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Microextraction Dyeing Method of Reactive Dyes

A technology of reactive dyes and dyeing methods, applied in dyeing methods, textiles and papermaking, etc., can solve the problems of lack of good solubility, poor dyeing effect, unfavorable dye recovery, etc., and achieve high dye concentration gradient and high color yield , the effect of saving water

Inactive Publication Date: 2017-03-08
SOUTHWEST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage of this method is that carbon dioxide is a non-polar molecule, and it has no good solubility for conventional reactive dyes with water as the medium; it is mainly suitable for dyeing hydrophobic fibers such as polyester, but for hydrophilic fibers such as cotton, the dyeing effect is not good. it is good
This method requires less water, but requires more surfactant to build the capsule wall of the droplet, which is not conducive to the recovery of the dye, and also increases the difficulty of dyeing the dye into the fabric.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The detailed steps of the microextraction dyeing method of reactive dyes are as follows:

[0026] (1) Dissolve 10 g of reactive red X-3B in 100 mL of acetone, add 2 mL of oleic acid, and obtain a transparent solution under ultrasound.

[0027] (2) Suction filtration of the above transparent solution under reduced pressure to obtain reactive red X-3B powder coated with oleic acid.

[0028] (3) Add the reactive red X-3B powder coated with oleic acid into 200 mL of isooctane, and disperse it ultrasonically to obtain a concentrated transparent dye solution.

[0029] (4) Take 0.1 mL of the concentrated transparent dye solution prepared in step (3) and dilute it into 20 mL of isooctane to obtain a dye solution.

[0030] (5) Put the cotton fabric (100% pass rate) that has been soaked with sodium carbonate (10g / L) solution into the dye liquor prepared in step (4), vibrate and heat to 40°C for dyeing for 30min, then heat to Fix the color at 60°C for 10 minutes.

Embodiment 2

[0032] The detailed steps of the microextraction dyeing method of reactive dyes are as follows:

[0033] (1) Dissolve 8 g of Reactive Yellow K-4G in 100 mL of acetone, add 3 mL of oleic acid, and obtain a transparent solution under ultrasound.

[0034] (2) Suction filtration of the above transparent solution under reduced pressure to obtain active bright yellow K-4G powder coated with oleic acid.

[0035] (3) Add the active bright yellow K-4G powder coated with oleic acid into 200mL isooctane, and disperse it ultrasonically to obtain a concentrated transparent dye solution.

[0036] (4) Take 0.4 mL of the transparent dye concentrated solution prepared in step (3) and dilute it into 20 mL of isooctane to obtain a dye solution.

[0037] (5) Put the cotton fabric (100% pass rate) that has been soaked with sodium carbonate (10g / L) solution into the dye liquor prepared in step (4), vibrate and heat to 40°C for dyeing for 30min, then heat to Fix the color at 100°C for 10 minutes. ...

Embodiment 3

[0039] The detailed steps of the microextraction dyeing method of reactive dyes are as follows:

[0040] (1) Dissolve 15 g of Active Turquoise Blue KN-G in 100 mL of acetone, add 4 mL of oleic acid, and obtain a transparent solution under ultrasound.

[0041] (2) Suction filtration of the above transparent solution under reduced pressure to obtain active turquoise blue KN-G powder coated with oleic acid.

[0042] (3) Add the reactive turquoise blue KN-G powder coated with oleic acid into 200mL of isooctane, and disperse it ultrasonically to obtain a concentrated transparent dye solution.

[0043] (4) Take 0.5 mL of the concentrated transparent dye solution prepared in step (3) and dilute it into 20 mL of isooctane to obtain a dye solution.

[0044] (5) Put the cotton fabric (100% pass rate) that has been soaked with sodium bicarbonate (15g / L) solution into the dye liquor prepared in step 4, vibrate and heat to 40°C for dyeing for 30min, then heat to 80°C ℃ color fixation 10m...

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PUM

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Abstract

The invention provides a reactive dye micro-extraction dyeing method. The method comprises the following steps of dissolving reactive dye extract in acetone, adding oleic acid into the solution, carrying out ultrasonic treatment to obtain a transparent solution, carrying out reduced pressure pumping filtration on the solution to obtain oleic acid-coated reactive dye powder, adding the oleic acid-coated reactive dye powder into isooctane, carrying out ultrasonic dispersion, diluting the prepared dye concentrated solution by isooctane, putting a cotton fabric padded with an alkali agent-containing solution into the dye solution, carrying out oscillation heating dyeing and carrying out heating dye fixation. The reactive dye is dissolved in the oil phase so that a water use amount is reduced and is 2-5% the common water use amount and thus water saving is promoted. The reactive dye is extracted by a water phase on the surface of the fabric and a small amount of the reactive dye is hydrolyzed because of a small amount of water. The extracted dye on the surface of the fabric has a high concentration, a high dye concentration gradient is formed, and a color yield of the fabric is high so that salt-addition dyeing accelerating is not needed.

Description

technical field [0001] The invention relates to a dyeing method, in particular to a micro-extraction dyeing method of reactive dyes. Background technique [0002] Reactive dyes used for textile dyeing are water-soluble, and the existing dyeing technology is to dissolve reactive dyes in aqueous solution, and then directly dye textiles. Although water has many advantages as a cheap dyeing medium, such as dissolving dyes and swelling fibers, reactive dyes are easily hydrolyzed in aqueous solution, resulting in waste, and dyeing requires a large amount of water, which not only pollutes water sources but also brings many ecological problems. According to the estimates of relevant research institutes, in the traditional dyeing process, about 30-50 tons of water are consumed for every ton of fiber dyed. The daily wastewater discharge of my country's textile printing and dyeing industry is 3×10 7 ~5×10 7 cubic meters, up to 2 billion cubic meters per year. Recently, supercritica...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P1/38D06P1/653D06P1/92D06P3/66
Inventor 刘一萍卢明李兰倩刘祖兰赵振云刘想
Owner SOUTHWEST UNIV