Novel polyester and application thereof
A polyester, a new type of technology, applied in the chemical field, can solve the problems of poor scratch resistance, poor yellowing resistance, poor handling adhesion, etc., and achieve the effect of improving yellowing resistance and simple process
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Embodiment 1
[0024] In the reactor, add 5 parts (parts by mass, the same below) of pentaerythritol, 15 parts of trimethylolpropane, 4 parts of propylene glycol, 4 parts of maleic anhydride, 14 parts of isononanoic acid, 21 parts of hexahydrophthalic anhydride, feed nitrogen and heat up to Stirring was started at 150°C, and then the temperature was raised to 230°C in steps of 10°C per hour. During the heating process, the gas phase temperature was controlled below 100°C, and the constant temperature was kept at 230°C until the sampling liquid level was transparent. After 30 minutes, slowly added 2 parts of xylene to control The reflux temperature is 225-230°C. After reflux for two hours, take a sample and test it. After passing the test, add 35 parts of xylene after cooling.
Embodiment 2
[0026] In the reactor, add 6 parts (parts by mass, the same below) of pentaerythritol, 14 parts of trimethylolpropane, 5 parts of propylene glycol, 5 parts of maleic anhydride, 13 parts of isononanoic acid, 19 parts of hexahydrophthalic anhydride, feed nitrogen and heat up to Stirring was started at 150°C, and then the temperature was raised to 230°C in steps of 10°C per hour. During the heating process, the gas phase temperature was controlled below 100°C, and the constant temperature was kept at 230°C until the sampling liquid level was transparent. After 30 minutes, slowly added 2 parts of xylene to control The reflux temperature is 225-230°C. After reflux for two hours, take a sample and test it. After passing the test, add 36 parts of xylene after cooling.
[0027] In the present invention, two different polyesters can be prepared respectively through the above two examples, and compared with other three polyesters on the market as the raw materials of the paint compositio...
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