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Rutile type high color saturation interference color pearlescent pigment and preparation method thereof

A technology of rutile-type and pearlescent pigments, which is applied in the field of pearlescent pigments, can solve the problems of insufficient heat resistance and weather resistance of anatase-type pearlescent pigments, performance differences of pearlescent pigments, and insufficient bright colors, etc., to achieve bright colors and enhance Pigment purity, effect of enhancing finish

Active Publication Date: 2020-12-22
GUANGXI CHESIR PEARL MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The interference color of ordinary pearlescent pigments is with Fe 2 o 3 and TiO 2 The change of coverage rate shows gold, red, purple, blue, green and other hues, and it is the hue that appears in the first circle. Its saturation is not high and the color is not bright enough.
[0003] Pearlescent pigments with anatase structure have insufficient performance in heat resistance and weather resistance, and generally can only be used indoors or in occasions with mild environmental conditions, which limits their widespread use
Both rutile and anatase macroscopic crystals belong to the tetragonal crystal system, but there are obvious differences in the performance of pearlescent pigments.

Method used

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  • Rutile type high color saturation interference color pearlescent pigment and preparation method thereof
  • Rutile type high color saturation interference color pearlescent pigment and preparation method thereof
  • Rutile type high color saturation interference color pearlescent pigment and preparation method thereof

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Embodiment 1

[0034] The structure is: natural mica + SiO 2 +SnO 2 +TiO 2 +SiO2 2 +SnO 2 +TiO 2

[0035] 1) Put natural mica flakes with a particle size of 20 to 80 μm into a reaction kettle filled with deionized water with a conductivity of less than 30 μS / cm, stir to form a suspension with a solid-to-liquid weight ratio of 1:10, and stir and heat to 80°C , to obtain the first suspension;

[0036] 2) Adjust the pH value of the first suspension to 6 with 32% NaOH solution under stirring conditions, add sodium silicate aqueous solution at a certain rate, and keep the system pH constant with 20% dilute hydrochloric acid, continue stirring after adding, and obtain the second suspension;

[0037] 3) Use 20% dilute hydrochloric acid to adjust the pH value of the second suspension to 2, add an aqueous solution of tin tetrachloride at a certain rate, use 32% NaOH solution to maintain a stable pH value, and continue stirring after adding to obtain a third suspension;

[0038] 4) Use 32% NaO...

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Abstract

The invention discloses a rutile type interference color pearlescent pigment with high color saturation degree. The rutile type interference color pearlescent pigment comprises a substrate and at least six oxide coating layers, wherein the multiple oxide coating layers are alternatively coated to the surface of the substrate; the refractive index of the first oxide coating layer is smaller than 1.8, the refractive index of the second oxide coating layer is greater than 2, the refractive index of the third oxide coating layer is larger than 2.0, the refractive index of the fourth oxide coatinglayer is smaller than 1.8, the refractive index of the fifth oxide coating layer is greater than 2.0, and the refractive index of the sixth oxide coating layer is greater than 2.0. Compared with the prior art, the rutile type interference color pearlescent pigment has the advantages that by coating the multiple oxide coating layers onto the surface of the substrate, the number of interfaces of different matters is increased, so that when the light rays encounter the interfaces of different matters in the propagation process, one part of light rays is refracted out, the other part of light raysis reflected out, the smoothness of each refraction layer is improved, and the reflection effect of mirror surface is improved; the technology of the preparation technology is simple, the operation is convenient, the obtained product is colorful, and the color saturation degree and purity are high.

Description

technical field [0001] The invention belongs to the technical field of pearlescent pigments. More specifically, the invention relates to a rutile type high-color-saturation interference color pearlescent pigment and a preparation method thereof. Background technique [0002] Pearlescent pigments are powder pigments formed by coating natural muscovite or synthetic mica or glass flakes with one or more layers of metal oxides on the surface of the core by a special chemical process, so that it has a structure The flat sandwich body that is very similar to natural pearls can decompose the composite light into various monochromatic lights like a prism during use, and form various interference colors through light interference, showing extremely beautiful pearls Gloss and metallic luster. The interference color of ordinary pearlescent pigments is with Fe 2 o 3 and TiO 2 The change of coverage rate shows gold, red, purple, blue, green and other hues, and it is the hue that appe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09C1/40C09C1/28C09C3/06
CPCC09C1/0051C09C3/063
Inventor 苏尔田杨静莫峰林正交谢思维梁立德
Owner GUANGXI CHESIR PEARL MATERIAL CO LTD
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