Preparation method of field ion emitter
A field ion emission and emitter technology is applied in the field of field ion emitter preparation to achieve the effects of improving overall performance, reducing size, and reducing the difficulty of preparation
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[0024] The basis of the preparation method of the present invention is to firstly obtain a carbon nanotube array sample. The preparation of the carbon nanotube array sample is a mature process at present, so it will not be described in detail here. The carbon nanotube array sample prepared by CVD method can be grown on silicon or metal substrate, and its morphology before preparation can be found in figure 2 .
[0025] The method of the present invention is to coat a layer of low melting point metal indium (In) or gallium (Ga) on the surface of the carbon nanotube array by thermal evaporation or electron beam evaporation or magnetron sputtering, as Field emission emitters.
Embodiment 1
[0026] Embodiment one takes In as the coating material of field emitter
[0027] Put the known carbon nanotube array into the vacuum chamber 2.1, the pressure of the vacuum chamber 2.1 is 1×10 -3 Pa to 1×10 -1 Pa, put the In metal source 2.2 on the heating device 2.3. Vacuumize, and under vacuum conditions, heat the In metal source 2.2 to vaporize it, and evaporate it to the carbon nanotube array to form the coated carbon nanotube array 3, on which the metal layer 3.1 is coated. Use a quartz crystal oscillator balance to measure the coating rate of the In source. By controlling the heating temperature, adjust the coating rate to 0.2nm / s until the thickness reaches 100nm. The radius of curvature of the tip of the carbon nanotube in the carbon nanotube array is basically the same as the diameter of the carbon nanotube. , is about 20nm. The morphology of carbon nanotubes coated with In is as follows: image 3 As shown, the specific preparation process can be found in Figu...
Embodiment 2
[0028] Embodiment two takes Ga as the coating material of field emitter
[0029] Put the known carbon nanotube array into the vacuum chamber 2.1, the pressure of the vacuum chamber 2.1 is 1×10 -3 Pa to 1×10 -1 Pa, put the Ga metal source 2.2 on the heating device 2.3. Vacuumize, and under vacuum conditions, heat the Ga metal source 2.2 to vaporize it, evaporate it to the carbon nanotube array, and form the coated carbon nanotube array 3, on which the metal layer 3.1 is coated. Use a quartz crystal oscillator balance to measure the coating rate of the In source. By controlling the heating temperature, adjust the coating rate to 0.2nm / s until the thickness reaches 100nm. The radius of curvature of the tip of the carbon nanotube in the carbon nanotube array is basically the same as the diameter of the carbon nanotube. , is about 50nm. The morphology of carbon nanotubes after Ga plating is as follows: Figure 4 As shown, the specific preparation process can be found in Fig...
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