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A kind of high-strength anti-wicking polyester industrial yarn and its preparation method

An anti-wicking, industrial yarn technology, applied in conductive/anti-static filament manufacturing, rayon manufacturing, cyanide reaction preparation, etc., can solve problems such as no anti-wicking effect and unusable use

Active Publication Date: 2017-08-22
JIANGSU HENGLI CHEM FIBER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the production process of this ultra-low shrinkage polyester industrial yarn, ordinary oil is used for oiling without adding anti-wicking agent. The obtained product has no anti-wicking effect and cannot be used in high-end light box advertising cloth and swimming pool fabrics and other fields.

Method used

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  • A kind of high-strength anti-wicking polyester industrial yarn and its preparation method
  • A kind of high-strength anti-wicking polyester industrial yarn and its preparation method
  • A kind of high-strength anti-wicking polyester industrial yarn and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0104] A preparation method of high-strength anti-wicking polyester industrial yarn, comprising the following steps:

[0105] (1) Preparation of anti-wicking agent

[0106] The synthetic steps of perfluoroalkyl (meth) acrylate, non-fluorinated alkyl (meth) acrylate and ternary block copolymer containing anti-ultraviolet groups are:

[0107] 1) Preparation of brominated end-capped polyperfluoroalkyl (meth)acrylate macroinitiator:

[0108] In a container under nitrogen protection, add catalyst CuBr, monomer perfluoroalkyl (meth)acrylate, solvent toluene, complexing agent pentamethyldiethyltriamine, initiator 2-ethyl bromopropionate , wherein initiator: catalyst: complexing agent: the molar ratio of monomer is 1:1:2:120, be warming up to 65 ℃, constant temperature reaction 6h; Dissolve with tetrahydrofuran after reaction finishes, pass column separation copper salt through alumina, The filtrate was precipitated with absolute ethanol to obtain a polymer, and the polymer was drie...

Embodiment 2

[0136] A preparation method of high-strength anti-wicking polyester industrial yarn, comprising the following steps:

[0137] (1) Preparation of anti-wicking agent

[0138] The synthetic steps of perfluoroalkyl (meth) acrylate, non-fluorinated alkyl (meth) acrylate and ternary block copolymer containing anti-ultraviolet groups are:

[0139] 1) Preparation of brominated end-capped polyperfluoroalkyl (meth)acrylate macroinitiator:

[0140] In a container under nitrogen protection, add catalyst CuBr l, monomer perfluoroalkyl (meth)acrylate, solvent toluene, complexing agent pentamethyldiethyltriamine, initiator 2-bromopropionic acid ethyl Ester, wherein the molar ratio of initiator:catalyst:coordinating agent:monomer is 1:1:2:120, the temperature is raised to 75°C, and the temperature is reacted for 6h; after the reaction is completed, it is dissolved in tetrahydrofuran, and the copper salt is separated through the column of alumina , the filtrate is precipitated with absolute ...

Embodiment 3

[0167] A preparation method of high-strength anti-wicking polyester industrial yarn, comprising the following steps:

[0168] (1) Preparation of anti-wicking agent

[0169] The synthetic steps of perfluoroalkyl (meth) acrylate, non-fluorinated alkyl (meth) acrylate and ternary block copolymer containing anti-ultraviolet groups are:

[0170] 1) Preparation of brominated end-capped polyperfluoroalkyl (meth)acrylate macroinitiator:

[0171] In a container under nitrogen protection, add catalyst CuBr l, monomer perfluoroalkyl (meth)acrylate, solvent toluene, complexing agent pentamethyldiethyltriamine, initiator 2-bromopropionic acid ethyl Ester, wherein the molar ratio of initiator:catalyst:coordinating agent:monomer is 1:1:2:120, the temperature is raised to 66°C, and the reaction is carried out at constant temperature for 6h; after the reaction is completed, it is dissolved in tetrahydrofuran, and the copper salt is separated through the column of alumina , the filtrate is pr...

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Abstract

The invention relates to a high-strength anti-wicking polyester industrial yarn and a preparation method thereof. The modified polyester viscosifying slice is used as a raw material, and is made through melt spinning and post-treatment; the modified polyester is composed of polyester and Amino fatty acid ethylene glycol ester is formed, the amino fatty acid ethylene glycol ester is dispersed among the molecular chains of the polyester, and there is a hydrogen bond between the amino fatty acid ethylene glycol ester and the polyester molecular chain, The relative positions of the amino fatty acid ethylene glycol ester and the molecular chain of the polyester are fixed; the anti-wicking agent contains perfluoroalkyl (meth)acrylate, non-fluorinated alkyl (meth)acrylate And ternary block copolymers containing UV-resistant groups. The product not only has the inherent high breaking strength of high-strength polyester industrial yarn, but also has good hydrophobic properties and good anti-ultraviolet aging properties. It can be widely used outdoors in the fields of high-end light box advertising cloth, waterproof cloth and swimming pool fabrics. It has very broad application prospects.

Description

technical field [0001] The invention belongs to the technical field of fiber modification, and relates to a high-strength anti-wicking polyester industrial yarn and a preparation method thereof. Background technique [0002] In recent years, with the development of high-grade light box advertising fabrics, swimming pool fabrics and sunshade fabrics, the market demand and application prospects of anti-wicking polyester industrial yarns have become increasingly broad. Anti-wicking polyester industrial yarn refers to the introduction of -CF on the surface of the fiber 2 The group reduces the surface tension of the fiber and makes the fiber surface difficult to infiltrate, thereby endowing polyester with superior water repellency and oil repellency, and making the fiber surface have good low moisture absorption performance. [0003] The active ingredients of anti-wicking agents are fluorocarbons. Fluorocarbons are surfactants with amphiphilic groups, respectively containing a ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/14D01F8/10D01F1/09D01F1/10C08G63/685C08G63/183C08G63/78C07C227/18C07C229/08C08F293/00C08F120/24C08F8/20D01D5/08D01D5/088
Inventor 张耀鹏杨大矛刘亚涛赵慧荣宋光坤范晓兵蔡明建
Owner JIANGSU HENGLI CHEM FIBER