Sealing agent for liquid crystal display elements, vertically conducting material and liquid crystal display element
A liquid crystal display element and sealant technology, which is applied in liquid crystal materials, optics, instruments, etc., can solve problems such as poor display, and achieve the effects of excellent adhesion, low liquid crystal pollution, and sufficient adhesion
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Embodiment 1
[0143] 2-Hydroxy-3-phenoxypropyl acrylate (manufactured by Kyoeisha Chemical Co., Ltd.) , "EPOXY ESTER M-600A") 20 parts by weight, caprolactone-modified bisphenol A type epoxy acrylate (manufactured by DICEL-ALLNEX, "EBECRYL3708") as a polymerizable compound (b) 50 parts by weight, as 30 parts by weight of partially acrylic-modified bisphenol E-type epoxy resin (manufactured by DICEL-ALLNEX, "KRM8287") of the polymerizable compound (c), 1-(4-(phenylthio) as a photoradical polymerization initiator )phenyl)-1,2-octanedione 2-(O-benzoyl oxime) (manufactured by BASF, "IRGACURE OXE01") 2 parts by weight, malonate dihydrazide (Otsuka Chemical Co., Ltd. 10 parts by weight manufactured by the company, "MDH"), 20 parts by weight of silica (manufactured by Admatechs Corporation, "Admafine SO-C2") as a filler, 3-glycidoxypropyl trimethyl as a silane coupling agent Mix 2 parts by weight of oxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., "KBM-403") and 15 parts by weight of core...
Embodiment 2~14 and comparative example 1~3
[0145] Each material of the compounding ratio described in Tables 1 and 2 was stirred and mixed similarly to Example 1, and the sealing compound for liquid crystal display elements of Examples 2-14 and Comparative Examples 1-3 were prepared.
[0146]
[0147] The following evaluation was performed about the sealing compound for liquid crystal display elements obtained in the Example and the comparative example. The results are shown in Tables 1 and 2.
[0148] (storage stability)
[0149] For each sealant for a liquid crystal display element obtained in Examples and Comparative Examples, the initial viscosity immediately after manufacture and the viscosity when stored at 25° C. for one week were measured, and (viscosity after one week of storage at 25° C.) / (initial Viscosity) is defined as the viscosity change rate, and the case where the viscosity change rate is less than 1.1 is set as "○", the case where the viscosity change rate is 1.1 or more and less than 2.0 is set as...
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