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Superhard abrasive particle coated with active metal and silicon and method for producing superhard abrasive particle

A technology of active metals and superhard abrasive grains, applied in metal material coating process, gaseous chemical plating, coating, etc., can solve the problems of unsatisfactory effect and poor bonding ability, and achieve low plating cost, Improvement of anti-oxidation ability and reduction of manufacturing cost

Inactive Publication Date: 2014-09-10
YANSHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the abrasives industry, there is a common problem: there is a high interfacial energy between the covalently bonded superabrasive grains and metal and vitrified bonds, which makes the bonding ability of abrasive grains and general metals comparable. Difference
However, because the titanium layer is very thin and easily oxidized, it is easy to be completely oxidized to expose the surface of superhard abrasive grains during sintering, and the effect is not very ideal.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Mix 100g of 140 / 170 mesh (80~120 micron) diamond and 20g of 30~50 micron titanium powder evenly into a self-made stainless steel container, put the container in the vacuum reaction furnace chamber, turn on the vacuum pump and heating valve, and heat at 5°C / min The rate of heating is heated to 600 ° C, and the vacuum degree is 10 -4 Pa, keep warm for 40 minutes, close the heating valve, cool to 299°C and turn off the vacuum pump; take out the container after cooling to room temperature, use a 100-mesh standard sieve to screen the titanium-coated superabrasive grains, and then polish with 280-mesh sandpaper , to remove excess metal particles adhered to the surface of the abrasive grains.

[0023] Evenly spread the above titanium-coated superabrasive grains in a stainless steel container, put the container into the vacuum reaction furnace chamber of the silicon plating equipment; turn on the vacuum pump and heating valve, heat to 600°C under a vacuum of 99Pa, and keep warm...

Embodiment 2

[0026] Evenly mix 100g W0.1 (0.1 micron) cubic boron nitride with 25g each of 80~500 micron zirconium powder and titanium powder and put them into a self-made stainless steel container, put the container in the vacuum reaction furnace cavity, turn on the vacuum pump and heating valve, Heat up to 620°C at a rate of 30°C / min, keep the vacuum at 100Pa, keep warm for 50 minutes, close the heating valve, cool to 145°C and turn off the vacuum pump; take out the container after cooling to room temperature, and use a 270-mesh standard sieve for plating Titanium-coated superhard abrasive grains are screened, and then polished with 2000-grit sandpaper to remove excess metal particles adhered to the surface of the abrasive grains.

[0027] Evenly spread the above titanium-coated superabrasive grains in a stainless steel container, put the container into the vacuum reaction chamber of the silicon plating equipment; turn on the vacuum pump and heating valve, heat to 950°C under 98Pa vacuum ...

Embodiment 3

[0030] Mix 100g of 50 / 60 mesh (230~250 micron) diamond and 30g of 5~80 micron vanadium powder evenly and put it into a self-made stainless steel container, put the container in the vacuum reaction furnace chamber, turn on the vacuum pump and heating valve, and heat at 10°C / per Minute rate heating up to 660°C with a vacuum of 10 -1 Pa, keep warm for 60 minutes, close the heating valve, cool to 275 ° C and turn off the vacuum pump; take out the container after cooling to room temperature, use a 200-mesh standard sieve to screen the vanadium-coated superhard abrasive grains, and then polish with 1000-mesh sandpaper , to remove excess metal particles adhered to the surface of the abrasive grains.

[0031] Evenly spread the vanadium-coated superabrasive grains in a stainless steel container, put the container into the vacuum reaction furnace chamber of the silicon plating equipment; turn on the vacuum pump and heating valve, heat to 660°C under 97Pa vacuum degree, and keep warm for...

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Abstract

A surface-coated active metal-coated silicon-coated superhard abrasive grain, which is coated with active metal on the surface of diamond or cubic boron nitride with a particle size of not less than 0.1 microns, and then coated with a layer of cubic boron nitride on the surface of the coated active metal layer. phase crystalline silicon; the manufacturing method is to put the above-mentioned superhard abrasive grains and active metal powder into a stainless steel container and put them into a vacuum reaction furnace cavity, heat up and vacuumize, and spread the above-mentioned superhard abrasive grains coated with active metal on the stainless steel Put the container into the vacuum reaction chamber of the silicon plating equipment, turn on the vacuum pump and heating valve, introduce the silane precursor gas, saturate and adsorb it at 200~1500Pa for 5~25 minutes, and extract the remaining gas and reaction product gas. The coating equipment of the present invention is simple and reliable, easy to operate, and low in cost. The anti-oxidation ability and thermal stability of the superhard abrasive grains are greatly improved, which can effectively prevent the shedding of the abrasive, increase the holding force of the matrix to the abrasive, and prolong the service life of the abrasive tool. longer.

Description

technical field [0001] The invention relates to a superhard material and a preparation method, in particular to a superhard abrasive grain and a preparation method. Background technique [0002] Superhard materials diamond and cubic boron nitride are widely used in many sectors of the national economy due to their high hardness, high wear resistance, high thermal conductivity and other comprehensive properties. Most of the superhard abrasives are used for cutting, grinding, Polishing and dressing tools are used, but due to the fine particles of industrial diamond and cubic boron nitride, most of the tools need to rely on metal, ceramics or resin as the matrix, and bond their fine particles together to become various superhard tools , to realize the processing of the workpiece. Therefore, the service life and efficiency of superhard tools are not only related to the selected superhard abrasive grains and bonding agent, but also depend on the bonding strength of superhard abr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22F1/00C23C16/02C23C16/24
Inventor 臧建兵王艳辉成晓哲
Owner YANSHAN UNIV