Biodegradable polylactic acid resin composition and product

A technology of polylactic acid resin and biodegradable polyester is applied in the fields of biodegradable polylactic acid resin composition and biodegradable plastic composition, and can solve the problems of high cost of plasticizer and low plasticization efficiency.

Inactive Publication Date: 2014-12-17
TORAY ADVANCED MATERIALS RES LAB CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the cost of this type of plasticizer is relatively expensive, and the plasticizing efficiency is low

Method used

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  • Biodegradable polylactic acid resin composition and product
  • Biodegradable polylactic acid resin composition and product
  • Biodegradable polylactic acid resin composition and product

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-11, comparative example 1-7

[0064] According to the proportion listed in Table 1, use a twin-screw extruder to extrude and granulate, and the extrusion temperature is 180-200°C.

[0065] After the particles were vacuum-dried at 80° C. for 8 hours, the particles were equally divided into 2 parts.

[0066] The first batch of particles was blown by a single-screw extruder to prepare a film with a thickness of 20 μm. The blow molding temperature is 180-200°C. Various performance tests were carried out on the obtained film, and the results are listed in Table 2. Comparative examples 1 and 6-7 had poor formability and could not be formed into films.

[0067] The second part of particles is injection-molded into impact test specimens by an injection molding machine, and the injection molding temperature is 180-220°C. The impact properties of the obtained splines were tested, and the results are listed in Table 2.

Embodiment 12-16

[0069] According to the proportioning in Table 3, use a twin-screw extruder to extrude and granulate, and the extrusion temperature is 180-200°C. Next, a film with a thickness of 100 μm is prepared by single-screw extrusion casting at a casting temperature of 180-220° C. Then, various performance tests were carried out on the obtained film, and the results are listed in Table 4.

Embodiment 17-21

[0071] According to the proportioning of Example 9, a twin-screw extruder is used to extrude and granulate, and the extrusion temperature is 180-200°C. Next, a raw film with a thickness of 100 μm was prepared by single-screw extrusion casting at a casting temperature of 180-220° C. Furthermore, under the conditions shown in Table 5, the original film was stretched, and then various performance tests were performed on the obtained film, and the results are listed in Table 5.

[0072] The biodegradable polylactic acid resin composition and products of the present invention have biodegradability, do not cause white pollution, are environmentally friendly, soft in nature, good in toughness, comfortable in touch, excellent in molding processability, and low in exudation rate. Compared with the comparison example, it is a more advantageous technology.

[0073]

[0074] table 3

[0075]

[0076] Table 4

[0077]

[0078] table 5

[0079] Note 1: Stretch in TD directi...

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Abstract

The invention discloses a biodegradable polylactic acid resin composition and a thin film prepared from the composition. The composition comprises the following components in parts by weight: (A) 10-89 parts by weight of polylactic acid resin, (B) 10-89 parts by weight of biodegradable polyester or polycarbonate except polylactic acid, and (C) 1-40 parts by weight of compounds having the following chemical structure described in the specification or a mixture thereof, wherein R1 and R2 are the same or different and are respectively selected from one or more of hydrogen atoms, and alkyl, alkylene, aryl, hydroxyl, ether, carbonyl, carboxyl or ester with the number-average molecular weight of 15-1000. The thin film prepared from the composition can be completely biodegraded, and besides, also has a suitable use period. Therefore, the composition can be widely applied in agricultural thin films, fresh-keeping films, gift packaging films and other packaging materials.

Description

technical field [0001] The invention belongs to the field of macromolecular materials, and relates to a biodegradable plastic composition, specifically, a biodegradable polylactic acid resin composition with toughness and flexibility. Background technique [0002] The composition of polylactic acid resin and biodegradable polyester or polycarbonate other than polylactic acid has some properties superior to that of polylactic acid resin alone, for example, in some cases, the toughness and flexibility of the composition are improved. CN102875986A discloses a composition of polylactic acid and polybutylene succinate with good toughness, and CN102906193A discloses another composition of polylactic acid and polyhydroxyalkanoate with good toughness. In addition, in order to better improve toughness and flexibility, a third component needs to be added. CN102892817A discloses a polylactic acid-based film, using a plasticizer having a polyether-based segment and a polylactic acid se...

Claims

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Application Information

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IPC IPC(8): C08L67/04C08L67/02C08L69/00C08K13/02C08K5/1535
Inventor桂宗彦王春江小慧阮晓白长田俊一
OwnerTORAY ADVANCED MATERIALS RES LAB CHINA