Low thermal conductivity membrane and producing method thereof and membrane distillation apparatus
A technology of thin film distillation and low thermal conductivity, which is applied in evaporation, separation methods, rayon manufacturing, etc., can solve the problems of flux attenuation, low film flux, increased equipment investment cost and energy consumption, and reduce temperature polarization , Improve the effect of characteristic heat preservation value
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[0036] In the preparation of modifying the mesoporous particle to make it hydrophobic, the hydrophobic group can be grafted to the surface of the mesoporous particle and the inner surface of the hole by copolymerization or grafting, wherein the hydrophobic group can be C 1 -C 10 Alkyl, vinyl, propenyl, or phenyl.
[0037] The preparation method of the copolymerization method includes: dispersing a precursor with a hydrophobic group in a solution containing a surfactant to carry out a self-assembly reaction, wherein the precursors can be of multiple types, but at least one of the precursors has a hydrophobic group; and removing the surfactant to obtain modified mesoporous particles grafted with the hydrophobic group on the surface and inner surface of the hole.
[0038] For example, the functionalization of mesoporous particles and the introduction of hydrophobic functional groups such as vinyl groups can be carried out by copolymerization chemical reactions, such as tetraetho...
Embodiment 1
[0062] will end with -CH 2 =CH 2 Multiple mesoporous particles modified by chemical functional groups were introduced into the electrospinning solution prepared with polyvinyldifluoride-hexafluoropropylene (PVDF-co-HFP) as raw material and dimethylformamide (Dimethylformamide, DMF) as solvent , adding 1 wt% of modified mesoporous particles, and then preparing a low thermal conductivity film by electrospinning technology.
Embodiment 2 to 4
[0064] Examples 2 to 4 are based on the steps of Example 1, respectively adding 10wt%, 20wt%, and 50wt% of modified mesoporous particles, and then preparing a low thermal conductivity film by electrospinning technology.
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