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Halogen-free flame-retardant toughened polypropylene cable material and preparation method thereof

A polypropylene and cable material technology, applied in the direction of plastic/resin/wax insulators, organic insulators, etc., can solve the problems of poor mechanical strength and elasticity, large amount of flame retardants, poor flame retardant effect, etc., to achieve wear resistance Excellent tear performance, improved tensile strength, good elasticity and flame retardant effect

Inactive Publication Date: 2017-07-25
泉州盈创新材料技术开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the halogen-free flame-retardant polypropylene cable materials currently on the market generally have poor mechanical strength and elasticity, and are not wear-resistant. The application of polypropylene cable material

Method used

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  • Halogen-free flame-retardant toughened polypropylene cable material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A halogen-free flame-retardant and toughened polypropylene cable material, the basic formula and weight ratio are as follows: 30 parts of random copolymerized polypropylene, 8 parts of maleic anhydride grafted polypropylene, 5 parts of powdered polyphenylene sulfide, terminal hydroxyl 10 parts of hyperbranched polyester, 6 parts of rare earth coupling agent, 15 parts of triphenyl phosphate, 3 parts of lanthanum hydroxide, 12 parts of nano talc powder modified by coupling agent, and 1 part of antioxidant.

[0024] The above-mentioned halogen-free flame-retardant toughened polypropylene cable material, its preparation process steps are as follows:

[0025] (1) Weigh the raw materials in the formula according to the weight ratio and add them to the high-mixer, stir for 20 minutes, and mix well;

[0026] (2) Put the raw materials mixed in step (1) into the hopper of the twin-screw extruder, melt and extrude, and granulate; the processing technology is as follows: the temper...

Embodiment 2

[0028] A halogen-free flame-retardant and toughened polypropylene cable material, the basic formula and weight ratio are as follows: 40 parts of random copolymerized polypropylene, 14 parts of maleic anhydride grafted polypropylene, 10 parts of powdered polyphenylene sulfide, terminal hydroxyl 16 parts of hyperbranched polyamide ester, 12 parts of rare earth coupling agent, 22 parts of phosphonate, 7 parts of cerium hydroxide, 18 parts of nano talc powder modified by coupling agent, and 5 parts of antioxidant.

[0029] The above-mentioned halogen-free flame-retardant toughened polypropylene cable material, its preparation process steps are as follows:

[0030] (1) Weigh the raw materials in the formula according to the weight ratio and add them to the high mixer, stir for 30 minutes, and mix well;

[0031] (2) Put the raw materials mixed in step (1) into the hopper of the twin-screw extruder, melt and extrude, and granulate; the processing technology is as follows: the barrel ...

Embodiment 3

[0033] A halogen-free flame-retardant and toughened polypropylene cable material, the basic formula and weight ratio are: 35 parts of random copolymerized polypropylene, 11 parts of maleic anhydride grafted polypropylene, 8 parts of powdered polyphenylene sulfide, terminal hydroxyl 13 parts of hyperbranched polyester, 9 parts of rare earth coupling agent, 18 parts of ammonium polyphosphate, 5 parts of cerium hydroxide, 15 parts of nano talc powder modified by coupling agent, and 3 parts of antioxidant.

[0034] The above-mentioned halogen-free flame-retardant toughened polypropylene cable material, its preparation process steps are as follows:

[0035] (1) Weigh the raw materials in the formula according to the weight ratio and add them to the high mixer, stir for 25 minutes, and mix well;

[0036] (2) Put the raw materials mixed in step (1) into the hopper of the twin-screw extruder, melt and extrude, and granulate; the processing technology is as follows: the barrel temperat...

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Abstract

The invention discloses a halogen-free flame-retardant toughened polypropylene cable material and a preparation method thereof. According to a basic formula, the halogen-free flame-retardant toughened polypropylene cable material comprises, by weight, 30-40 parts of polypropylene, 8-14 parts of maleic anhydride graft, 5-10 parts of polyphenylene sulfide, 10-16 parts of hyperbranched polymer, 6-12 parts of coupling agent, 15-22 parts of halogen-free flame retardant, 3-7 parts of flame-retardant synergist, 12-18 parts of coupling agent modified filler, and 1-5 parts of antioxidant. The preparation method includes sending the materials which are mixed uniformly into a feed hopper of a dual-screw extruder and then extruding and pelletizing through dual screws. The polypropylene cable material prepared by the method has the advantages of high mechanical strength, good elasticity and flame-retardant effect and excellent wear resistance and tear resistance properties, and is applicable to the field of wires and cables.

Description

technical field [0001] The invention relates to the field of wire and cable materials, in particular to a halogen-free flame-retardant and toughened polypropylene cable material and a preparation method thereof. Background technique [0002] Polypropylene (PP) is a semi-crystalline thermoplastic with high impact resistance, strong mechanical properties, and resistance to various organic solvents and acid and alkali corrosion. It is widely used in wire and cable, building materials, automobile industry, household Electrical appliances, packaging materials, etc. Due to the poor flame retardancy of polypropylene, it is easy to burn. Its limiting oxygen index (LOI) is 18.5. Applications in the field of cables. Most of the products currently on the market are polypropylene cable materials modified by adding halogen-free flame retardants. [0003] However, the halogen-free flame-retardant polypropylene cable materials currently on the market generally have poor mechanical stren...

Claims

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Application Information

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IPC IPC(8): C08L23/14C08L87/00C08L81/02C08K13/06C08K3/22C08K5/521C08K5/5333C08K3/32H01B3/44
CPCC08L23/14C08K2003/221C08K2003/2213C08K2003/323C08L2201/02C08L2201/22C08L2203/202C08L2205/035C08L2205/05H01B3/441C08L87/00C08L81/02C08K13/06C08K3/22C08K5/521C08K5/5333C08K3/32
Inventor 刘凤姐
Owner 泉州盈创新材料技术开发有限公司