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Polyethylene glycol bisalkenyl succinate monoalkyl ester and preparation method thereof

A technology of monoalkyl alkenyl succinate and polyethylene glycol, which is applied in the field of steel plate rolling oil, can solve the problems of complex rolling oil formulation, and achieves the advantages of solving the problem of formula complexity and excellent emulsifying performance. Effect

Active Publication Date: 2018-04-17
JINGJIANG HENGFENG CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of this invention is to provide a kind of polyoxyethylene glycol double alkenyl succinate monoalkyl ester and preparation method, by adopting a kind of specific chemical molecular structure of design, make it have excellent emulsifying performance, regulate general-purpose The ratio of the low-molecular emulsifier and the invented high-molecular emulsifier can be used in combination to control the diameter of the emulsion particles of the produced steel plate rolling oil, and maintain the required stable lubricating performance during the steel plate rolling process, and has Low oil coke formation tendency and good post-rolling annealing cleanliness to solve the complex problem of rolling oil formulation

Method used

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  • Polyethylene glycol bisalkenyl succinate monoalkyl ester and preparation method thereof
  • Polyethylene glycol bisalkenyl succinate monoalkyl ester and preparation method thereof
  • Polyethylene glycol bisalkenyl succinate monoalkyl ester and preparation method thereof

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Embodiment

[0028] In a three-necked flask with a reflux condenser, add 265 grams of dodecenyl maleic anhydride in a nitrogen atmosphere, add 1% toluenesulfonic acid of the weight of dodecenyl maleic anhydride as a catalyst, then add 186 gram of lauryl fatty alcohol, and 10% dehydrating agent in total, heated up to 115-120°C under stirring, and analyzed the acid value of the reaction system every 0.5 hours during the reaction until the acid value remained unchanged, and the reaction time was 4-5 hour; then add 102 grams of polyethylene glycol (average molecular weight 200), and heat up to 150-160°C under stirring. During the reaction, analyze the acid value of the reaction system every 0.5 hours until the acid value remains unchanged. The reaction time is 6-8 hours, until no water is distilled off, and then the solution is decompressed to make the vacuum of the system reach 0.07-0.08MPa, and the solvent xylene is distilled off. The product of the reaction is the product.

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Abstract

Polyethylene glycol bisalkenyl succinate monoalkyl esters comprising the following ingredients: alkenyl maleic anhydride of a suitable alkyl group, an alkyl fatty alcohol, polyethylene glycol of a suitable degree of polymerization, a catalyst, a suitable alkyl Alkenyl maleic anhydride and alkyl fatty alcohol react under the action of catalyst to generate alkenyl succinic acid monoalkyl ester, alkenyl succinic acid monoalkyl ester and polyethylene glycol with appropriate degree of polymerization , The reaction gives polyethylene glycol double alkenyl succinic acid monoalkyl ester. The present invention adopts a specific chemical molecular structure to make it have excellent emulsifying properties, and adjusts the ratio of the general-purpose low-molecular emulsifier and the invented high-molecular emulsifier to be used together to control the produced steel plate rolling oil. The diameter of the emulsion particles can be adjusted, and the required stable lubricating performance can be maintained during the steel rolling process. It has low oil coke formation tendency and good steel plate post-rolling annealing cleanliness, and solves the problem of complex rolling oil formulation. The invention is used in the field of steel plate rolling.

Description

technical field [0001] The invention relates to the field of steel plate rolling oil, in particular to a steel plate rolling oil emulsification additive polyethylene glycol bisalkenyl succinate monoalkyl ester having emulsifying performance and capable of stabilizing the particle size of the emulsified liquid and a preparation method thereof. Background technique [0002] The present invention relates to a lubricating oil additive for cold rolling steel sheets and strips. When cold-rolling steel plates, it must go through various processes such as pickling-cold rolling-cleaning-annealing-levelling-inspection. The composition of general steel plate cold rolling oil is based on grease, mineral oil or fatty acid synthetic fat, etc., adding various emulsifiers, antirust agents, extreme pressure agents, lubricants, oily agents, antioxidants and other additives. into an oil-in-water emulsion. Usually used at a concentration of 1-20%, it can play a lubricating role to prevent the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G65/48C07C69/593C07C67/08C10M145/38
Inventor 韦利行任晓平赵洪
Owner JINGJIANG HENGFENG CHEM IND CO LTD
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