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Biological degrading agent for degrading cyanide and preparing method and application of biological degrading agent

A technology of biodegradation agent and cyanide, applied in the direction of using microorganisms, methods based on microorganisms, biochemical equipment and methods, etc., can solve the problems of destroying soil structure and biological communities, and achieve the effect of strong adsorption capacity

Inactive Publication Date: 2015-12-23
POTEN ENVIRONMENT GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The embodiment of the invention discloses a biodegradation agent for degrading cyanide, its preparation method and application, which are used to solve the problem of destroying soil structure and biological community in repairing cyanide-contaminated soil by chemical means

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Take 200g of peanut shells in a 500mL beaker, add 200ml of 10% ferric nitrate aqueous solution, soak for 12h, after the solution is completely blotted, place the obtained solid in a tube furnace, protect it with nitrogen, and calcinate at 450°C for 3h, after cooling Wash with 15% and 3% ammonium nitrate aqueous solutions in turn, then wash with deionized water for 3 times, dry at 105°C, pulverize, pass through a 120-mesh sieve, and sterilize with ozone for 10 minutes to obtain an activated carrier.

[0041] Take high-efficiency microbial flora B3501g and inoculate it in 100ml liquid medium. The formula of liquid medium is: KH 2 PO 4 0.5g / L, K 2 HPO 4 0.5g / L, MgSO 4 ·7H 2 O0.2g / L, CaCl 2 0.1g / L, NaCl0.2g / L, MnSO 4 ·H 2 O0.01g / L, FeCl 2 0.01g / L, NH 4 Cl1.0g / L; add potassium cyanide to make CN - The concentration is 2.0mg / L, and cultured in a shaker at 37°C for 3 days. After mycelium grows in the medium, 10ml of medium is supplemented every 3 days, and potassium ...

Embodiment 2

[0045] Take 100g of coconut peat into a 500mL beaker, add 150ml of 12% ferric phosphate aqueous solution, soak for 18h, after the solution is completely blotted, put the obtained solid in a tube furnace, protect it with nitrogen, calcinate at 400°C for 4h, cool After that, it was washed once with 20% and 4% ammonium phosphate aqueous solution successively, and then washed three times with deionized water, dried at 110°C, pulverized, passed through a 120-mesh sieve, and sterilized by ozone for 10 minutes to obtain an activated carrier.

[0046] Take high-efficiency microbial flora B3501g and inoculate it in 75ml liquid medium, the formula of liquid medium is: KH 2 PO 4 0.7g / L, K 2 HPO 4 0.7g / L, MgSO 4 ·7H 2 O0.1g / L, CaCl 2 0.2g / L, NaCl0.15g / L, MnSO 4 ·H 2 O0.03g / L, FeCl 2 0.02g / L, NH 4 Cl1.2g / L; add potassium cyanide to make CN - The concentration is 1.0mg / L, and cultured in a shaker at 35°C for 2 days. After mycelium grows in the medium, 15ml of medium is supplemente...

Embodiment 3

[0050] Take 500g of corn cobs in a 1000mL beaker, add 500ml of 8% magnesium nitrate aqueous solution, soak for 15h, after the solution is completely blotted, place the obtained solid in a tube furnace, protect it with nitrogen, and calcinate at 380°C for 4.5h. After cooling, it was washed once with 17% and 5% sodium nitrate aqueous solution, and then washed five times with deionized water, dried at 105°C, pulverized, passed through a 120-mesh sieve, and sterilized by ozone for 10 minutes to obtain an activated carrier.

[0051] Take 10g of high-efficiency microbial flora B350 and inoculate it in 1000ml liquid medium, the formula of liquid medium is: KH 2 PO 4 0.65g / L, K 2 HPO 4 0.65g / L, MgSO 4 ·7H 2 O0.2g / L, CaCl 2 0.15g / L, NaCl0.15g / L, MnSO 4 ·H 2 O0.01g / L, FeCl 2 0.02g / L, NH 4 Cl1.3g / L; add potassium cyanide to make CN - The concentration is 2.0mg / L, and cultured in a shaker at 37°C for 4 days. After mycelium grows in the medium, 300ml of medium is supplemented eve...

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PUM

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Abstract

The embodiment of the invention discloses a biological degrading agent for degrading cyanide and a preparing method and application of the biological degrading agent. The preparing method comprises the steps that waste biomass is used for preparing an activation carrier; an efficient microbial flora is used for culturing hyphae, and an active cyanide degrading bacterium solution is further prepared through the processes of culturing, centrifuging and dispersing; the activation carrier is steeped into the active cyanide degrading bacterium solution, and the biological degrading agent is obtained through the processes of culturing, filtering and washing. Compared with a chemical restoring method in the prior art, in the method, no acid-base agent or oxidizing agent is used, a biological degrading mode is adopted, and damage to the soil structure and the biocenosis can be avoided.

Description

technical field [0001] The invention relates to the field of cyanide treatment, in particular to a biodegradation agent for degrading cyanide, its preparation method and application. Background technique [0002] Cyanide, such as potassium cyanide or sodium cyanide, is widely used in the fields of metallurgy, electroplating, manufacturing, and coking because of its excellent complexing properties. At the same time, more and more cyanide enters the soil and accumulates in the soil. Because cyanide has a strong ability to combine with iron, it can destroy the iron-containing molecules (such as P450, etc.) in the enzyme system in the organism, so it is extremely toxic to various organisms including humans. Therefore, soil cyanide pollution is receiving more and more attention. Cyanide exists in two ways in soil: one exists in a stable complex state, which has low toxicity and less risk; the other exists in an unstable complex state or free state, called easily released cyanide...

Claims

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Application Information

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IPC IPC(8): C12N11/14C12N1/36C12N1/20C12N1/14B09C1/10C12R1/38C12R1/80
Inventor 乔瑞平李海涛蒋玮张伦梁
Owner POTEN ENVIRONMENT GRP