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Preparation method of thermoplastic polyurethane elastomer film

A thermoplastic polyurethane and elastomer technology, which is applied in the field of polymer material preparation, can solve the problems of poor performance and uneven thickness of polyurethane elastomer film, and achieve the effects of reducing energy consumption, eliminating interchain interaction, and saving floor space

Active Publication Date: 2017-12-15
苏州奥斯汀新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a method for preparing a thermoplastic polyurethane elastomer film to solve the problems of uneven thickness and poor performance of polyurethane elastomer films in the prior art

Method used

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  • Preparation method of thermoplastic polyurethane elastomer film
  • Preparation method of thermoplastic polyurethane elastomer film
  • Preparation method of thermoplastic polyurethane elastomer film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The ratio of raw materials for thermoplastic polyurethane elastomer film, in parts by mass:

[0030]

[0031]

[0032] Preparation process: melt polyester polyol with a relative molecular weight of 1000 in a hot water bath at 90°C and put it into storage tank A; melt 4,4'-diphenylmethane-diisocyanate in a hot water bath at 45°C and put it into storage tank A. Tank B, 1,4-butanediol is melted in a hot water bath at 60°C and put into storage tank C. After mixing the materials evenly according to the formula table, use a metering pump to inject them into the mixing head respectively, and the high-speed rotating rotor will mix them evenly. Injected on the conveyor belt, the material is solidified into sheets through the drying tunnel, the sheets are broken or pelletized, and sent to the extruder for secondary granulation at 110°C, at a temperature of 110°C and a pressure of -0.09MPa~ - 0.1MPa drying machine post-aging for 6h, drying in a dehumidification drying tower ...

Embodiment 2

[0035] The ratio of raw materials for thermoplastic polyurethane elastomer film, in parts by mass:

[0036]

[0037]

[0038] Preparation process: melt polyester polyol with a relative molecular weight of 2000 in a hot water bath at 90°C and put it into storage tank A; melt 4,4'-diphenylmethane-diisocyanate in a hot water bath at 43°C and put it into storage tank A. In tank B, melt 1,4-butanediol in a hot water bath at 65°C and put it into storage tank C. Mix the materials evenly according to the formula table and then inject them into the mixing head with a metering pump, and mix them evenly with the high-speed rotating rotor , injected on the conveyor belt, the material is solidified into sheets through the drying tunnel, the sheets are broken or pelletized, and sent to the extruder for secondary granulation at 110°C, at a temperature of 105°C and a pressure of -0.09MPa ~-0.1MPa drier post-aging for 6 hours, and drying in a dehumidification drying tower at 120°C until ...

Embodiment 3

[0041] The ratio of raw materials for thermoplastic polyurethane elastomer film, in parts by mass:

[0042]

[0043]

[0044]Preparation process: Melt polyester polyol with a relative molecular weight of 3000 in a hot water bath at 95°C and put it into storage tank A, and put 4,4'-diphenylmethane-diisocyanate into tank A after melting it in a hot water bath at 45°C Storage tank B, melt 1,4-butanediol in a hot water bath at 75°C and put it into storage tank C, mix the materials evenly according to the formula table, then inject them into the mixing head with a metering pump, and mix them with the high-speed rotating rotor Uniform, injected on the conveyor belt, the material is solidified into sheets through the drying tunnel, the sheets are broken or pelletized, and sent to the extruder for secondary granulation at 110°C, at a temperature of 100°C and a pressure of -0.09 MPa~-0.1MPa drier post-cure for 6h, and dry in a dehumidification drying tower at 110°C until the wate...

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Abstract

The invention relates to a preparation method of a thermoplastic polyurethane elastomer film. The specific steps include: preheating polyester polyol, 4, 4'-diphenylmethane-diisocyanate and 1, 4-butanediol, then conducting mixing, mixing titanate and / or an organic tin catalyst, aerosil, an antioxidant, a lubricant, an ultraviolet absorbent and a hydrolysis resistant agent; mixing the mixtures evenly, then injecting the product to a conveyor belt, carrying out curing, fragmentation and secondary granulation, performing vacuum post-curing, and conducting dehumidification drying to a moisture content of less than 300ppm, thus obtaining a film grade thermoplastic polyurethane elastomer; subjecting the film grade thermoplastic polyurethane elastomer, aerosol and polyethylene to coextrusion, passing the product through a cooling roller to obtain a composite film, conducting continuous rolling-up and stripping, thus obtaining a polyethylene film and a thermoplastic polyurethane elastomer film. The thermoplastic polyurethane elastomer film prepared by the method provided by the invention has excellent performance and uniform thickness.

Description

technical field [0001] The invention relates to the field of polymer material preparation, in particular to a preparation method of a thermoplastic polyurethane elastomer film. Background technique [0002] Thermoplastic polyurethane elastomer (TPU) not only has the rubber characteristics of high strength and high wear resistance of cross-linked polyurethane, but also has the thermoplastic properties of linear polymer materials, so that its application can be extended to the field of plastics. Especially in recent decades, TPU has become one of the fastest growing polymer materials. TPU film is an important application form of TPU material. In recent years, with the development and progress of high technology, it has been more and more widely used. However, on the one hand, due to the very unstable characteristics of TPU film products in the production process, advanced technology and equipment are required for development and testing; High-efficiency development, high-qu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/06C08K13/04C08K7/26C08K5/134C08K5/20C08K5/07C08K5/29C08G18/42C08G18/32C08G18/76C08G18/66B29D7/01
CPCB29D7/01C08G18/3206C08G18/42C08G18/664C08G18/7671C08K5/07C08K5/1345C08K5/20C08K5/29C08K7/26C08K13/04C08L2203/16C08L2207/04C08L75/06
Inventor 周述明汪泽恒邓春艳杨向宏
Owner 苏州奥斯汀新材料科技有限公司