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Nano titanium dioxide modified through liquid silicon deposition

A nano-titanium dioxide, liquid-phase silicon deposition technology, applied in chemical instruments and methods, inorganic pigment treatment, fibrous fillers, etc., can solve the problem of easy agglomeration of nano-titanium dioxide, reduce surface energy, facilitate industrial production, and low raw material prices Effect

Active Publication Date: 2015-12-09
苏州远略知识产权运营有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a liquid-phase silicon deposition modified nano-titanium dioxide for the problem that nano-titanium dioxide is easy to agglomerate in the prior art, and the nano-titanium dioxide has better dispersibility and stability

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] 1) Dissolve 5g of methyl silicone oil with a mass fraction of 15% in 15mL of n-hexane solvent, then add 2.5g of nano-titanium dioxide and stir evenly to obtain a mixed solution;

[0015] 2) Evaporate the mixed solution prepared in step 1) to dryness at a water bath temperature of 75°C, put it in an oven for drying, and then place it in a muffle furnace under oxygen-enriched conditions at a rate of 10°C / min Raise the temperature to 500° C. and keep it for 2 hours to convert the methyl silicone oil into silicon dioxide, that is, to obtain nano-titanium dioxide modified by silicon deposition on the surface.

Embodiment 2

[0017] 1) Dissolve 5g of methyl silicone oil with a mass fraction of 20% in 15mL of n-hexane solvent, then add 4g of nano-titanium dioxide, and stir evenly to obtain a mixed solution;

[0018] 2) Evaporate the mixed solution prepared in step 1) to dryness at a water bath temperature of 75°C, put it in an oven for drying, and then place it in a muffle furnace under oxygen-enriched conditions at a rate of 10°C / min Raise the temperature to 500° C. and keep it for 2 hours to convert the methyl silicone oil into silicon dioxide, that is, to obtain nano-titanium dioxide modified by silicon deposition on the surface.

Embodiment 3

[0020] 1) Dissolve 5g of methyl silicone oil with a mass fraction of 30% in 15mL of n-hexane solvent, then add 5g of nano-titanium dioxide, and stir evenly to obtain a mixed solution;

[0021] 2) Evaporate the mixed solution prepared in step 1) to dryness at a water bath temperature of 75°C, put it in an oven for drying, and then place it in a muffle furnace under oxygen-enriched conditions at a rate of 10°C / min Raise the temperature to 500° C. and keep it for 2 hours to convert the methyl silicone oil into silicon dioxide, that is, to obtain nano-titanium dioxide modified by silicon deposition on the surface.

[0022] Each raw material that the present invention adopts:

[0023] raw material name Specification Manufacturer Nano Titanium Dioxide Average particle size: 25nm self made Methicone Quality score: 15-30% Sinopharm Chemical Reagent Co., Ltd. n-Hexane Reagent grade Sinopharm Chemical Reagent Co., Ltd.

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PUM

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Abstract

The invention relates to nano titanium dioxide modified through liquid silicon deposition and belongs to the technical field of powder materials. In the invention, silicon dioxide is deposited on surface of nano titanium dioxide, wherein the silicon dioxide accounts for 18-30% by mass of the nano titanium dioxide. The nano titanium dioxide modified through liquid silicon deposition is advantaged in that: (1) silicon deposition modification is carried out on surface of the nano titanium dioxide, so that the surface energy of the nano titanium dioxide is greatly reduced, thereby improving dispersibility and stability of nano titanium dioxide; (2) the nano titanium dioxide is low in raw material cost, is simple in process, is beneficial to industrial production, and is quite suitable for the fields of cosmetics, nano functional textiles, functional plastics and coatings and the like.

Description

technical field [0001] The invention relates to nano-titanium dioxide modified by liquid-phase silicon deposition, which belongs to the technical field of powder materials. Background technique [0002] Nano-titanium dioxide is widely used in pigments, rubber, plastics, paper and other industries due to its good UV resistance, weather resistance, chemical corrosion resistance, heat resistance, photocatalysis, and thermal stability. Catalysts, photovoltaic cells, ultraviolet shielding agents, etc. are widely used. Nano-titanium dioxide without surface treatment has a high surface energy and contains polar hydroxyl groups on the surface. Therefore, nano-titanium dioxide is prone to agglomeration due to polar adsorption or moisture absorption. [0003] When nano-titanium dioxide without surface modification is added as an additive to high molecular polymers to prepare composite materials, there is a technical problem of uneven dispersion, which makes the comprehensive performa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09C1/36C09C3/06
Inventor 左士祥张宇
Owner 苏州远略知识产权运营有限公司