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A kind of method of preparing nitrogen carbon molecular sieve by bagasse

A carbon molecular sieve and bagasse technology, which is applied in chemical instruments and methods, carbon compounds, inorganic chemistry, etc., can solve the problems such as the preparation of carbon molecular sieves that have not been seen, and achieve the effects of low price, wide source and uniform pore size

Active Publication Date: 2017-12-22
重庆渝赞企业管理咨询中心
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Wherein the most important three kinds are coal, wood, fruit shell, do not see the report that adopts bagasse as raw material to prepare carbon molecular sieve

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A method for preparing nitrogen carbon molecular sieves from bagasse, comprising the steps of:

[0021] Step 1: After simply cleaning the bagasse, crush it mechanically to 1-3mm, heat it to 220°C by steam, keep it for 5 minutes, and release the pressure instantaneously within 0.5s to expand the bagasse cell wall fibers to obtain Expanded bagasse for later use;

[0022] Step 2: Soak the expanded bagasse in 12 times the volume of enzyme solution and hydrolyze it for 20 minutes at pH 4-5 and 90-100°C;

[0023] Step 3: Treat the solution under ultrasonic waves with a frequency of 28KHz for 35 minutes, filter, and collect the filtrate;

[0024] Step 4: Add ethanol to make the concentration in the filtrate to 85%, precipitate bagasse polysaccharide solids, and vacuum dry to obtain bagasse polysaccharide solids;

[0025] Step 5: Put the bagasse polysaccharide solid into a carbonization furnace, lay the raw materials naturally on a plane, raise the temperature to the carboniz...

Embodiment 2

[0030] A method for preparing nitrogen carbon molecular sieves from bagasse, comprising the steps of:

[0031] Step 1: After simply cleaning the bagasse, it is mechanically crushed to 1-3mm, heated to 260°C by steam, maintained for 2 minutes, and then the pressure is released instantaneously within 0.1s to expand the bagasse cell wall fibers to obtain Expanded bagasse for later use;

[0032] Step 2: Soak the expanded bagasse in 10 times the volume of enzyme solution and hydrolyze at pH 4-5 and 90°C for 25 minutes;

[0033] Step 3: Treat the solution under ultrasonic waves with a frequency of 35KHz for 40 minutes, filter, and collect the filtrate;

[0034] Step 4: adding ethanol to make the concentration in the filtrate to 90%, precipitating bagasse polysaccharide solids, and vacuum drying to obtain bagasse polysaccharide solids;

[0035] Step 5: Put the bagasse polysaccharide solid into a carbonization furnace, lay the raw materials naturally on a plane, raise the temperatur...

Embodiment 3

[0040] A method for preparing nitrogen carbon molecular sieves from bagasse, comprising the steps of:

[0041] Step 1: After simply cleaning the bagasse, crush it mechanically to 1-3mm, heat it to 190°C by steam, keep it for 5 minutes, and release the pressure instantaneously within 1 second to expand the bagasse cell wall fibers to obtain puffed Bagasse for use;

[0042] Step 2: Soak the expanded bagasse in 10 times the volume of enzyme solution and hydrolyze it at pH 4-5 at 90°C for 15 minutes;

[0043] Step 3: Treat the solution under ultrasonic waves with a frequency of 25KHz for 40 minutes, filter, and collect the filtrate;

[0044] Step 4: adding ethanol to make the concentration in the filtrate to 80%, precipitating bagasse polysaccharide solids, and vacuum drying to obtain bagasse polysaccharide solids;

[0045] Step 5: Put the bagasse polysaccharide solid into a carbonization furnace, lay the raw materials naturally on a plane, raise the temperature to the carboniza...

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Abstract

The invention discloses a method for preparing a carbon molecular sieve for nitrogen from bagasse. The raw material bagasse has the advantages of wide sources and low price. The prepared carbon molecular sieve has the advantage of uniform pore size, and is suitable for nitrogen preparation; and the method is a novel process for utilizing bagasse.

Description

technical field [0001] The invention relates to a method for preparing molecular sieves, belonging to the field of carbon materials, in particular to a method for preparing nitrogen carbon molecular sieves from bagasse. Background technique [0002] Carbon molecular sieve is a kind of carbonaceous porous material, which belongs to a kind of activated carbon. The voids are mainly composed of micropores below 1nm and a small amount of macropores, and the pore size distribution is narrow, about 0.5-1.0nm. In addition to micropores, ordinary activated carbon also has a large number of mesopores and macropores, with an average pore size of about 2nm. The pores of carbon molecular sieve are slit type. The raw materials that can be used to prepare carbon molecular sieves are very wide, from natural products to high molecular polymers can be used to manufacture carbon molecular sieves. Wherein the most important three kinds are coal, timber, fruit shell, do not see the report tha...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B32/324
Inventor 王玲燕
Owner 重庆渝赞企业管理咨询中心