Polyimide laminate and method for producing same
A technology of polyimide layer and polyimide, applied in the direction of chemical instruments and methods, coatings, layered products, etc., can solve the warping of laminated bodies, insufficient suppression effect, and inability to miniaturize the display part, etc. problem, to achieve the effect of suppressing warpage and good precision
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[0083] Hereinafter, the present invention will be specifically described based on Examples and Comparative Examples. Furthermore, the present invention is not limited by these contents.
[0084] First, the meaning of the abbreviation used below, the evaluation method of the physical property etc. in an Example etc. are shown.
[0085] PMDA: pyromellitic dianhydride
[0086] BPDA: 3,3′,4,4′-biphenyltetracarboxylic dianhydride
[0087] 6FDA: 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride
[0088] AAPBZ: 5-amino-2-(4-aminophenyl)benzimidazole
[0089] BAPP: 2,2′-bis(4-aminophenoxyphenyl)propane
[0090] TFMB: 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl
[0091] DMAc: N,N-Dimethylacetamide
[0092] GBL: γ-butyl lactone
[0093] 〔Transmittance(%)〕
[0094] The light transmittance at 500 nm was calculated|required with respect to a polyimide film (50mmx50mm) using the U4000 type|mold spectrophotometer.
[0095] 〔Coefficient of thermal expansion (CTE)〕
[009...
Synthetic example 1
[0112] Under nitrogen flow, TFMB: 8.49 g was dissolved in 85 g of GBL as a solvent while stirring in a 100 ml separable flask. Next, PMDA: 5.04 g was added to this solution. After 10 minutes the anhydride 6FDA: 1.47 g was added. The molar ratio of acid anhydride and diamine was set to 0.998. Afterwards, the solution was continuously stirred at room temperature for 4 hours and polymerized for one day and night. Then, a viscous colorless polyamic acid solution was obtained, and production of polyamic acid A with a high degree of polymerization was confirmed.
Synthetic example 2
[0113] Synthesis Example 2 to Synthesis Example 7
[0114]Except having changed acid anhydride and diamine into the mass composition shown in Table 1, it carried out similarly to the synthesis example 1, and prepared the polyamic-acid solution, and obtained polyamic-acid (resin) B - polyamic-acid (resin) G.
[0115] [Table 1]
[0116] Weight (g)
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