Method for preparing copper nitride powder
A copper nitride and powder technology, applied in nitrogen-metal/silicon/boron binary compounds, bulk chemical production, nanotechnology, etc. The effect of low temperature and strong applicability
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0027] Put 24.0 g of copper oxide in a reactor with a volume of 1 L, add 93 g of methanol, vacuumize the reactor to 0.03 MPa, feed 147.8 g of ammonia gas into the reactor, and the pressure in the reactor is 0.61 MPa At the same time, the reactor was heated to 210 °C, and the pressure inside the reactor was maintained at 16.4 MPa. After 2.5 h of reaction under this condition, the reactor pressure was reduced to 0.3 MPa within 0.5 h, and the reactor was naturally cooled to room temperature. The solid product in the reactor was separated, washed three times with absolute ethanol, and then vacuum-dried at 80 °C for 1.0 h to obtain 19.6 g of dark green copper nitride powder.
Embodiment 2
[0029] Take by weighing 20.0 g of copper nitrate and place it in a reactor with a volume of 1 L. After adding 144.5 g of ethanol, the reactor is airtight and then decompressed to 0.04 MPa. Then 153.8 g of liquid ammonia is put into the reactor, and the reactor is heated to 200 ℃, the pressure is 15.8 MPa, and then reacted under this condition for 2.4 h, after the reaction was completed, the pressure was reduced to 0.5 MPa, after cooling the reactor, the solid product was separated, washed three times with absolute ethanol, and vacuumed at 80 ℃ After drying, 7.1 g of dark green copper nitride powder was obtained.
Embodiment 3
[0031] 10.0 g of copper oxide and 10.0 g of copper sulfate were placed in the reactor, 116.3 g of methanol and 100.8 g of ammonium carbonate were added, the reactor was evacuated to 0.03 MPa, the reactor was heated to 190 ° C, and the pressure in the reactor was maintained at 12.5 MPa, and after reacting under this condition for 1.8 h, the reactor pressure was reduced to 0.3 MPa within 1.0 h, and the reactor was naturally cooled to room temperature. The solid product in the reactor was separated, washed three times with absolute ethanol, and then vacuum-dried at 80 °C for 1.0 h to obtain 12.8 g of dark green copper nitride powder.
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More