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High-toughness and crack-resistant plastic for pipe and preparation method of high-toughness and crack-resistant plastic

A technology for pipes and plastics is applied in the field of high-toughness and anti-cracking plastics for aluminum-plastic composite pipes and their preparation. The effect of improving the service life and light weight

Inactive Publication Date: 2018-07-06
安徽中一阀门集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The role of the aluminum layer is to increase the strength of internal pressure resistance, block oxygen, etc., so as to avoid the threat of corrosion to the water pipeline equipment, and the aluminum layer can improve the heat conduction effect to avoid heat concentration, antistatic and good shielding performance, and has a certain flame retardant effect ; Compared with traditional polyethylene, cross-linked polyethylene has a more stable intermolecular structure and is more suitable for building water supply and heating systems. However, the shrinkage rate of pipes made of ordinary cross-linked polyethylene materials is relatively large. Users generally report that the inner and outer layers of aluminum-plastic composite pipes, steel-plastic pipes, and copper-plastic pipes shrink due to the shrinkage of cross-linked polyethylene, so that the circumferential hot melt adhesive cannot bond the metal to the cross-linked polyethylene firmly, and the shelf life of the product is short , the stability of the production process is poor; and, when the aluminum-plastic composite pipe is used as a hot water pipe, due to long-term thermal expansion and contraction, the pipe wall will be misaligned and cause leakage, which directly leads to the use of the product. shortened lifespan

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A plastic for high-toughness and anti-cracking pipes, the plastic is made of a raw material composition and includes:

[0026] 100 parts by weight of polyethylene resin

[0027] 42 parts by weight of polyether glycol

[0028] 23 parts by weight of toluene diisocyanate

[0029] Titanium dioxide particles (average particle size 250nm) 8 parts by weight

[0030] 1.3 parts by weight of ethylene glycol

[0031] 5 parts by weight of sodium lauryl alcohol polyoxyethylene ether sulfate;

[0032] The preparation method of the above-mentioned plastic for high toughness and anti-cracking pipe is:

[0033] A1: Part of the polyethylene resin is pretreated and dried to a moisture content below 500 ppm, mixed with polyether glycol and toluene diisocyanate, kneaded in an internal mixer and pelletized by an extruder at 130°C to obtain a masterbatch;

[0034] A2: Pretreat and dry the remaining polyethylene resin to a moisture content below 500 ppm, and fully mix with titanium dioxide particles, ethyle...

Embodiment 2

[0036] A plastic for high-toughness and anti-cracking pipes, the plastic is made of a raw material composition and includes:

[0037] 100 parts by weight of polyethylene resin

[0038] 35 parts by weight of polyether triol

[0039] 15 parts by weight of isophorone diisocyanate

[0040] 6 parts by weight of calcium carbonate particles (average particle size 300nm)

[0041] 0.8 parts by weight of 1,3-butanediol

[0042] 3 parts by weight of ammonium lauryl sulfate;

[0043] The preparation method of the above-mentioned plastic for high toughness and anti-cracking pipe is:

[0044] A1: Part of the polyethylene resin is pretreated and dried to a moisture content below 500ppm, mixed with polyether triol and isophorone diisocyanate, kneaded in an internal mixer and pelletized by an extruder at 130°C to obtain a mother material;

[0045] A2: Pretreat and dry the remaining polyethylene resin to a moisture content below 500 ppm, and fully mix with calcium carbonate particles, 1,3-butanediol, ammoni...

Embodiment 3

[0047] A plastic for high-toughness and anti-cracking pipes, the plastic is made of a raw material composition and includes:

[0048] 100 parts by weight of polyethylene resin

[0049] 50 parts by weight of polytetrahydrofuran glycol

[0050] 30 parts by weight of diphenylmethane diisocyanate

[0051] 10 parts by weight of barium sulfate particles (average particle size 150nm)

[0052] 1,4-cyclohexanediol 2.5 parts by weight

[0053] 8 parts by weight of dodecylbenzene sulfonic acid;

[0054] The preparation method of the above-mentioned plastic for high toughness and anti-cracking pipe is:

[0055] A1: Part of the polyethylene resin is pretreated and dried to a moisture content below 500ppm, mixed with polytetrahydrofurandiol and diphenylmethane diisocyanate, kneaded in an internal mixer and pelletized by an extruder at 140°C to obtain a masterbatch ;

[0056] A2: Pretreat and dry the remaining polyethylene resin to a moisture content below 500ppm, and mix with barium sulfate particles, 1...

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Abstract

The invention relates to a plastic for an aluminum and plastic composite pipe and particularly relates to a high-toughness and crack-resistant plastic for the aluminum and plastic composite pipe and apreparation method of the high-toughness and crack-resistant plastic. The plastic is prepared from a raw material composition, and on the basis that the weight part of polyethylene resin is 100, theraw material composition comprises the components in parts by weight: 100 parts of polyethylene resin, 20-60 parts of polyether polyol, 10-35 parts of isocyanate, 5-12 parts of inorganic filler particles, 0.5-3 parts of chain extender and 1-10 parts of surfactant. According to the high-toughness and crack-resistant plastic for the pipe, provided by the invention, the polyether polyol is introducedto the surface of the polyethylene resin, and the polyethylene resin further reacts with isocyanate to obtain a composite resin formed by reticulated interlacing of the polyethylene resin and polyurethane resin, and the composite resin has the advantages of lightweight, high strength and high toughness and is capable of expanding and shrinking when adapting to cold and thermal shock, greatly prolonging to the service life of the aluminum and plastic composite pipe when being used as an outer-layer plastic of the aluminum and plastic composite pipe and avoiding the phenomena of separation andcracking of a pipe layer.

Description

Technical field [0001] The invention relates to plastics for aluminum-plastic composite pipes, in particular to a high-toughness anti-cracking plastic for aluminum-plastic composite pipes and a preparation method thereof. Background technique [0002] The aluminum-plastic composite pipe is composed of plastic, hot melt adhesive, aluminum alloy, hot melt adhesive, and plastic from the inside to the outside. It has good heat preservation performance, and the inner and outer walls are not easy to corrode. Because the inner wall is smooth, it has little resistance to fluid. ; Because of its good bending performance, it is more convenient to install and construct. As a water supply pipe, the aluminum-plastic composite pipe has sufficient strength. [0003] There are three main types of aluminum-plastic composite pipes on the market: (1) PE / AL / PE; (2) PE / AL / PEX; (3) PEX / AL / PEX. Among them, the first one is that both the inner and outer layers are made of poly Ethylene, the second is the...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L75/08C08L71/02C08K3/22C08K3/26C08K3/30
CPCC08K2003/2227C08K2003/2241C08K2003/265C08K2003/3045C08K2201/003C08K2201/011C08L23/06C08L2203/18C08L2205/03C08L75/08C08L71/02C08K3/22C08K3/26C08K3/30
Inventor 查士荣卜启满
Owner 安徽中一阀门集团有限公司