resist stripper
A technology of resist stripper and anti-corrosion agent, applied in the field of photolithography, can solve problems such as wiring corrosion, and achieve the effects of excellent corrosion resistance, good corrosion resistance effect and lower production cost
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[0038] The preparation method of described hydroxyethyl-oleic acid imidazoline is specifically:
[0039]Add 1L of oleic acid and 400mL of hydroxyethylethylenediamine into a 2.5L reaction vessel, the reaction vessel is connected with a water separator and a condenser, then add 450ml of xylene in the reaction vessel as a water-carrying agent, start the mixer, and heat up to Reflux began at 150°C, water was generated, and after reflux for 2 hours, the temperature was raised to 230°C, and the reaction was completed for 6 hours. The excess solvent was evaporated under reduced pressure, and the product was completely dried in a drying oven to obtain the product.
[0040] The structural formula of hydroxyethyl-oleic acid imidazoline is as follows:
[0041]
[0042] The organic solvent includes one or more substances selected from the group consisting of N-methylpyrrolidone (NMP), 1,3-dimethyl-2-imidazolinone (DMI), dimethylsulfoxide (DMSO) , dimethylacetamide (DMAc), dimethylform...
Embodiment 1
[0054] The preparation of embodiment 1 imidazolinone formamide compound
[0055] Put 50g of 4-chloroacetophenone and 20ml of glacial acetic acid into a 300ml reaction vessel in turn, add 45g of bromine solution dropwise under mechanical stirring at room temperature, keep 1ml / min, after the addition is complete, continue to react for 1 hour, and pour the reaction solution into saturated carbonic acid In the sodium solution, adjust the pH value to neutral, extract with dichloromethane containing ice cubes, wash the extract twice with saturated sodium carbonate, and wash with water successively, dry the organic layer with anhydrous sodium sulfate, and remove the dichloromethane under reduced pressure , the solid was washed with petroleum ether, and suction filtered to obtain 7.5g of solid, which was 4-chloro-α-bromoacetophenone; in a 1L reaction vessel, 6g of 4-chloro-α-bromoacetophenone and 50ml Solvent chloroform, stirred and dissolved, added 5g urotropine, reacted at room temp...
Embodiment 22
[0059] The preparation of embodiment 22-oxazolidinone
[0060] Add 50g of ethanolamine, 75g of dimethyl carbonate and 2.5g of zinc acetate into the stirring reflux reaction device, heat up to 80 degrees for reflux reaction for 4 hours, then remove the solvent, and recrystallize with absolute ethanol to obtain 50g of the product 2-oxazolidine ketone.
[0061] product of 1 HNMR analysis
[0062] 1 HNMR (CDCl 3 )
[0063] δ: 6.32(br, -NH), 4.46(t, J=7.2Hz, 2H, -CH 2 O), 3.65(t, J=7.2Hz, 2H, -CH 2 NH).
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