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Polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester and preparation method thereof

A technology of alkenyl succinate monoalkyl ester and polyethylene glycol double, which is applied in the field of steel rolling oil, can solve the problems of complex rolling oil formula, and achieve the problem of complex formula and excellent emulsifying performance Effect

Active Publication Date: 2013-11-20
JINGJIANG HENGFENG CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of this invention is to provide a kind of polyethylene glycol double alkenyl succinate monoalkyl ester and preparation method, by adopting a specific The chemical molecular structure makes it have excellent emulsifying properties. Adjusting the ratio of the general-purpose low-molecular emulsifier and the invented high-molecular emulsifier for compound use can control the diameter of the emulsion particles of the steel rolling oil produced, and in Maintain the required stable lubricating performance during the rolling process of the steel plate, and have a low tendency to generate oil coke and good annealing cleanliness after the rolling of the steel plate, solving the problem of complex rolling oil formulations

Method used

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  • Polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester and preparation method thereof
  • Polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester and preparation method thereof
  • Polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester and preparation method thereof

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Embodiment

[0028] In a three-necked flask with a reflux condenser, add 265 grams of dodecenyl maleic anhydride in a nitrogen atmosphere, add 1% toluenesulfonic acid of the weight of dodecenyl maleic anhydride as a catalyst, then add 186 gram of lauryl fatty alcohol, and 10% dehydrating agent in total, heated up to 115-120°C under stirring, and analyzed the acid value of the reaction system every 0.5 hours during the reaction until the acid value remained unchanged, and the reaction time was 4-5 hour; then add 102 grams of polyethylene glycol (average molecular weight 200), and heat up to 150-160°C under stirring. During the reaction, analyze the acid value of the reaction system every 0.5 hours until the acid value remains unchanged. The reaction time is 6-8 hours, until no water is evaporated, and then the solution is decompressed to make the vacuum of the system reach 0.07-0.08Mpa, and the solvent xylene is evaporated. The product of the reaction is the product.

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Abstract

The invention provides polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester. The polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester comprises alkenyl maleic anhydride with appropriate alkyl, alkyl fatty alcohol, polyethylene glycol with appropriate degree of polymerization and a catalyst. According to a preparation method of the polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester, the alkenyl maleic anhydride with the appropriate alkyl reacts with the alkyl fatty alcohol under the action of the catalyst to generate monoalkyl alkenyl succinate; the monoalkyl alkenyl succinate reacts with the polyethylene glycol with an appropriate degree of polymerization to obtain the polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester. The polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester has excellent emulsifying property due to adoption of a specific chemical molecular structure; a universal low-molecular-weight emulsifying agent and the invented high-molecular-weight emulsifying agent are compounded in an adjusted proportion for use; the diameters of emulsion particles of produced steel plate rolling oil can be controlled; and required stable lubrication property in a steel plate rolling process can be maintained. The prepared the polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester has low oil coke generation tendency and good annealing detergency property after rolling of steel plates and overcomes the problem of complexity of a rolling oil formula. The polyethylene glycol double-alkenyl succinic acid monoalkyl-ester ester is used in the field of steel plate rolling.

Description

technical field [0001] The invention relates to the field of steel plate rolling oil, in particular to a steel plate rolling oil emulsification additive polyethylene glycol bisalkenyl succinate monoalkyl ester having emulsifying performance and capable of stabilizing the particle size of the emulsified liquid and a preparation method thereof. Background technique [0002] The present invention relates to a lubricating oil additive for cold rolling steel sheets and strips. When cold-rolling steel plates, it must go through various processes such as pickling-cold rolling-cleaning-annealing-levelling-inspection. The composition of general steel plate cold rolling oil is based on grease, mineral oil or fatty acid synthetic fat, etc., adding various emulsifiers, antirust agents, extreme pressure agents, lubricants, oily agents, antioxidants and other additives. into an oil-in-water emulsion. Usually used at a concentration of 1-20%, it can play a lubricating role to prevent th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G65/48C07C69/593C07C67/08C10M145/38
Inventor 韦利行任晓平赵洪
Owner JINGJIANG HENGFENG CHEM IND CO LTD
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