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Two-component polyurethane adhesive for electronic potting and preparation method thereof

A two-component polyurethane and adhesive technology, applied in the field of polyurethane, to achieve the effect of low viscosity and good flexibility

Inactive Publication Date: 2016-10-26
WUXI WANLI ADHESION MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a two-component low-viscosity flame-retardant polyurethane potting adhesive and its preparation method for the defects of existing common adhesives

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Preparation of component A: Add 20g of castor oil, 180g of polyether polyol PPG4000, and 0.2g of defoamer MOK6021 into the reaction kettle, heat to 90-110°C, vacuum dehydrate for 1 hour, then cool down to 60°C and add MDI- 50 205g, react under nitrogen protection for 3 hours, cool down to normal temperature, add 200g of flame retardant tricresyl phosphate, and seal the package.

[0021] Preparation of component B: Add 100g of polyether polyol PPG 1000, 40g of polyether polyol PEG800, 5g of crosslinking agent TMP, 0.5g of catalyst T-12, and 30g of plasticizer Eastman 168 into the reactor, and heat to 80°C , dehydrated in vacuum for 3 hours, then cooled down to room temperature under nitrogen protection, and sealed and packaged.

[0022] Mix component A and component B uniformly at a weight ratio of 1:1, and place it at 60°C for 1 hour to obtain the finished product.

[0023] When in use, the uniformly mixed glue is poured into the dry electronic components, and then pla...

Embodiment 2

[0025] Preparation of component A: Add 50 g of castor oil, 150 g of trifunctional polyether polyol polyoxypropylene triol, and 0.4 g of defoamer MOK6021 into the reaction kettle, heat to 90-110 °C, and vacuum dehydrate for 1 hour. After cooling down to 60°C, add 225g of MDI, react under nitrogen protection for 3 hours, cool down to normal temperature, add 200g of flame retardant tributyl phosphate, and seal the package.

[0026] Preparation of component B: Add 120g of polyether polyol PPG 2000, 20g of polyether polyol PEG400, 7g of crosslinking agent TMP, 1g of catalyst T-9, and 35g of plasticizer Benzoflex 9-88 into the reaction kettle, heat to 80 ℃, vacuum dehydration for 3 hours, and then cooled down to room temperature under the protection of nitrogen, and sealed and packaged.

[0027] Mix component A and component B uniformly at a weight ratio of 1:1, and place it at 60°C for 1 hour to obtain the finished product.

[0028] When in use, the uniformly mixed glue is poured ...

Embodiment 3

[0030] Preparation of component A: Add 80g of castor oil, 120g of polyether polyol PPG1000, and 0.5g of defoamer MOK6021 into the reaction kettle, heat to 90-110°C, vacuum dehydrate for 1 hour, then cool down to 60°C and add MDI- 50 275g, react under nitrogen protection for 3 hours, cool down to normal temperature, add 222g of flame retardant tricumyl phosphate, and seal the package.

[0031] Preparation of component B: Add polyether polyol PPG 2000 80g, polyether polyol PEG2000 120g, crosslinking agent 1,4-butanediol 10g, catalyst T-12 0.3g, plasticizer Eastman 168 80g to the reaction In the kettle, heat to 80°C, vacuum dehydrate for 3 hours, then cool down to normal temperature under the protection of nitrogen, and seal the package.

[0032] Mix component A and component B uniformly at a weight ratio of 1:1, and place it at 60°C for 1 hour to obtain the finished product.

[0033] When in use, the uniformly mixed glue is poured into the dry electronic components, and then pl...

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PUM

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Abstract

The invention discloses a two-component polyurethane adhesive for electronic potting and a preparation method thereof, belongs to the technical field of polyurethane, and particularly relates to the preparation method of the two-component polyurethane adhesive for electronic potting. The two-component polyurethane adhesive is formed by mixing a component A and a component B with an equal mass ratio and then curing at room temperature or thermally curing; the component A contains a prepolymer obtained from isocyanate and polyol, a halogen-free flame retardant, free isocyanate and a defoaming agent; the component B contains polyol with polyfunctionality, a catalyst, an environmentally friendly plasticizer, a crosslinking agent, a defoaming agent, and polyether polyol with difunctionality. The adhesive for electronic potting has low viscosity, is suitable for assembly line production, has the advantages of environmental friendliness, transparency, good flexibility, water insulation, damp prevention, and no bubbles, and is especially suitable for electronic potting.

Description

technical field [0001] The invention belongs to the technical field of polyurethane, and in particular relates to a preparation method of a two-component polyurethane adhesive for electronic potting. Background technique [0002] Polyurethane potting adhesives are widely used in the field of electronic potting. The required properties are: waterproof, moisture-proof, corrosion-proof, dust-proof, shock-proof, transparent and easy to rework and repair, etc. It has a high dielectric constant and stabilizes the performance parameters of electronic components. Improve the service life of the overall circuit, prevent electronic components from burning due to damage, can withstand long-term repeated cold and heat cycles, and have certain heat-generating mechanical properties. [0003] The performance of electronic components is getting higher and higher, the volume is getting smaller and smaller, and the calorific value is also reduced. Most polyurethane potting adhesives contain n...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/08C09J11/06C08G18/66C08G18/48C08G18/36
CPCC08G18/36C08G18/4812C08G18/4825C08G18/4829C08G18/4833C08G18/6696C08K5/521C08K5/523C09J11/06C09J175/08
Inventor 蔡海元
Owner WUXI WANLI ADHESION MATERIALS