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Resourceful treatment method for silica gel waste water

A treatment method and recycling technology, applied in the field of comprehensive resource treatment of silica gel wastewater, can solve problems such as the difficulty of silica wastewater treatment, achieve significant environmental and social benefits, save freshwater resources, and achieve significant environmental benefits.

Inactive Publication Date: 2012-09-26
ZHEJIANG MARINE DEV RES INST
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is to provide a resource-based treatment method for silica gel wastewater that has a reasonable sewage treatment process, better treatment effect and can be directly reused after treatment, so as to solve the technical problem that the treatment of silica gel wastewater is difficult at present

Method used

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  • Resourceful treatment method for silica gel waste water
  • Resourceful treatment method for silica gel waste water

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] like figure 1 The shown silica gel wastewater resource treatment method, the method comprises the following steps:

[0026] 1. Water quality adjustment

[0027] In the water quality adjustment tank, add lime to the silica gel waste water to adjust the pH to the range of 7-8.

[0028] 2. Coagulation and silicon removal

[0029] The pH-adjusted wastewater flows into the coagulation sedimentation tank, and 300 mg / L calcium chloride and 100 mg / L magnesium chloride are added to the wastewater, and mixed to remove dissolved silicon in the wastewater, and then 150 mg / L is added to the wastewater Ferric chloride solution, fully mixed to form alum flowers, and finally add 2 mg / L polyacrylamide to increase the size of the alum flowers and accelerate the settlement. The wastewater stays in the coagulation sedimentation tank for 45 minutes and is separated from the slag water to obtain Clearer supernatant.

[0030] The above-mentioned calcium chloride, magnesium chloride, ferri...

Embodiment 2

[0039] The specific method is the same as in Example 1, the difference is that the dosages of calcium chloride, magnesium chloride, ferric chloride, and polyacrylamide are respectively 200 mg / L, 50 mg / L, and 100 mg / L in terms of per liter of waste water , 1mg / L; the hydraulic retention of wastewater in the coagulation sedimentation tank is 60 minutes; in the ceramic membrane filtration, the ceramic membrane with a pore size of 0.2μm is selected, and the operating pressure is 0.2Mpa; the nanofiltration membrane is cellulose acetate with a molecular weight cut-off of 150 Membrane: The operating pressure of nanofiltration membrane filtration is 2.5MPa, and the operating temperature is 40°C.

[0040] The concentration ratio of the concentrated water obtained in this example was 3.4 times, and the sodium sulfate content was 9.68%. High-quality sodium sulfate solids were obtained after evaporation and drying; see Table 3 for the effluent quality of nanofiltration membrane.

[0041] ...

Embodiment 3

[0044] The specific method is the same as in Example 1, the difference is that the dosages of calcium chloride, magnesium chloride, ferric chloride and polyacrylamide are respectively 400 mg / L, 80 mg / L and 200 mg / L in terms of per liter of waste water , 5 mg / L; the hydraulic retention of wastewater in the coagulation sedimentation tank is 60 minutes; in the ceramic membrane filtration, the ceramic membrane with a pore size of 0.2 μm is selected, and the operating pressure is 0.2Mpa; the nanofiltration membrane is a composite nanofiltration with a molecular weight cut-off of 300 Membrane: The operating pressure of nanofiltration membrane filtration is 2.5MPa, and the operating temperature is 20°C.

[0045] The concentration ratio of the obtained concentrated water was 3.5 times, and the sodium sulfate content was 9.98%. High-quality sodium sulfate solids were obtained after evaporation and drying;

[0046] Table 4 The effluent quality of nanofiltration membrane filtration

[004...

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Abstract

The invention belongs to the technical field of water treatment, and in particular relates to a resourceful treatment method for silica gel waste water. The treatment method mainly comprises the following steps: (1) water quality regulation; (2) silica removal by coagulation; (3) ceramic membrane filtration; and (4) nanofiltration membrane filtration. In the step of silica removal by coagulation, calcium chloride, magnesium chloride, ferric chloride and polyacrylamide are added in the form of an aqueous solution into waste water, wherein the addition amount of calcium chloride, magnesium chloride, ferric chloride and polyacrylamide are respectively 200-400 mg / L, 50-100mg / L, 100-200 mg / L, and 1-5 mg / L in per liter of the waste water. A nanofiltration penetrating liquid of the invention can be reused in production to replace partial fresh water, thereby avoiding pollution and saving abundant fresh water resources at the same time; and a concentrated liquid of the invention can be used in the production of high-quality sodium sulfate, therefore the treatment method of the invention has significant environmental benefits, social benefits, and economic benefits.

Description

technical field [0001] The invention belongs to the technical field of water treatment, and in particular relates to a comprehensive resource treatment method of silica gel wastewater. Background technique [0002] The main raw material for the production of silica gel is sodium silicate (commonly known as water glass, sodium silicate), which is obtained by chemical processing of silica. That is, the melt produced by calcining quartz ore powder and soda ash at a high temperature of 1100-1350°C is soaked in water to obtain a colorless and transparent viscous liquid. The production methods of silica gel are: (1) sulfuric acid method, which is obtained by reacting sodium silicate and sulfuric acid (other acids can also be used); (2) double decomposition method, which is obtained by the action of sodium silicate and water-soluble salts; (3) ) Precipitation method, which is obtained by precipitating silica gel from alkali metal silicate solutions with the help of various organic...

Claims

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Application Information

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IPC IPC(8): C02F9/04C01D5/00C02F1/66C02F1/52C02F1/56C02F1/44
Inventor 范会生陆阿定张海春郁小芬王波孙保库孙兆栋
Owner ZHEJIANG MARINE DEV RES INST