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Coloured austenite stainless steel material with high corrosion resistance and high hardness and production method thereof

A kind of technology of austenitic stainless steel and manufacturing method, which is applied in the direction of metal material coating process, coating, solid diffusion coating, etc., can solve the problems of easy wear, low surface hardness, and low adhesion force of base metal, etc., to achieve Reduced manufacturing costs, good corrosion resistance, and good decorative effects

Inactive Publication Date: 2014-12-24
DONG A UNIV RES FOUND FOR IND ACAD COOP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Although the Ti or Zr hard film formed on the surface of stainless steel by CVD or PVD has high hardness, its adhesion to the base material is low, and it is easy to peel off, and it can only present a single golden color.
In addition, it cannot provide corrosion resistance matching that of stainless steel as a base material
[0007] In addition, the Italian INCO method (Ukpat, 275, 781) immerses stainless steel in an acidic Cr solution to form an oxide layer with a thickness of about 1 μm composed of oxides of Fe, Ni, and Cr, and according to the optical properties of the oxide layer, However, the thickness of the oxide layer formed at this time is only hundreds of angstroms, so the thickness of the coating is thin, the surface hardness is low, and it is easy to wear
[0008] Although oxidation treatment of stainless steel in a high-temperature oxidizing atmosphere can impart hues such as gold, brown, and blue, the oxide film formed in this case with a thickness of about angstroms is as prone to wear as the INCO method
[0009] In addition, the above method cannot increase the hardness of the base material, so it is difficult to be used in the application of bearing a large load

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] Use STS304, STS316 and STS310 materials to manufacture tubes with an outer diameter of φ30mm, a thickness of 1mm, and a length of 300mm. The tube was loaded into a pit furnace set at 400 °C and heated with N 2 Replace the air in the furnace, and then inject a fluorine-based gas (8% by volume of NF 3 and 92 volume percent N 2 mixed gas) and maintain this state for 20 minutes. Then, with N 2 Nitriding gas at 400°C (60% by volume NF 3 , 10 vol% CO 2 and 30% by volume of N 2 ) in an atmosphere of nitriding for 15 hours, followed by air cooling.

[0060] When the nitriding treatment is carried out in this way, the thicknesses of the compound layers of the STS304, STS316 and STS310 materials are 15 μm, 18 μm, and 14 μm, respectively, and the hardnesses of the compound layers are 1010Hv, 1070Hv, and 1100Hv, respectively. Furthermore, as a result of evaluating corrosion resistance by a salt spray test (KSD 9502), no rust occurred even after 600 hours.

[0061] Grinding ...

Embodiment 2

[0063] Disc-shaped test pieces with a thickness of 5 mm and a diameter of 20 mm were made from STS304 and STS316 materials and plasma nitriding was performed on them. The condition for plasma nitriding is to introduce 80% by volume of N 2 and 20 vol% H 2 The mixed gas was decompressed to 5 Torr, the test piece was used as the cathode and a voltage of about 500V was applied, and it was carried out in a glow discharge state for 13 hours. At this time, the temperature of the test piece was 390° C., and the furnace was cooled to normal temperature in a high vacuum state after the nitriding treatment.

[0064] When plasma nitriding was performed as described above, the thicknesses of the compound layers were 12 μm and 14 μm for STS304 and STS316, respectively, and the hardnesses of the compound layers were 1020 Hv and 1200 Hv, respectively. Its corrosion resistance was evaluated by the salt spray test (KSD 9502), and the results showed that it did not rust even after 600 hours. ...

Embodiment 3

[0067] Salt bath nitriding was carried out on balls with a diameter of 11 mm made of STS316 and STS310. Salt bath nitriding by 45% by weight of NaCN, 45% by weight of Na 2 CO 3 and 15% by weight of (NaK) 4 Fe(CN) 6 The method of immersing the composition in the mixed molten salt for 8 hours was carried out. When salt bath nitriding was carried out as above, the compound layer thicknesses of STS316 and STS310 were 22 μm and 19 μm, respectively, and the hardness of the compound layer was about 1000 Hv for both materials.

[0068] Thereafter, the salt-bath nitrided balls were barrel-milled. The condition of barrel grinding is to immerse 100 balls in a mixture of 500 cc of water, 800 cc of grinding stones with a diameter of 3 mm and 30 cc of abrasive (compound) and make the rotation speed reach 200 rpm for 20 minutes of barrel centrifugal motion.

[0069] The ground ball was oxidized in a mixed gas atmosphere of 60% by volume of oxygen and 40% by volume of nitrogen at 500°C ...

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Abstract

The present invention relates to a coloured austenite stainless steel base material with high corrosion resistance and high hardness, which processes a base material and a part produced by the austenite stainless steel by malcomising, processing the surface and oxidizing so that the corrosion resistance is good, and the surface hardness is high, no abrasion is produced, and the colours are various, and production of the part. In addition, by the base material and part of the coloured austenite stainless steel base material with high corrosion resistance and high hardness produced by the invention, under the condition that the colour and the lustre of the surface are light during the use process, the surface processing technique and the coloured oxide film covering technique can be constructed again and used again.

Description

technical field [0001] The present invention relates to an austenitic stainless steel material and a manufacturing method thereof, and in more detail relates to carrying out a nitrding heat treatment (nitrding) and a surface processing process on a base material or a component made of austenitic stainless steel, and then performing an oxidation treatment to make it have good properties. High corrosion resistance and high hardness color austenitic stainless steel material with high corrosion resistance, high surface hardness and various colors and its manufacturing method. Background technique [0002] Austenitic stainless steel (austenitic stainless steel) used in fields where corrosion resistance is important is generally called "18-8 stainless steel" as a base material containing iron containing 18% by weight of chromium and 8% by weight of nickel. . In addition, austenitic stainless steel containing 1 to 3% by weight of Mo in the 18-8 stainless steel is also commonly use...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C8/26C23C8/38C23C8/50C23C8/80
CPCC23C8/02C23C8/08C23C8/24C23C8/26C23C8/34C23C26/00
Inventor 金荣熙
Owner DONG A UNIV RES FOUND FOR IND ACAD COOP