8% of antioxygen, 5-10% of polyol ester and 10-20% of solvent. The invention adopts a proper quantity of metal stabilizer and synergetic stabilizing agent to cooperate, has reasonable prescription and simple method, keeps favourable heat stability and transparency to PVC products, conforms to environmental protection requirements, has the characteristics of favourable performance, low production cost and the like and is suitable for popularizing and applying.

Description

technical field [0001] The invention relates to a PVC heat stabilizer, in particular to a liquid composite stabilizer for PVC pipes and pipe fittings and its application. Background technique [0002] At present, lead salt heat stabilizers have been banned in the United States and the European Union. In the United States, organotin heat stabilizers have completely replaced lead salt heat stabilizers, while calcium / zinc heat stabilizers are mainly used in Europe. In Asia, due to production cost and technical reasons, China and India are still the largest users of lead salt composite stabilizers. In China, with the improvement of people's living standards, people's increasing attention to health issues and the gradual improvement of corresponding environmental protection laws and regulations, lead salt composite stabilizers will be replaced by varieties with higher safety and reasonable cost that meet environmental protection requirements. . The increasingly stringent, espec...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08K5/00C08K5/098C08K5/524C08K5/1515C08K5/07C08K5/103C08L27/06F16L9/12
Inventor 施珣若
Owner 杭州三叶新材料股份有限公司