Organic solvent base coating composition
A pigment composition and a technology for the composition, which are applied in the field of repair coating, can solve the problems of poor appearance and poor durability of the undercoating film, and achieve the effects of excellent adhesion and sufficient durability.
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[0110] Hereinafter, the present invention will be described more specifically by way of examples. However, the present invention is not limited to these examples. In addition, "part" and "%" in the following example represent "part by mass" and "% by mass", respectively.
[0111]
manufacture example 1
[0113] Add 52 parts of butyl acetate to the reaction vessel, raise the temperature to 110°C while stirring, and add 15 parts of styrene and 10 parts of methyl methacrylate dropwise at a constant speed for 3 hours at a temperature below 110°C using a dropping pump. , 10 parts of n-butyl methacrylate, 20 parts of tert-butyl methacrylate, 19 parts of 2-ethylhexyl methacrylate, 15 parts of 2-hydroxyethyl methacrylate, Placcel FA-2D (trade name, Daicel Chemical Co., Ltd., a monomer mixture containing 10 parts of a reaction product of caprolactone and hydroxyethyl acrylate), 1 part of acrylic acid, and 2.0 parts of azobisisobutyronitrile, and a polymerization initiator. After completion of the dropwise addition, the temperature was kept at 110° C. for 60 minutes, and stirring was continued. Thereafter, a solution obtained by dissolving 0.5 parts of azobisisobutyronitrile as an additional catalyst in 7 parts of butyl acetate was added dropwise at a constant rate over 60 minutes. The...
manufacture example 2
[0115] In the said manufacture example 1, except having made the monomer composition into the following, it carried out similarly, and obtained the lactone-modified acrylic resin solution (A-2). The weight average molecular weight of the resin is 14000, the hydroxyl value of the solid is 80mgKOH / g, the acid value of the solid is 8mgKOH / g, and the glass transition temperature is 35°C.
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