Positive-type photosensitive resin composition, photosensitive resin film produced using same, and display device
A technology of photosensitive resin and composition, applied in the direction of photosensitive materials, optics, and optomechanical equipment for optomechanical equipment, can solve problems such as pattern decay of organic light-emitting diodes, and achieve the effect of excellent heat resistance and chemical resistance
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Embodiment 1
[0215] [Synthesis Example 1] Synthesis of Polybenzoxazole Precursor (PA-1)
[0216] 17.4 g of 2,2-bis(3-amino-4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane and 0.86 g of 1,3-bis(aminopropyl) Tetramethyldisiloxane is placed in a four-necked flask equipped with a stirrer, a temperature regulator, a nitrogen injector and a cooler, while nitrogen is passed through the flask, and 280 g of N-methyl-2-pyrrolidone is added thereto (NMP) to dissolve the mixture. Here, the solution obtained included a solids content of 9% by weight.
[0217] When the solid was completely dissolved in the solution, 9.9 g of pyridine was added thereto, and slowly added thereto by dissolving 13.3 g of 4,4'-oxodibenzoyl chloride in 142 g of N-methyl - The obtained solution in 2-pyrrolidone (NMP) while keeping the mixture at 0°C to 5°C. After the addition in a dropwise manner, the reaction was performed at 0 to 5° C. for one hour and then the reaction was further performed for one hour after raising its ...
Embodiment 2
[0219] [Synthesis Example 2] Synthesis of Polybenzoxazole Precursor (PA-2)
[0220] A polybenzoxazole precursor (PA-2) was prepared according to the same method as in Synthesis Example 1 except that maleic anhydride was used instead of 5-norbornene-2,3-dicarboxylic anhydride.
Embodiment 3
[0221] [Synthesis Example 3] Synthesis of Polybenzoxazole Precursor (PA-3)
[0222] A polybenzoxazole precursor (PA-3) was prepared according to the same method as in Synthesis Example 1 except that aconitic anhydride was used instead of 5-norbornene-2,3-dicarboxylic anhydride.
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