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A process for denitrification of sintering flue gas

A technology of sintering flue gas and process method, which is applied to the improvement of process efficiency, furnace, lighting and heating equipment, etc., can solve the problems of high operating cost, little progress, large investment, etc., and achieve low operating cost and strong applicability Effect

Active Publication Date: 2021-02-09
钢研晟华科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, little progress has been made in the construction of sintering flue gas denitrification. There are less than 10 sintering denitrification devices reported in my country. Among them, it is recognized that the activated carbon method has a better removal effect. Activated carbon technology can simultaneously remove SOx, NOx, and dioxins and Other harmful volatiles, but the process requires large investment and high operating costs, making it difficult to popularize
Other Selective Catalytic Reduction (SCR) denitrification methods that are maturely used in the power industry, denitrification technology cannot be realized due to the low temperature of the burnt tail gas. If the exhaust gas is heated to the temperature required for the catalytic reaction, the energy consumption will be huge, and the operating cost will also increase.
[0003] In terms of waste heat utilization in the sintering process, on the one hand, the energy consumption of the sintering process is second only to blast furnace ironmaking, accounting for about 15% of the total energy consumption of iron and steel enterprises; on the other hand, the proportion of waste heat utilization in the sintering process is very low, only 35% to 45%. About 0.9GJ of heat energy per ton of sinter is not utilized

Method used

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  • A process for denitrification of sintering flue gas
  • A process for denitrification of sintering flue gas
  • A process for denitrification of sintering flue gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The sintering flue gas at 120-130°C is discharged from the desulfurization tower after wet desulfurization, the tail gas temperature is 55-60°C, and the water content is 75mg / m 3 , the steam with high moisture content is dehumidified through the lithium bromide and lithium chloride salt solution contained in the plastic material, and the relative humidity of the flue gas after dehumidification is 20% to 30%;

[0024] During the dehumidification process, the dehumidification solution absorbs the moisture in the tail gas, and its own concentration decreases, and the dehumidification solution is concentrated and regenerated by using the waste heat of the sintering flue gas pipeline at 120-130°C;

[0025] The desulfurized tail gas after dehumidification first passes through the pipeline heat exchanger to exchange heat with the sintering flue gas and sintering ore. After the heat exchange, the tail gas temperature is about 100°C;

[0026] The heat exchange exhaust gas is blo...

Embodiment 2

[0034] The sintering flue gas at 120-130°C is discharged from the dust bag after dry desulfurization, the tail gas temperature is about 90°C, and the relative humidity is about 40%;

[0035] Desulfurization tail gas passed through anhydrous CaCl 2 The dehumidification device further dehumidifies so that the relative humidity is below 20%;

[0036] CaCl 2 Heat release after moisture absorption, tail gas temperature remains at around 90°C after dehumidification, CaCl after moisture absorption 2 Dehydration and regeneration of tail gas after heat exchange by waste heat boiler;

[0037] The heat exchange tail gas is blown in by the fan in the high temperature section of the belt cooler to exchange heat with the sinter, and the sinter in the low temperature section is cooled by natural wind, and a partition wall is added in the belt cooler to prevent the desulfurization tail gas from mixing with the cold air in the low temperature section;

[0038] After the heat exchange, the t...

Embodiment 3

[0045] The sintering flue gas at 120-130°C is discharged from the dust bag after dry desulfurization, the tail gas temperature is about 90°C, and the relative humidity is about 40%;

[0046]The heat exchange tail gas exchanges heat with the sinter through the vertical tank type sinter cooling device. After the heat exchange, the temperature of the desulfurized tail gas is above 320°C. The cold air is cut into the vertical tank to continue cooling the sinter to below 100°C, and the sinter is discharged and sent to Blast furnace smelting.

[0047] After heat exchange, the tail gas is dedusted by the electric precipitator to make the dust concentration of the flue gas meet the requirements of selective catalytic reduction and denitrification;

[0048] Ammonia vapor is introduced into the denitrification device with built-in catalyst for reduction and denitrification. The removal rate of NOx in the flue gas is above 85%. The reaction equation of selective catalytic reduction and d...

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Abstract

The invention relates to a process method for denitrification of sintering flue gas, which is especially suitable for the flue gas treatment of iron ore sintering in the iron and steel industry. This method can be used as a supporting construction of an existing sintering desulfurization process, or can be newly built together with a mature sintering flue gas desulfurization process. The tail gas after sintering desulfurization is dehumidified and then used for heat exchange of sinter in the high-temperature section of the ring cooler, belt cooler or vertical tank sinter cooling device. The temperature of the heat exchange tail gas is kept above 300°C after dust removal. SCR is used to denitrify the tail gas. The removal rate of NOx in the flue gas is above 85%. The temperature of the tail gas after denitrification is higher than 250°C. It can be used for waste heat power generation or hot air sintering of sintering machines, ignition and combustion, and preheating of sintering ore. The process method has the advantages of large processing capacity, strong applicability, full use of sensible heat of sintered ore, and low operating cost.

Description

technical field [0001] The invention relates to the treatment of desulfurization tail gas in the iron ore sintering process, and is particularly suitable for a treatment process method for denitrification of sintering flue gas. Background technique [0002] my country's iron and steel production is mainly based on the blast furnace-converter long process, sintering ore accounts for about 70% to 75% of the blast furnace charge, and the dust emission and SO 2 The emissions of industrial dust and SO in my country account for about 2 At the same time, the sintering process also discharges a large amount of harmful substances such as NOx, HF, HCl, heavy metals and dioxins, becoming the main source of air pollution. At present, the technology of sintering flue gas desulfurization is mature, and there are many methods. There are about 650 sets of sintering desulfurization facilities built and put into operation in China. However, little progress has been made in the construction ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): F27D17/00
CPCY02P10/25
Inventor 郭玉华齐渊洪严定鎏林万舟周和敏于恒
Owner 钢研晟华科技股份有限公司