A kind of positive electrode material of lithium battery and preparation method thereof
A positive electrode material and lithium battery technology, applied in the direction of battery electrodes, polycrystalline material growth, chemical instruments and methods, etc., can solve the problems of slight fatigue, and achieve simple preparation methods, high initial charge-discharge specific capacity, and easy access Effect
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[0030] A method for preparing a cathode material for a lithium battery, comprising the steps of:
[0031] (1) Synthesis of active materials: Weigh 0.2000 g of ammonium metavanadate, 0.7000 g of boric acid, 0.8000 g of lithium chloride, 0.1000 g of cobalt acetate, and 0.3000 g of oxalic acid, and place them in a 25.00 ml high-pressure tank lined with polytetrafluoroethylene. Into the reaction kettle, add 10.00 ml of distilled water, mix well, stir with magnetic force for 30 minutes, and adjust the pH value to 8.20 with ethylenediamine. Finally, the reaction kettle was placed at 160° C. for 120 hours at a constant temperature, and then allowed to cool down to room temperature naturally. Suction filtration obtained a brown octahedral single crystal compound (yield is about 70% based on vanadium calculation). Although the chemical composition of cobalt acetate has not been reflected in the final results of the experiment, the results of many experiments have shown that the compou...
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