Lithium battery electrolyte based on sulfate additive
An additive and sulfate technology, applied in the field of lithium battery electrolyte and new energy materials, can solve the problems of dendrite growth and low coulombic efficiency, and achieve the effect of easy large-scale continuous production, easy manufacturing and strong universality
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[0038] Example 1: 1M LiPF with dimethyl sulfate added 6 EC / DMC (v=1:1) electrolyte lithium deposition / precipitation efficiency
[0039] In an inert atmosphere, 1wt% of dimethyl sulfate was added to the commercially available 1M LiPF 6 In the EC / DMC (v=1:1) solution, prepare a ready-to-use electrolyte. According to the order of the positive battery case, the copper pole piece, the diaphragm, the lithium metal pole piece, and the negative battery case, inject the ready-to-use electrolyte, and assemble the button battery in the glove box.
[0040] The assembled button cell constitutes a copper and lithium two-electrode system. The lithium metal pole piece is used as the reference and auxiliary electrode, and the copper pole piece is used as the working electrode. The deposition and precipitation process of lithium metal on the current collector can be examined. This process can be analyzed , Can judge the reversibility and efficiency of the deposition and precipitation process, so a...
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[0042] Example 2: 1M LiPF with dimethyl sulfate added 6 Scanning electron microscope topography of lithium deposition / precipitation in EC / DMC (v=1:1) electrolyte
[0043] Using the method of Example 1, disassemble the button cell after 20 weeks of circulation in the glove box, take out the copper pole piece, wash the pole piece with dimethyl carbonate, dry it, and place it under a scanning electron microscope for observation. Such as image 3 Shown. The control group without sulfate ester additives showed a typical lithium deposition morphology. Needle-like dendrites with a diameter of about 200nm were deposited on the copper current collector. The growth of such dendrites would pierce the separator and cause the inside of the battery. Short circuit causes serious safety problems. After adding the sulfuric acid ester additive, after the electrolyte was circulated for 20 weeks, the morphology of the lithium deposit was dendrites about 5 μm tumor-like particles, and the growth of...
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[0044] Example 3: 1M LiTFSI DOL / DME (v=1:1)+1% LiNO added with diethyl sulfate 3 Lithium deposition / extraction efficiency of electrolyte
[0045] In an inert atmosphere, add diethyl sulfate to 1M LiTFSI DOL / DME (v=1:1)+1% LiNO 3 In the electrolyte, its mass fraction is 3.8%. The Li|Cu button cell was assembled according to the method in Example 1, and the electrochemical performance test was performed.
[0046] Figure 4 It is 1M LiTFSI DOL / DME (v=1:1)+1% LiNO added with diethyl sulfate 3 Cycle life diagram of Li|Cu battery of electrolyte. From Figure 4 It can be seen that the deposition / precipitation efficiency of the blank control example was only 91.2% in the first week, while the electrolyte with the diethyl sulfate additive increased to 95.1% in the first week. At the same time, the number of cycles of Li|Cu batteries added with the electrolyte of diethyl sulfate increased from 40 to 100 weeks, an increase of 2.5 times. Prove that the sulfate additives are in 1M LiTFSIDOL / D...
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