Novel dendritic macromolecule and its preparation method and use
A dendritic and macromolecular technology, applied in sexual diseases, drug combinations, etc., can solve the problems of inefficiency, tedious operation, time-consuming and labor-intensive consumables, etc., and achieve the improvement of egg fertilization rate, increase egg fertilization rate, and great social significance. and scientifically meaningful effects
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Embodiment 1
[0049] 1) The dendrimer polyamide-amine G3 (commercially available) with S-S as the core was catalyzed by sodium bisulfite (commercially available) at 20 degrees Celsius for 24 hours in dichloromethane and methanol (1:1) solution Reductive decomposition into half dendrimer G with SH bond activity 3 ;
[0050]
[0051] revert to
[0052]
[0053] 2) 1 mole of the branched compound Linker (commercially available or prepared) is mixed with 1 mole of polyethylene with a carboxyl group at one end and a methoxy group at the other end at a pH of 7.5 and at room temperature. Diol (commercially available) was reacted for 20 hours to generate compound B with a branched structure through reaction coupling, which was then lyophilized for use;
[0054]
[0055] +
[0056]
[0057]
[0058]
[0059] n is approximately equal to 100.
[0060] 3) One mole of compound B and two moles of compound A were reacted overnight in a solution of N,N'-dicyclohexylcarbodiimide and ch...
Embodiment 2
[0068] 1) Reductively decompose the S-S-centered dendrimer polyamide-amine G2 (commercially available) in dimethyl sulfoxide solution under the catalysis of vitamin C (commercially available) at 15 degrees Celsius for 24 hours to form SH Healthy active half dendrimer G2;
[0069]
[0070] reduction
[0071]
[0072] 2) 1 mole of the branched compound LinkerA (commercially available and can also be prepared) is catalyzed by N,N-dimethylformamide and trifluoroacetic acid by adding acetic anhydride to generate LinkerB (commercially available), and then LinkerB is in Under the condition of pH 6.5, react with 1 mole of polyethylene glycol (commercially available) with an amino group at one end and a methoxy group at the other end at room temperature for 24 hours for reaction coupling to generate compound B with a branched structure, Then freeze-dry for later use;
[0073] (linkerA)
[0074] TFA; anhydr; DMF
[0075] (linkerB)
[0076]
[0077] +
[0078]
...
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