Catalyst for oxidative dehydrogenation and preparation method thereof
A technology of oxidative dehydrogenation and catalysts, which is applied in the direction of catalyst activation/preparation, carbon compound catalysts, metal/metal oxides/metal hydroxide catalysts, etc., can solve the problems of low pass-through rate, reduce waste water discharge, improve Through rate, the effect of a wide range of applications
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Embodiment 1 to 6
[0074] In Examples 1 to 6, zinc was used as the divalent metal cation and the catalyst was prepared according to the high concentration synthesis method.
Embodiment 1
[0076] in step 1 , 18.029g of zinc chloride (ZnCl 2) and 71.495g of ferric chloride (FeCl 3 ) was dissolved in 233.39 g of distilled water, thereby preparing 322.914 g of an aqueous metal precursor solution of pH 1 (concentration of the precursor solution: 27.7% by weight). Here, the molar ratio of the metal component contained in the metal precursor aqueous solution is Fe:Zn=2:1.
[0077] in step 2 , 0.005% by weight of ammonia solution was added to 233.39 g of distilled water at room temperature (25° C.) in the coprecipitation tank to adjust the pH to 8. The coprecipitation tank was equipped with an outlet for the aqueous solution of the metal precursor and an outlet for the aqueous solution of ammonia. Export. While adding the prepared metal precursor aqueous solution dropwise at a rate of 2 g / min through the outlet of the aqueous metal precursor solution, an aqueous solution of ammonia (pH 13.6) with a concentration of 28% to 30% is provided at room temperature throu...
Embodiment 2
[0082] except in in step 2 A zinc ferrite catalyst was prepared in the same manner as in Example 1 except that the precursor solution was added at a dropping rate of 7 g / min.
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