Chemical synthetic method of potential medicines g x50, g x52, g x 52, g x 180 for preventing and treating Alzheimer disease
A technology for Alzheimer's disease and chemical synthesis, which can be used in chemical instruments and methods, organic chemistry, preparation of organic compounds, etc., and can solve problems such as low yields
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[0013] Scheme 1, by aryl acrylic acid I a Synthesis of aryl acryloyl activated intermediate I a’ , and then with arylethylamine I b Reaction synthesis target compound II:
[0014] 1.1.1 Weigh 5.00g (33.7mmol) of aryl acrylic acid Ia into a 100ml three-necked flask and measure 30.0ml of DCM, SOCl 2 1 Add 2.20ml (168.1mmol) to the constant pressure dropping funnel, install a condenser tube, dry the tube, and saturate with K 2 CO 3 The solution absorbs the exhaust gas. Add SOCl dropwise at room temperature 2 Heating to reflux for 2.0h reaction after completion, removing the solvent under reduced pressure, measuring 5.0ml DCM and adding it to the concentrated solution to depressurize again to take out the low boiling point fraction. Activated intermediate Ia' 5.58g.
[0015] 1.1.2 Weigh 5.00g (33.7mmol) of aryl acrylic acid Ia into a 100ml three-necked flask, measure 30.0ml of toluene, SOCl 2 Add 2.94ml (40.5mmol) into the constant pressure dropping funnel, install a conde...
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