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Polyester composite film and its preparation method

A composite film and polyester technology, applied in the field of polyester composite film, can solve the problems of large equipment investment, high energy consumption, environmental pollution, etc., and achieve the effects of low oxygen permeability, increased fracture growth rate, and reduced production costs.

Active Publication Date: 2012-02-01
CHINESE TEXTILE ACAD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, there are disadvantages such as large investment in equipment, high energy consumption, and pollution to the environment.

Method used

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  • Polyester composite film and its preparation method
  • Polyester composite film and its preparation method
  • Polyester composite film and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] 1. Preparation of modified copolyester raw materials

[0045] On a 1 cubic polyester semi-continuous device, according to the method produced by the device, use about 665 kg of large bright chips and 108 kg of ethylene glycol and an appropriate amount of alcoholysis catalyst to carry out alcoholysis at 260 ° C to Prepare mother liquor; add 300 kg of PTA (or equivalent molar amount of dibasic acid), 150 kg of EG and a certain molar amount of modified monomer CHDM in each batch in the beating kettle, and an appropriate amount of catalyst and melt strength strengthening agent, the catalyst ethylene glycol antimony is added in a weight ratio of 0.35‰ of the copolyester, and the melt strength enhancer is 1,2,4-trimellitic anhydride, and the weight ratio added is 0.125‰ of the copolyester; each batch The slurry is fed into the esterification tank at a certain speed, so that the reaction temperature in the esterification tank is controlled at 250°C; the materials in each batch...

Embodiment 2

[0058] 1. Preparation of modified copolyester raw materials

[0059] On a 1 cubic polyester semi-continuous device, according to the method produced by the device, use about 665 kg of large bright chips and 108 kg of ethylene glycol and an appropriate amount of alcoholysis catalyst to carry out alcoholysis at 260 ° C to Prepare mother liquor; In beating kettle, add 300 kilograms of PTA (or the dibasic acid of considerable molar quantity), 150 kilograms of EG and the modified monomer CHDM of certain molar quantity in every batch, and an appropriate amount of catalyzer, catalyzer antimony acetate The weight ratio added is 0.45‰ of the copolyester; each batch of slurry is added to the esterification kettle at a certain speed, so that the reaction temperature in the esterification kettle is controlled at 250°C; the materials in each batch of beating kettle are completely added to the esterification kettle And after the reaction is complete, the part of the esterified lactone in th...

Embodiment 3

[0072] 1. Preparation of modified copolyester raw materials

[0073] On a 1 cubic polyester semi-continuous device, according to the method produced by the device, use about 665 kg of large bright chips and 108 kg of ethylene glycol and an appropriate amount of alcoholysis catalyst to carry out alcoholysis at 260 ° C to Prepare mother liquor; add 300 kg of PTA (or equivalent molar amount of dibasic acid), 150 kg of EG and a certain molar amount of CHDM in each batch in the beating kettle, and an appropriate amount of catalyst and melt strength enhancer, catalyst antimony The weight ratio added is 0.2‰ of the copolyester, and the weight ratio of the melt strength enhancer glycerin added is 0.05‰ of the copolyester; each batch of slurry is added to the esterification kettle at a certain speed, so that the esterification kettle The reaction temperature is controlled at 250°C; the material in each batch of beating kettle is completely added to the esterification kettle and after t...

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Abstract

The invention relates to a polyester composite film, concretely relates to a composite film composited by a modified copolyester film and a polyolefin film through an adhesive layer, and a preparation method. The composite film comprises a modified copolyester film layer, a polyolefin film layer positioned on one surface or upper and lower surfaces of the modified copolyester film, and an adhesive layer positioned between the polyester layer and the polyolefin layer. According to the invention, the modified copolyester is used in the composite film, wherein a melt-strength reinforcer is introduced in the modified copolyester, so that the melt strength is enhanced, the composite film can be prepared by the modified copolyester through a double-bubble blown film moulding method, thereby the secondary composite processing procedure is reduced. The polyester composite film is used for packaging food, medicines and biological products, and overcomes the disadvantage that the copolyester is unsuitable for preparing the membrane.

Description

technical field [0001] The invention relates to a polyester composite film, in particular to a composite film formed by compounding a modified copolyester film and a polyolefin film through an adhesive layer, and a preparation method thereof. Background technique [0002] Due to its low melt strength and high crystallinity, conventional polyester raw materials are currently limited to the processing method of extrusion casting biaxial stretching. The polyester composite film used in the field of food packaging is also limited to the use of dry composite processing methods. Therefore, there are disadvantages such as large investment in equipment, high energy consumption, and pollution to the environment. [0003] Patent ZL200610155089.4 discloses a composite film with ultra-high oxygen resistance and retort resistance packaging. The composite film includes a three-layer structure of base material-high oxygen resistance glue-polyolefin, and the base material can be polyester ...

Claims

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Application Information

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IPC IPC(8): B32B27/08B32B27/32B32B27/36B32B37/15C08L67/00C08L23/06
Inventor 罗欣翟立鹏李乃祥韩朝阳盛平厚迟克栋
Owner CHINESE TEXTILE ACAD