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Preparation process of a strippable semiconductive outer shielding material

A preparation process and outer shielding technology, which is applied in the field of preparation technology of strippable semi-conductive outer shielding materials for cables, can solve the problems of large amount of conductive carbon black added, affecting product performance, and poor material fluidity.

Inactive Publication Date: 2015-10-07
苏州市双鑫新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The existing semi-conductive outer shielding materials are mainly prepared by adding conductive carbon black with certain conductivity to the base material of polymer composite materials, and then adding other auxiliary materials. However, the selection of base materials and auxiliary materials, especially for each composition There is no unanimous opinion on the formula, but it is precisely these components and their content that have an extremely important impact on the subsequent product preparation process and the final product performance
For example, the base material adopts ethylene-propylene rubber, polyvinyl chloride and other materials with high molecular weight, which have poor capacity for fillers, and the addition of conductive carbon black is large, which leads to poor fluidity of the material and subsequent extrusion processing. However, the commonly used ethylene-vinyl acetate copolymer as a base material has defects such as poor peelability from the insulating layer, VA is thermally decomposed during extrusion processing, and particles are produced on the surface, which affects product performance.

Method used

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  • Preparation process of a strippable semiconductive outer shielding material
  • Preparation process of a strippable semiconductive outer shielding material
  • Preparation process of a strippable semiconductive outer shielding material

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Embodiment 1

[0019] According to the distribution ratio of each group given in Table 1, the ingredients are mixed and all the raw materials are dried to 100°C for standby; then the EPDM rubber (A) is masticated first, and the roller temperature is controlled at 70°C during the mastication. Plasticizing time 5-10min; then press ethylene-vinyl acetate copolymer (B), conductive carbon black (C), plasticizer (D), reinforcing agent (E), antioxidant (F), stripping agent (G) ), antioxidant (H) sequence, each raw material is added to the internal mixer for mixing, the mixing temperature is 100-120℃, and the mixing time is 10-15min; then the plasticized EPDM rubber Put into the internal mixer for melting and mixing, the mixing temperature is 170-190℃, and the mixing time is 5-10min; after mixing and discharging, it is extruded and granulated by a single screw extruder, and then enters high-speed kneading after granulation The machine sprays the cross-linking agent (I) and mixes at high speed, and th...

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Abstract

The invention provides a formula of a strippable semiconductive outer shielding material and a preparation process thereof. The formula consists of the following components in parts by weight: 100 parts of base material, 50-55 parts of conductive carbon black, 2-4 parts of stripping agent, 3-5 parts of antioxidant, 3-5 parts of crosslinking agent, 1-3 parts of reinforcing agent, 0.5-1 part of anti-aging agent and 10-12 parts of plasticizer. The preparation process comprises the following steps: plastifying the base material in the formula; sequentially adding the base material, the conductive carbon black, the plasticizer, the reinforcing agent, the anti-aging agent, the stripping agent and the antioxidant, and performing melting mixing; and after the mixing, extruding and granulating and performing high-speed mixing and high-temperature crosslinking. According to the semiconductive outer shielding material provided by the invention, through the coordination effect of the components and the optimal content proportions as well as a proper preparation process, excellent mechanical property, stripping property, flame retardance, conductivity and temperature stability are obtained.

Description

Technical field [0001] The invention relates to the technical field of composite materials, in particular to a preparation process of a peelable semi-conductive outer shielding material for cables. Background technique [0002] The wire and cable industry is an important supporting industry for the two pillar industries of the national economy, electric power and communications, and has an extremely important position in the national economy. The total output of the industry accounts for 4‰ to 5‰ of the total GDP of the country. Wire and cable products play a role in transportation. The important role of energy and information transmission is the "blood vessel" and "nerve" of the national economy. [0003] Insulated cables are usually composed of conductor cores covered with insulating layers. As we all know, in higher high-voltage direct current electric fields, the presence of fine unevenness in insulated cables can easily cause the insulation between the insulating layer and the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/08C08L23/16C08L23/30C08L81/02C08K13/04C08K7/00C08K3/04C08K7/08C08K3/22C08K5/134C08K5/14C08K5/098C08K5/18
CPCC08K2201/001C08K2201/003C08L31/04C08L2201/02C08L2203/202C08L2205/035H01B7/17C08L23/16C08L23/30C08L81/02C08K13/04C08K7/24C08K3/04C08K7/08C08K5/1345C08K5/14C08K5/098C08K5/18
Inventor 杨雪洪
Owner 苏州市双鑫新材料科技有限公司