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CuO/Ni/carbon fiber composite absorbing material and preparation method thereof

A composite wave-absorbing material and carbon fiber technology, applied in chemical instruments and methods, metal material coating technology, other chemical processes, etc., can solve problems such as narrow absorption frequency band and weak absorption strength, and achieve the effect of excellent impedance matching characteristics

Inactive Publication Date: 2015-07-08
ENG UNIV OF THE CHINESE PEOPLES ARMED POLICE FORCE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to overcome the problems of weaker absorption strength and narrower absorption frequency band of existing carbon fiber reinforced composite wave-absorbing materials, and provide a kind of CuO / Ni / carbon fiber composite wave-absorbing material and its preparation method

Method used

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  • CuO/Ni/carbon fiber composite absorbing material and preparation method thereof
  • CuO/Ni/carbon fiber composite absorbing material and preparation method thereof
  • CuO/Ni/carbon fiber composite absorbing material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] 1) Soak the carbon fiber in acetone and sonicate for 30 minutes, then clean it with distilled water to get a clean carbon fiber;

[0030] 2) Put the clean carbon fiber into concentrated nitric acid with a mass concentration of 65% for roughening treatment. The specific method of roughening: soak the clean carbon fiber in concentrated sulfuric acid while ultrasonically treating it for 1 hour, and then continue soaking in concentrated nitric acid for 6 hours , followed by washing with distilled water to neutrality to obtain roughened carbon fibers; ultrasonic treatment while soaking clean carbon fibers can make carbon fibers fully contact with concentrated nitric acid;

[0031] 3) Electrodeposit the coarsened carbon fibers in the nickel plating solution. During the electrodeposition, the nickel plating solution is continuously stirred under the condition of a constant temperature water bath at 25°C, so that the surface of the carbon fibers is electrodeposited with a metal ...

Embodiment 2

[0035] 1) Soak the carbon fiber in acetone and sonicate for 30 minutes, then clean it with distilled water to get a clean carbon fiber;

[0036] 2) Put the clean carbon fiber into concentrated nitric acid with a mass concentration of 65% for roughening treatment. The specific method of roughening: soak the clean carbon fiber in concentrated sulfuric acid while ultrasonically treating it for 1 hour, and then continue soaking in concentrated nitric acid for 6 hours , followed by washing with distilled water to neutrality to obtain roughened carbon fibers; ultrasonic treatment while soaking clean carbon fibers can make carbon fibers fully contact with concentrated nitric acid;

[0037] 3) Electrodeposit the coarsened carbon fibers in the nickel plating solution. During the electrodeposition, the nickel plating solution is continuously stirred under the condition of a constant temperature water bath at 25°C, so that the surface of the carbon fibers is electrodeposited with a metal ...

Embodiment 3

[0041] 1) Soak the carbon fiber in acetone and sonicate for 30 minutes, then clean it with distilled water to get a clean carbon fiber;

[0042] 2) Put the clean carbon fiber into concentrated nitric acid with a mass concentration of 65% for roughening treatment. The specific method of roughening: soak the clean carbon fiber in concentrated sulfuric acid while ultrasonically treating it for 1 hour, and then continue soaking in concentrated nitric acid for 6 hours , followed by washing with distilled water to neutrality to obtain roughened carbon fibers; ultrasonic treatment while soaking clean carbon fibers can make carbon fibers fully contact with concentrated nitric acid;

[0043] 3) Electrodeposit the coarsened carbon fibers in the nickel plating solution. During the electrodeposition, the nickel plating solution is continuously stirred under the condition of a constant temperature water bath at 25°C, so that the surface of the carbon fibers is electrodeposited with a metal ...

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Abstract

The invention discloses a CuO / Ni / carbon fiber composite absorbing material and a preparation method thereof. The method comprises the following steps: carrying out electrolytic deposition on a coarsened carbon fiber in a nickel plating solution, so that a metal nickel layer is deposited on the surface of the carbon surface; then filtering the carbon fiber with the metal nickel layer deposited on the surface, cleaning and drying, so as to obtain a nickel-plated carbon fiber; adjusting the pH value of a chemical copper plating solution to 11-13, and then carrying out chemical copper plating on the nickel-plated carbon fiber; filtering, cleaning and drying to obtain a nickel-plated copper carbon fiber; putting the nickel-plated copper carbon fiber into a tubular furnace to oxidize in air at 300-450 DEG C; then naturally cooling to room temperature, so as to obtain the CuO / Ni / carbon fiber composite absorbing material. The CuO / Ni / carbon fiber composite absorbing material structurally comprises a carbon fiber and a metal nickel layer coated on the surface of the carbon fiber, wherein a CuO layer is also coated on the surface of the metal nickel layer. By adopting the preparation method of the CuO / Ni / carbon fiber composite absorbing material, the carbon fiber has excellent impedance matching characteristics on the basis of keeping the original performance, and can have two electromagnetic wave loss mechanisms of dielectric loss and magnetic loss. Therefore, the CuO / Ni / carbon fiber composite absorbing material is high in absorption strength and wide in absorption band.

Description

technical field [0001] The invention belongs to the field of microwave absorbing materials, in particular to a CuO / Ni / carbon fiber composite absorbing material and a preparation method thereof. Background technique [0002] Carbon fiber has a series of excellent characteristics: high tensile strength, up to 3000-4000MPa, 4 times higher than steel, 6-7 times higher than aluminum; high elastic modulus, up to 600GPa; low density, high specific strength, The density is 1 / 4 of steel and 1 / 2 of aluminum. The specific strength is 16 times greater than steel and 12 times greater than aluminum alloy. It has good high and low temperature resistance. When the temperature is higher than 400 ° C, obvious oxidation occurs. Generate CO and CO 2 ;In a non-oxidizing atmosphere, it can be used at 2000°C; at -180°C, steel becomes more brittle than glass, while carbon fiber is still very soft; strong corrosion resistance, able to withstand concentrated hydrochloric acid, sulfuric acid, phospho...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K3/00C23C28/00
Inventor 曾俊薛军
Owner ENG UNIV OF THE CHINESE PEOPLES ARMED POLICE FORCE