Adhesive for yacht and preparation method thereof
A technology for adhesives and yachts, applied in the direction of adhesive types, polyurea/polyurethane adhesives, adhesives, etc., can solve problems such as poor weather resistance, and achieve the effect of good initial adhesion and excellent weather resistance.
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Embodiment 1
[0017] This embodiment provides an adhesive for yachts, which is used in the adhesion of yachts made of PVC. It has the characteristics of strong initial adhesion and excellent weather resistance. The adhesive is 70-85% by weight Organic solvent and 15-30% main agent are raw materials, the two raw materials are mixed and stirred at 30-40°C for 1-2 hours to obtain a solid content of 15-30% and a rotational viscosity of 300 at 25°C ~600mPa·s adhesive; wherein, the main agent is 92~93% polyester polyol and 7~8% toluene diisocyanate by weight percentage as raw materials, each raw material is heated at 75~95 ℃ After mixing and reacting at high temperature for 1-2 hours, the resin obtained is extruded and granulated by twin-screw. Organic solvent can adopt any one in toluene, ethyl acetate, methyl acetate, butanone or acetone.
[0018] The polyester polyol in the above-mentioned main ingredient is a polyester with a hydroxyl value of 45-55 mgKOH / g, an acid ester of 0.1-2 mgKOH / g, a...
Embodiment 2
[0042] This embodiment provides an adhesive for yachts, which is used for bonding yachts made of PVC, and has the characteristics of strong initial adhesion and excellent weather resistance. The preparation method of the adhesive is as follows:
[0043] Prepare the main ingredient:
[0044] (a) prepare main ingredient polyester polyol, get each raw material according to following formula:
[0045]
[0046] Steps:
[0047] (1) primary esterification:
[0048]Add 27 parts by mass of 1,4 succinic acid and 35 parts by mass of hexanediol into the polyester synthesis kettle, raise the temperature of the polyester synthesis kettle to 210-230°C, and react for 2-3 hours; during the reaction, keep The water output of the polyester synthesis kettle is stable (the water output is 0.5-1.0% / hour of the total weight of raw materials input into the primary esterification), and the distilled water is 8.24%;
[0049] (2) Secondary esterification:
[0050] Add 20 parts by mass of isophtha...
Embodiment 3
[0063] This embodiment provides an adhesive for yachts, which is used for bonding yachts made of PVC, and has the characteristics of strong initial adhesion and excellent weather resistance. The preparation method of the adhesive is as follows:
[0064] (a) the preparation of polyester polyol, get each raw material that prepares polyester polyol by following formula:
[0065]
[0066] Steps:
[0067] (1) primary esterification:
[0068] Add 30 parts by mass of 1,4 succinic acid and 35 parts by mass of hexanediol into the polyester synthesis kettle, heat up to 210-230° C., and react for 3 hours. During the reaction, keep the water output stable (the water output is 0.5 to 1.0% of the total weight of the raw material is put into the esterification once per hour), and the distilled water is 9.15%;
[0069] (2) Secondary esterification:
[0070] Add 18 parts by mass of isophthalic acid and 17 parts by mass of ethylene glycol to the polyester synthesis kettle after primary es...
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Abstract
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