Novel ductile metal foil laminate and method for producing the same
A flexible metal and foil laminate technology, applied in metal layered products, chemical instruments and methods, coatings, etc., can solve the problems of difficult manufacturing methods, long manufacturing processes, cumbersome manufacturing methods, etc., and achieve simple and convenient manufacturing processes. , the effect of improving productivity and economy
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Embodiment 1
[0109] Example 1. Manufacture of polyimide, epoxy resin and flexible copper foil laminate using them
[0110] 1-1. Manufacture of polyimide
[0111] Nitrogen was passed into a 1000mL round-bottomed flask equipped with a thermometer, a stirrer, a nitrogen gas inlet and a powder dispensing funnel, while 9.733g of p-phenylenediamine (p-PDA) (0.09mol ) and 12.014 g of 4,4'-diaminodiphenyl ether (4,4'-ODA) (0.06 mol) were added with 500 mL of N-methylpyrrolidone (NMP), stirred, and completely dissolved. The above solution was maintained at 50°C, and 30.893g of 3,3',4,4'-biphenyltetracarboxylic dianhydride (BPDA) (0.105mol) and 9.815g of pyromellitic dianhydride (PMDA) were slowly added ( 0.045mol), and polymerized while stirring to obtain a polyamic acid varnish with a viscosity of 25,000cps.
[0112] The polyamic acid varnish produced above was coated on an electrolytic copper foil (ILJIN Materials Co., Ltd.) having a thickness of 12 μm with a doctor blade. At this time, the co...
Embodiment 2
[0120] Nitrogen was passed into a 1000mL 4-neck round-bottomed flask equipped with a thermometer, a stirrer, a nitrogen gas inlet and a powder dispensing funnel, while 9.733g of p-phenylenediamine (p-PDA) (0.09 mol) and 12.014 g of 4,4'-diaminodiphenyl ether (4,4'-ODA) (0.06 mol), 500 mL of N-methylpyrrolidone (NMP) was added, stirred, and completely dissolved. 14.7 g of Talc was added there, and it stirred for 30 minutes.
[0121] The above solution was maintained at 50°C, and 30.893g of 3,3',4,4'-biphenyltetracarboxylic dianhydride (BPDA) (0.105mol) and 9.815g of pyromellitic dianhydride (PMDA) were slowly added ( 0.045mol), and polymerized while stirring to obtain a polyamic acid varnish with a viscosity of 23,000cps. The polyamic acid varnish produced above was coated on an electrolytic copper foil (ILJIN Materials Co., Ltd.) having a thickness of 12 μm with a doctor blade. At this time, the coating thickness was adjusted so that the thickness of the final polyimide resi...
Embodiment 3~6
[0124] Except that the relative proportions of p-PDA, ODA, BPDA, PMDA, and Talc were varied according to the following Table 2, the same implementation was carried out as in the above-mentioned Example 1, and finally the flexible copper foil laminates of Examples 3-6 were respectively manufactured. Their properties were measured and listed in Table 3.
[0125] Table 2
[0126] Example N
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