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Heavy metal poly-hole adsorption material and preparation method thereof

A pore adsorption and heavy metal technology, applied in the field of environment and materials, can solve the problems of solid waste pollution of eggshells, tailings pollution, etc., and achieve the effects of low price, low production cost, and reduced production cost.

Active Publication Date: 2015-12-09
FUJIAN XINSEN CARBON
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The object of the present invention is to provide a kind of method that utilizes lead-zinc tailings, water glass, clay, activated carbon and egg shell to prepare heavy metal polyporous adsorption material, the heavy metal polyporous adsorption material that makes can effectively adsorb heavy metal ions in sewage, It plays the role of environmental protection, and can effectively solve the pollution of tailings and poultry eggshell solid waste, and realize the reuse of waste

Method used

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  • Heavy metal poly-hole adsorption material and preparation method thereof
  • Heavy metal poly-hole adsorption material and preparation method thereof
  • Heavy metal poly-hole adsorption material and preparation method thereof

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preparation example Construction

[0025] The specific steps of the preparation method of the heavy metal polyporous adsorption material prepared by utilizing lead-zinc tailings, water glass, clay, activated carbon and egg shells are as follows:

[0026] 1) Put the lead-zinc tailings in a drying oven at 60°C for 3 hours at a constant temperature, grind and pulverize them and pass them through a 100-mesh sieve, and grind and pulverize the activated carbon through a 40-mesh sieve.

[0027] 2) Weigh the pretreated lead-zinc tailings, activated carbon, and clay respectively according to the formula, and add them into a ball mill for mixing. Add a corresponding amount of water glass and water, extrude and cut in an extrusion molding machine, and then granulate in a disc granulator to obtain raw pellets with a particle size of about 5-8mm.

[0028] 3) Dry the formed raw balls at 70°C for 12h, put them into a high-temperature box furnace, and sinter at 1120°C for 1h to obtain lightweight ceramsite.

[0029] 4) Soak l...

Embodiment 1

[0031] The weight ratio of the raw material formula is: 50wt% of lead-zinc tailings, 20wt% of water glass, 20wt% of clay, and 10wt% of activated carbon.

[0032] The specific steps are:

[0033] 1) Put the lead-zinc tailings in a drying oven at 60°C for 3 hours at a constant temperature, grind and pulverize them and pass them through a 100-mesh sieve, and grind and pulverize the activated carbon through a 40-mesh sieve.

[0034] 2) Weigh the pretreated lead-zinc tailings, activated carbon, and clay respectively according to the formula, and add them into a ball mill for mixing. Add a corresponding amount of water glass and water, extrude and cut in an extrusion molding machine, and then granulate in a disc granulator to obtain raw pellets with a particle size of about 5-8mm.

[0035] 3) Dry the formed raw balls at 70°C for 12h, put them into a high-temperature box furnace, and sinter at 1120°C for 1h to obtain lightweight ceramsite.

[0036] 4) Soak light ceramsite in phosph...

Embodiment 2

[0041] The weight ratio of the raw material formula is: 60wt% of lead-zinc tailings, 20wt% of water glass, 15wt% of clay, and 5wt% of activated carbon.

[0042] The specific steps are:

[0043] 1) Put the lead-zinc tailings in a drying oven at 60°C for 3 hours at a constant temperature, grind and pulverize them and pass them through a 100-mesh sieve, and grind and pulverize the activated carbon through a 40-mesh sieve.

[0044] 2) Weigh the pretreated lead-zinc tailings, activated carbon, and clay respectively according to the formula, and add them into a ball mill for mixing. Add a corresponding amount of water glass and water, extrude and cut in an extrusion molding machine, and then granulate in a disc granulator to obtain raw pellets with a particle size of about 5-8mm.

[0045] 3) Dry the formed raw balls at 70°C for 12h, put them into a high-temperature box furnace, and sinter at 1120°C for 1h to obtain lightweight ceramsite.

[0046] 4) Soak light ceramsite in phospho...

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Abstract

The invention discloses a heavy metal poly-hole adsorption material and a preparation method thereof. Lead-zinc tailings, water glass, clay and activated carbon are used as haydite materials, egg shells are used as calcium sources, so as to extract a calcium containing solution, and haydite is modified by combining a phosphoric acid solution, so as to prepare the heavy metal poly-hole adsorption material. According to the heavy metal poly-hole adsorption material, the lead-zinc tailings as main raw materials are tailings after beneficiation of lead-zinc ores, calcium is from solid waste generated during processing of agricultural products, so that waste utilization is realized, the heavy metal poly-hole adsorption material has persistent effective adsorption capacity on heavy metal ions in sewage, so that the purpose of using waste to control pollution is achieved, the cost of the raw materials is reduced, the problem of local tailings can be solved to a certain degree, and the heavy metal poly-hole adsorption material has good environmental, economic and social benefits.

Description

technical field [0001] The invention belongs to the field of environment and materials, and in particular relates to a method for preparing a heavy metal polypore adsorption material by using lead-zinc tailings, water glass, clay, activated carbon and egg shells. Background technique [0002] With the development of our country's economy, the problem of water pollution has become increasingly serious. Manufacturing, mining, metallurgy, chemical industry and other industries have produced a large amount of industrial wastewater containing heavy metal ions, which has caused great damage to the environment. The adsorption method has stable and reliable characteristics, and is currently the most promising wastewater purification method. In order to control the problem of heavy metal pollution in water, a simple and effective heavy metal adsorption material is needed. [0003] Lead-zinc tailings are powdery or fine sandy waste residues discharged from lead-zinc mines after flota...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/30C02F1/28
Inventor 于岩张复伟张海峰凌华金
Owner FUJIAN XINSEN CARBON