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Method for preparing anti-fouling and bactericidal high-quality tile gap filler

A bactericidal, high-quality technology, applied in the field of ceramic tile grout preparation, can solve the problems of easy accumulation of dust and dirt, prone to pan-alkali phenomenon, poor stain resistance, etc. The effect of poor contamination and strong sterilization performance

Active Publication Date: 2016-11-30
佛山市卓仕高新型材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The technical problem to be solved by the present invention: Aiming at the disadvantages of poor compactness, easy accumulation of dust and dirt, poor stain resistance and easy occurrence of pan-alkali phenomenon in the current ceramic tile grouting agent, a kind of mixing and melting reaction of white cement and quartz sand is provided. Afterwards, spray liquid nitrogen to cool to obtain a solid for later use, then take octamethylcyclotetrasiloxane, tetramethyldivinyldisiloxane, etc. Stirring reaction to obtain organosilicon styrene-acrylic polymer, and then add it to an emulsifier, then add spare solids, copper sulfate, etc. After high-speed stirring reaction, the method of preparing anti-fouling and bactericidal high-quality ceramic tile joint sealant through shaking table vibration treatment
The preparation steps of the invention are simple, the obtained product has good compactness, no dust and dirt accumulation phenomenon occurs, is easy to clean, effectively solves the problems of poor stain resistance and easy efflorescence phenomenon, and has strong bactericidal performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0016] First, weigh 30g of white cement, 2g of quartz sand, and 10g of glass powder into the autoclave in turn, control the temperature at 600°C, and the pressure at 20MPa, stir and react for 2 hours to obtain the reactant, add the reactant to the flask, and put 0.1L Spray liquid nitrogen onto the beaker, lower the temperature of the beaker to -20°C, and then naturally return to room temperature to obtain a solid for later use; then weigh 2g of octamethylcyclotetrasiloxane, 0.3g of isobutyltriethoxy Add base silane into a three-necked flask with a thermometer and a reflux device, place the flask in a water bath, control the temperature at 80°C, then add 0.1g of lauroyl peroxide, and stir for 30 minutes. After the stirring is completed, add 3g of tetramethyldivinyldisiloxane, stirred and reacted for 3h to obtain vinylpolysiloxane; then add 10g of styrene and 10g of acrylate to the above vinylpolysiloxane in turn, stir for 10min, and then add 0.1g cupric chloride, 0.1g lauroyl p...

example 2

[0019] First, weigh 35g of white cement, 3g of quartz sand, and 15g of glass powder into the autoclave in turn, control the temperature at 650°C, and the pressure at 25MPa, stir and react for 3 hours to obtain the reactant, add the reactant to the flask, and put 0.2L Spray liquid nitrogen onto the beaker, lower the temperature of the beaker to -15°C, and then naturally return to room temperature to obtain a solid for later use; then weigh 3g of octamethylcyclotetrasiloxane, 0.4g of isobutyltriethoxy Add base silane into a three-necked flask equipped with a thermometer and a reflux device, place the flask in a water bath, control the temperature at 85°C, then add 0.2g of lauroyl peroxide, and stir for 35 minutes. After the stirring is completed, add 4g of tetramethyldivinyldisiloxane, stirred and reacted for 4h to obtain vinylpolysiloxane; then add 15g of styrene and 15g of acrylate to the above vinylpolysiloxane successively, stir for 15min, and then add 0.2g cupric chloride, ...

example 3

[0022]First, weigh 40g of white cement, 4g of quartz sand, and 20g of glass powder into the autoclave in turn, control the temperature at 700°C, and the pressure at 30MPa, stir and react for 3 hours to obtain the reactant, add the reactant to the flask, and put 0.3L Spray liquid nitrogen onto the beaker, lower the temperature of the beaker to -10°C, and then naturally return to room temperature to obtain a solid for later use; then weigh 4g of octamethylcyclotetrasiloxane, 0.5g of isobutyltriethoxy Add base silane into a three-necked flask equipped with a thermometer and a reflux device, place the flask in a water bath, control the temperature at 90°C, then add 0.3g of lauroyl peroxide, and stir for 40 minutes. After the stirring is completed, add 5g of tetramethyldivinyldisiloxane, stirred and reacted for 4h to obtain vinylpolysiloxane; then add 20g of styrene and 20g of acrylate to the above vinylpolysiloxane in sequence, stir for 20min, and then add 0.3g cupric chloride, 0....

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Abstract

The invention discloses a method for preparing an anti-fouling and bactericidal high-quality tile gap filler and belongs to the technical field of preparation of tile gap fillers. The method comprises the steps of weighing white cement, quartz sand and the like, carrying out a mixed and fused reaction, then, carrying out liquid-nitrogen-spraying cooling so as to prepare solids for later use, then, weighing octamethylcyclotetrasiloxane, divinyl tetramethyl disiloxane and the like, carrying out a reaction with stirring so as to obtain vinyl polysiloxane, then, subjecting the obtained vinyl polysiloxane to a stirred reaction with styrene and acrylate so as to obtain an organosilicon styreneacrylate copolymer, then, adding the organosilicon styreneacrylate copolymer into an emulsifying machine, then, adding the solids for later use, copper sulfate and the like in the emulsifying machine, carrying out a reaction with high-speed stirring, and then, carrying out shaking treatment by a shaking table, thereby preparing the anti-fouling and bactericidal high-quality tile gap filler. The method has the beneficial effects that the preparation steps of the method are simple, the obtained product is good in compactness, the phenomenon that dust and dirt are accumulated is absent, and the cleaning is easy; and the problems that the contamination resistance is poor and an efforescence phenomenon easily occurs are effectively solved, and the bactericidal performance is high.

Description

technical field [0001] The invention relates to a preparation method of an antifouling and sterilizing high-quality tile grout, and belongs to the technical field of tile grout preparation. Background technique [0002] The caulking agent has the characteristics of strong adhesion, small shrinkage, strong color fixation, anti-crack flexibility, good decorative texture, pressure resistance, wear resistance, and mold resistance, making it perfect for repairing cracks or damage on the floor surface. The surface can also be painted and has good water resistance. The caulking agent is rich in color and can be prepared by itself, so it is more and more popular among customers. Brick sealant is used for gap decoration of tiles, mosaics, stone, wood, glass, aluminum-plastic panels and other materials. After the caulking agent is solidified, it will form a clean surface as smooth as porcelain on the joints of the tiles, which is wear-resistant, waterproof, oil-proof, non-staining, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B26/32C04B18/02C08F283/12C04B111/20
CPCC04B18/021C04B26/32C04B2111/00672C04B2111/20C04B2111/2023C08F283/124C04B24/32C04B22/142C04B14/308C04B2103/0068C04B14/06C04B14/22
Inventor 雷春生盛海丰孟浩影
Owner 佛山市卓仕高新型材料有限公司