Compound for treating prostatic cancers, preparation method therefor and use of compound
A technology for prostate cancer and compounds, which is applied in the directions of steroids, medical preparations containing active ingredients, organic chemistry, etc., can solve problems such as drug treatment not being a treatment plan, drug deficiency, and limitation of CYP11B1 activity and efficacy.
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[0018] The present invention will be described in detail below in conjunction with the examples. The examples of the present invention are only used to illustrate the technical solutions of the present invention, and do not limit the essence of the present invention.
[0019] Put 3.6g of Formula B in 20ml of dichloromethane, add 1.3g of triethylamine, dropwise add 1.8g of acetyl chloride at room temperature, react for 1h, after the reaction is complete, wash twice with 10ml of water, dry over anhydrous sodium sulfate, and concentrate to obtain the product 4.0 g.
[0020]
[0021] Put 3.6g of formula B in 20ml of dichloromethane, add 1.9g of N-Boc glycine, add 1.1g of thionyl chloride dropwise at zero degree, react for 1h, then react for 2h at room temperature, after concentration, add 20ml of methanol, add 2ml of 1N hydrochloric acid , refluxed for 1h, cooled to room temperature, added 20ml of water, adjusted the pH to about 8 with a saturated sodium bicarbonate solution, f...
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